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Carbosieve SIII was used to filter dichloromethane (DCM) from a simulated spacecraft gas stream. This adsorbent was tested as a possible commercial-off-the-shelf (COTS) filtration solution to controlling spacecraft air quality. DCM is a halocarbon commonly used in manufacturing for cleaning and degreasing and is a typical component of equipment offgassing in spacecraft. The performance of the filter was measured in dry and humid atmospheres. A known concentration of DCM was passed through the adsorbent at a known flow rate. The adsorbent removed dichloromethane until it reached the breakthrough volume. Carbosieve SIII exposed to dry atmospheric conditions adsorbed more DCM than when exposed to humid air. Carbosieve SIII is a useful thermally regenerated adsorbent for filtering DCM from spacecraft cabin air. However, in humid environments the gas passes through the filter sooner due to co-adsorption of additional water vapor from the atmosphere.

A lab-scale testbed for screening and characterizing the chemical specificity of commercial “off-the-shelf” (COTS) polymer adsorbents was built and tested. COTS polymer adsorbents are suitable candidates for future trace contaminant (TC) control technologies. Regenerable adsorbents could reduce overall TC control system mass and volume by minimizing the amounts of consumables to be resupplied and stored. However, the chemical specificity of these COTS adsorbents for non-methane volatile organic compounds (NMVOCs) (e.g., methanol, ethanol, dichloromethane, acetone, etc) commonly found in spacecraft is unknown. Furthermore, the effect of humidity on their filtering capacity is not well characterized. The testbed, composed of a humidifier, an incubator, and a gas generator, delivers NMVOC gas streams to conditioned sorbent tubes.

Understanding the effects of dynamic thermal and vacuum regeneration on VOC desorption kinetics is needed for the development of regenerable trace contaminant control air revitalization systems. The effects of temperature and vacuum quality on the desorption kinetics of ethanol from Carbosieve SIII were examined using 1 hour regeneration cycles. The effect of vacuum quality on ethanol desorption was studied by exposing adsorption tubes loaded with ethanol to low pressures (1.0, 0.5, 0.3, and 0.12 atm) at various thermal regeneration temperatures (160, 100, 70, and 25 °C). At 1 atm of pressure, ethanol removal was found to increase from 2% at 25 °C, to 25% at 70 °C, to 55% at 100 °C, and to 77% at 160 °C. Decreasing the atmospheric pressure from 1 to 0.1 atm for 1 hr did not significantly enhance Carbosieve SIII regeneration at ambient temperatures (25 °C). However, heating the adsorbent at low pressures enhanced its regeneration.