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To clarify the microcrystal structure of soot particulate in the combustion chamber, we examined sampling methods which freeze the reaction of sample specimens from the combustion chamber and collected the soot particulates on microgrids. We investigated the microcrystal structure with a high resolution transmission electron microscope. The results were: the particle size distribution and the microcrystal structure of the soot particulates is little different for the cooled freezing method and room temperature sampling. The typical layer plane structure which characterizes graphite carbon is not observed in the exhaust of diesel engines, but some particulates display a somewhat similar layer plane structure. The structure of soot particulate is a turbostratic structure as the electron diffraction patterns show polycrystals. The soot particulates in the combustion chamber is similar to exhaust soot particulates.

The blending of dimethyl carbonate (DMC), which contains 53% of oxygen, in diesel fuel is very effective to suppress the formation of exhaust particulates, however, the mechanism of the suppression has not been made clear. In this study, the comparison on the performance of gas oil and DMC mixture was achieved. The effect of the oxygen in DMC molecule has to suppress the formation of particulates was monitored by way of using thermal cracking analyzer under various conditions.

This paper presents results of experiments to reduce smoke emitted from direct Injection diesel engines by strong turbulence generated during the combustion process. The turbulence was created by jets of burned gas from an auxiliary chamber installed in the cylinder head. Strong turbulence, which was induced late in the combustion period, enhanced the mixing of air with unburned fuel and soot, resulting in a remarkable reduction of smoke and particulate; NOx did not show any increase with this system, and thermal efficiency was improved at high loads. The paper also shows that the combination of EGR and water injection with this system effectively reduces the both smoke and NOx.

Copper ion-exchanged ZSM-5 zeolite catalyst, which reduces nitrogen oxides (NOx) in the presence of oxygen and hydrocarbons, was applied to actual diesel engine exhaust. Copper ion-exchanged ZSM-5 zeolite effectively reduced NOx by 25% in normal engine operation, and by 80% when hydrocarbons in the exhaust were increased. Water in the exhaust gas decreased the NOx reduction efficiency, but oxygen and sulfur appeared to have only a small effect. Maximum NOx reduction was observed at 400°C irrespective of hydrocarbon species, and did not decrease with space velocity up to values of 20,000 1/h. THE PURPOSE of this paper is to evaluate the possibilities and problems in catalytic reduction of NOx in actual diesel engine exhaust. Here, a copper ion-exchanged ZSM-5 zeolite (Cu-Z) catalyst was applied to diesel engine exhaust to examine the dependency of the NOx reduction efficiency on temperature and space velocity. The effects of oxygen, water and hydrocarbons were also examined.

Exhaust Particulate emitted from diesel engines is a serious problem form the point of view of the environment and energy saving. Exhaust particulate is consist of dry soot and SOF (soluble organic fraction). To clarify the formation process of SOF in the combustion chamber of diesel engines, first lower temperature column condensed method was investigated. The gas from combustion chamber was collected to the sampling column using this method, and the cracked as well as the condensation polymerized components were analyzed with gas chromatography. The sampling condition of the low temperature column condensation method are length of condensation column 600mm, cooling temperature 198K, and dilution ratio 5. The diesel fuel injected into the combustion chamber, first cracks into lower boiling point hydrocarbons, this is followed by dehydrogenation and formation of benzene ring compounds through condensation polymerization. This is followed by the formation of PAH.

This paper presents experimental results of the reduction of both particulate and NOx emitted from direct injection diesel engines by a two stage combustion process. The primary combustion is made very rich to reduce NOx and then the particulate is oxidized by strong turbulence generated during the secondary combustion. The rich mixture is formed by low pressure fuel injection and a small cavity combustion chamber configuration. The strong turbulence is generated by a jet of burned gas from an auxiliary chamber installed at the cylinder head. The results showed that NOx was reduced significantly while maintaining fuel consumption and particulate emissions. An investigation was also carried out on the particulate reduction process in the combustion chamber with the turbulence by gas sampling and in-cylinder observation with an optical fiber scope and a high speed camera.

With the aid of static mixer and non-ionic emulsifying agent, a comparatively stable water-fuel emulsion was obtained. Engine performance in a 4 cycle direct injection engine using these fuels were studied. A large reduction of NOx concentration was obtained over the wide range of engine operation, in spite of increased ignition lag and rapid combustion. Furthermore, improvements of economy and reduction of exhaust smoke were obtained. The reduction of NOx concentration, fuel consumption and smoke were even more remarkable when compared with operating same engine with water fumigation.

This paper reports the results of two parallel investigations: An investigation on the solubility of alcohols in diesel fuels, and the diesel engine performance with the blended fuels. The investigation proposes an empirical formula for the solubility of alcohols in diesel fuels, as a function of temperature, water content, additive concentration and specific gravity of the diesel fuel. The engine performance when using the blended fuels was also investigated. Compared with conventional diesel fuels, the blended fuels show promise of better thermal efficiency, smoke free operation, and reduction of HC, NOx, and CO emissions.

