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Engine-out HC emissions from a PFI spark ignition engine were measured using a gas chromatograph and a flame ionization detector (FID). Two port fuel injectors were used respectively for ethanol and gasoline so that the delivered fuel was comprised of 0, 25, 50, 75 and 100% (by volume) of ethanol. Tests were run at 1.5, 3.8 and 7.5 bar NIMEP and two speeds (1500 and 2500 rpm). The main species identified with pure gasoline were partial reaction products (e.g. methane and ethyne) and aromatics, whereas with ethanol/gasoline mixtures, substantial amounts of ethanol and acetaldehyde were detected. Indeed, using pure ethanol, 74% of total HC moles were oxygenates. In addition, the molar ratio of ethanol to acetaldehyde was determined to be 5.5 to 1. The amount (as mole fraction of total HC moles) of exhaust aromatics decreased linearly with increasing ethanol in the fuel, while oxygenate species correspondingly increased.

The knock metric for controlled auto-ignition (CAI) engines is assessed by considering the physical processes that establish the pressure wave that contributes to the acoustic radiation of the engine, and by analyzing pressure data from a CAI engine. Data sets from the engine operating with port fuel injection, early direct injection and late direct injection are used to monitor the effect of mixture composition stratification. Thermodynamic analysis shows that the local pressure rise produced by heat release has to be discounted by the work spent in acoustic expansion against the ambient pressure to properly predict the pressure wave amplitude. Based on this analysis, a modified correlation between the pressure wave amplitude and the maximum pressure rise rate (MPRR) is developed by introducing an MPRR offset to account for the expansion work.

The engine out particular matter number (PN) distributions at engine coolant temperature (ECT) of 0° C to 40° C for ethanol/ gasoline blends (E0 to E85) have been measured for a direct-injection spark ignition engine under cold fast idle condition. For E10 to E85, PN increases modestly when the ECT is lowered. The distributions, however, are insensitive to the ethanol content of the fuel. The PN for E0 is substantially higher than the gasohol fuels at ECT below 20° C. The total PN values (obtained from integrating the PN distribution from 15 to 350 run) are approximately the same for all fuels (E0 to E85) when ECT is above 20° C. When ECT is decreased below 20° C, the total PN values for E10 to E85 increase modestly, and they are insensitive to the ethanol content. For E0, however, the total PN increases substantially. This sharp change in PN from E0 to E10 is confirmed by running the tests with E2.5 and E5. The midpoint of the transition occurs at approximately E5.

The blending of oxygenated compounds with gasoline is projected to increase because oxygenate fuels can be produced renewably, and because their high octane rating allows them to be used in substitution of the aromatic fraction in gasoline. Blending oxygenates with gasoline changes the fuels' properties and can have a profound affect on the distillation curve, both of which are known to affect engine-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon and particulate emissions is experimentally determined in a spray guided direct injection engine. Particulate number concentration and size distribution were measured using a Cambustion DMS500. These data are presented for different air fuel ratios, loads, ignition timings and injection timings. In addition, the ASTM D86 distillation curve was modeled using the binary activity coefficients method for the fuel blends used in the experiments.

Certain diesel fuel specification properties are considered to be environmental parameters according to the European Fuels Quality Directive (FQD, 2009/EC/30) and previous regulations. These limits included in the EN 590 specification were derived from the European Programme on Emissions, Fuels and Engine Technologies (EPEFE) which was carried out in the 1990’s on diesel vehicles meeting Euro 2 emissions standards. These limits could potentially constrain FAME blending levels higher than 7% v/v. In addition, no significant work has been conducted since to investigate whether relaxing these limits would give rise to performance or emissions debits or fuel consumption benefits in more modern vehicles. The objective of this test programme was to evaluate the impact of specific diesel properties on emissions and fuel consumption in Euro 4, Euro 5 and Euro 6 light-duty diesel vehicle technologies.

In Europe, the development and implementation of new regulatory test procedures including the chassis dynamometer (CD) based World Harmonised Light Duty Test Procedure (WLTP) and the Real Driving Emissions (RDE) procedure, has been driven by the close scrutiny that real driving emissions and fuel consumption from passenger cars have come under in recent times. This is due to a divergence between stated certification performance and measured on-road performance, and has been most pointed in the case of NOx (oxides of nitrogen) emissions from diesel cars. The RDE test is certainly more relevant than CD test cycles, but currently certification RDE cycles will not necessarily include the most extreme low speed congested or low temperature conditions which are likely to be more challenging for NOx after-treatment systems.

The NOx emission and knock characteristics of a PFI engine operating on ethanol/gasoline mixtures were assessed at 1500 and 2000 rpm with λ =1 under Wide-Open-Throttle condition. There was no significant charge cooling due to fuel evaporation. The decrease in NOx emission and exhaust temperature could be explained by the change in adiabatic flame temperature of the mixture. The fuel knock resistance improved significantly with the gasohol so that ignition could be timed at a value much closer or at MBT timing. Changing from 0% to 100% ethanol in the fuel, this combustion phasing improvement led to a 20% increase in NIMEP and 8 percentage points in fuel conversion efficiency at 1500 rpm. At 2000 rpm, where knocking was less severe, the improvement was about half (10% increase in NIMEP and 4 percentage points in fuel conversion efficiency).