To clarify the formation processes of soot particulates in the combustion chamber, we sampled the gas during combustion in a precombustion chamber and a main chamber using an electromagnetic sampling valve, and made a gas analysis by gas chromatography, examined the soot concentration, and size distribution and dispersion of soot particulates with a transmission electron microscope. The following results were obtained: (1) In the prechamber soot particulates form at the period of rapid combustion in the initial stage rather than the end of the diffusion combustion. (2) Soot particulates which were formed in the prechamber were introduced to the main chamber, and a part of the soot particulates were burned. (3) Soot particulates formed at the initial stage of the combustion process exhibited a tendency to become smaller by oxidation. (4) If the oxygen concentration in the combustion chamber is above 5%, the combustion of soot particulates take place.

This paper provides information on measurements and measurement techniques for particulate and unburnt hydrocarbon emissions from diesel engines. A dilution mini-tunnel was used to characterize the effects of the dilution ratio and sample temperature on the total particulate mass and soluble organic fraction(SOF) constituents. Increasing the sample temperature resulted in changes in the polynuclear aromatic hydrocarbon(PAH) constituents in SOF. The SOF was isolated by column chromatography, and the PAH fraction was determined by high performance liquid chromatography(HPLC). Column chromatography with silicagel, an octadecylsilan-bonded column, and keeping at high temperatures improved the analytical efficiency of HPLC. The gaseous hydrocarbon in raw exhaust was analysed by GC with FID. The temperature of the sample glass syringe affected measurements of high boiling point hydrocarbon constituents.

Exhaust particulate in diesel engines are affected by fuel properties, especially the aromatic hydrocarbon content and distillation properties, but the reasons for this are not clear. The process of particulate formation has been reported to start with a thermal cracking of the fuel to lower boiling point hydrocarbons followed by condensation polymerization and production of benzene ring compounds; the formation of particulate takes place via polycyclic aromatic hydrocarbons. The fuel properties affect diesel engine particulate because the thermal cracking and condensation polymerization of various fuels are different.

Exhaust particulate in diesel engines is affected by fuel properties, but the reason for this is not clear. Interest in using low-grade fuels in diesel engines has made it necessary to understand the particulate formation mechanism and factors to decrease it. Particulate formation has been reported to start with thermal cracking of the fuel to lower boiling point hydrocarbons followed by condensation polymerization and production of benzene ring compounds; the formation of particulate takes place via polycyclic aromatic hydrocarbons. This report investigates the amount and configuration of particulate with a fluid reaction tube and in a nitrogen atmosphere, and analyzes polycyclic aromatic hydrocarbons (PAH) of fuels with different molecular structure and carbon number.

Micro-explosions and vaporizing behaviors of droplets of various emulsified fuels were investigated to determine the influence of emulsified fuel properties such as water content, water particle size, and viscosity of base fuel on combustion in a diesel engine. The investigation used gas oil, A heavy oil, and B heavy oil mixed with water and evaporated on a hot surface under atmospheric pressure. The influence on the engine performance was also investigated. It was confirmed that the viscosity of the base fuel, the water content, and the water particle size influenced the droplet evaporation on the hot surface and the occurrence and intensity of micro-explosions. There were remarkable differences in the BSFC for emulsified fuels in or outside the range where micro-explosions occurred on the hot surface.

This paper is a systematic investigation of the effects of combustion and injection systems on hydrocarbon(HC) and particulate emissions from a DI diesel engine. Piston cavity diameter, swirl ratio, number of injection nozzle openings, and injection direction are varied as the experimental parameters, and the constituents in the soluble organic fraction (SOF) of the particulate were analyzed. The results show that the emission characteristics of deep dish chambers greatly differ from those of shallow dish chambers varying with the number of nozzle openings, the injection direction, and swirl intensity. The HC analysis shows mainly low carbon number gaseous HC constituents, and there is a tendency towards increasing polynucleation of polynuclear aromatic hydrocarbon(PAH) in SOF with increasing soot formation.

Experiments on a large number of soluble fuel additives were systematically conducted for diesel soot reduction. It was found that Ca and Ba were the most effective soot suppressors. The main determinants of soot reduction were: the metal mol-content of the fuel, the excess air factor, and the gas turbulence in the combustion chamber. The soot reduction ratio was expressed by an exponential function of the metal mol-content in the fuel, depending on the metal but independent of the metal compound. A rise in excess air factor or gas turbulence increased the value of a coefficient in the function, resulting in larger reductions in soot with the fuel additives. High-speed soot sampling from the cylinder showed that with the metal additive, the soot concentration in the combustion chamber was substantially reduced during the whole period of combustion. It is thought that the additive acts as a catalyst not only to improve soot oxidation but also to suppress soot formation.