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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

The target of the investigation is the particular influence of a fuel injection system and its components as a noise source in automotive engines. The applied methodology is demonstrated on an automotive Inline 4-cylinder Diesel engine using a common rail system. This methodology is targeted as an extension of a typical standard acoustic simulation approach for combustion engines. Such approaches basically use multi-body dynamic simulation with interacting FEM based flexible structures, where the main excitation crank train, timing drive, valve train system and piston secondary motion are considered. Within the extended approach the noise excitation of the hydraulic and mechanical parts of the entire fuel system is calculated and subsequently considered within the multi-body dynamic simulation for acoustic evaluation of structural vibrations.

Although the application of cylinder pressure sensors to gain insight into the combustion process is not a novel topic itself, the recent availability of inexpensive in-cylinder pressure sensors has again prompted an upcoming interest for the utilization of the cylinder pressure signal within engine control and monitoring. Besides the use of the in-cylinder pressure signal for combustion analysis and control the information can also be used to determine related quantities in the exhaust or intake manifold. Within this work two different methods to estimate the pressure inside the exhaust manifold are proposed and compared. In contrary to first principle based approaches, which may require time extensive parameterization, alternative data driven approaches were pursued. In the first method a Principle Component Analysis (PCA) is applied to extract the cylinder pressure information and combined with a polynomial model approach.

A thermo-mechanical fatigue analysis was conducted based on a coupled Finite Element Analysis (FEA) - Computational Fluid Dynamics (CFD) method on the crack failure of the exhaust manifold for an inline 4-cylinder turbo-charged diesel engine under the durability test. In the this analysis, the temperature-dependent material properties were obtained from measurements and the model was calibrated with comparison of the predicted exhaust manifold temperatures with the on-engine measurements under the same engine load condition. Temperature and stress/strain distributions in the exhaust manifold were predicted with the calibrated model. Analysis results showed that the cracks took place at locations with high plastic deformations, suggesting that the cause of the failure be thermo-mechanical fatigue (TMF). Using the equivalent plastic strain (PEEQ) as the indicator for thermal mechanical fatigue, three exhaust manifold design revisions were carried out by CAE analysis.

One of the most important safety issues for automotive engineering is to avoid any fire due to the ignition of flammable liquids, which may result from leaks. Fire risk is a combination of hot temperature, fast vaporisation and accumulation of vapor in a cavity. In IC engines, potentially flammable liquids are fuel and oil. To guarantee safety, flammable liquids must not come into contact with hot parts of the engine. Consequently, shields are designed to guide the flow path of possible leakages and to take any flammable liquid out of the hot areas. Simulation is a great help to optimize the shape of the shield by investigating a large number of possible leakages rapidly. Recent breakthroughs in numerical methods make it possible to apply simulations to industrial design concepts. The employed approach is based on the Lagrangian Smoothed Particle Hydrodynamics (SPH) method.

The backward flow of the hot burned gas surrounding a diesel flame was found to be one of the factors dominating the set-off length (also called the lift-off length), that is, the distance from a nozzle exit into which a diffusion flame cannot intrude. In the combustion chamber of an actual diesel engine, the entrainment of the surrounding gas into a spray jet from a multi-hole nozzle is restricted by the walls and adjacent spray jets, which induces the backward flow of the surrounding gas. A new momentum theory to calculate the backward flow velocity was established by extending Wakuri's momentum theory. Shadowgraph imaging in an optical engine successfully visualized the backward flow of the hot burned gas.

This paper presents a newly developed quasi-dimensional multi-zone dual fuel combustion model, which has been integrated within the commercial engine system simulation framework. Model is based on the modified Multi-Zone Combustion Model and Fractal Combustion Model. Modified Multi-Zone Combustion Model handles the part of the combustion process that is governed by the mixing-controlled combustion, while the modified Fractal Combustion Model handles the part that is governed by the flame propagation through the combustion chamber. The developed quasi-dimensional dual fuel combustion model features phenomenological description of spray processes, i.e. liquid spray break-up, fresh charge entrainment, droplet heat-up and evaporation process. In order to capture the chemical effects on the ignition delay, special ignition delay table has been made.

Nowadays, detailed kinetics is necessary for a proper estimation of both flame structure and pollutant formation in compression ignition engines. However, large mechanisms and the need to include turbulence/chemistry interaction introduce significant computational overheads. For this reason, tabulated kinetics is employed as a possible solution to reduce the CPU time even if table discretization is generally limited by memory occupation. In this work the authors applied tabulated homogeneous reactors (HR) in combination with different turbulent-chemistry interaction approaches to model non-premixed turbulent combustion. The proposed methodologies represent good compromises between accuracy, required memory and computational time. The experimental validation was carried out by considering both constant-volume vessel and Diesel engine experiments.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

NOx and PM are the critical emissions to meet the legislation limits for diesel engines. Often a value for these emissions is needed online for on-board diagnostics, engine control, exhaust aftertreatment control, model-based controller design or model-in-the-loop simulations. Besides the obvious method of measuring these emissions, a sensible alternative is to estimate them with virtual sensors. A lot of literature can be found presenting different modeling approaches for NOx emissions. Some are very close to the physics and the chemical reactions taking place inside the combustion chamber, others are only given by adapting general functions to measurement data. Hence, generally speaking, there is not a certain method which is seen as the solution for modeling emissions. Finding the best model approach is not straightforward and depends on the model application, the available measurement channels and the available data set for calibration.

This study deals with the experimental investigation of the mechanical properties of a lithium-ion pouch cell and its modelling in an explicit finite element simulation code. One can distinguish between ‘macroscopic’ and ‘microscopic’ modelling approaches. In the ‘macroscopic’ approach, one material model approximates the behaviour of multiple inner cell layers. In the ‘microscopic’ approach, which is used in the present study, all layers and their interactions are modelled separately. The cell under study is a pouch-type lithium-ion cell with a liquid electrolyte. With its cell chemistry, design, size and capacity it is usable for automotive applications and can be assembled into traction batteries. One cell sample was fully discharged and disassembled, and its components (anode, cathode, separator and pouch) were examined and measured by electron microscopy. Components were also tensile tested.

The continuously decreasing emission limits lead to a growing importance of exhaust aftertreatment in Diesel engines. Hence, methods for achieving a rapid catalyst light-off after engine cold start and for maintaining the catalyst temperature during low load operation will become more and more necessary. The present work evaluates several valve timing strategies concerning their ability for doing so. For this purpose, simulations as well as experimental investigations were conducted. A special focus of simulation was on pointing out the relevance of exhaust temperature, mass flow and enthalpy for these thermomanagement tasks. An increase of exhaust temperature is beneficial for both catalyst heat-up and maintaining catalyst temperature. In case of the exhaust mass flow, high values are advantageous only in case of a catalyst heat-up process, while maintaining catalyst temperature is supported by a low mass flow.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

The flow field resulting from injecting a gas jet into a crossflow confined in a narrow square duct has been studied under steady regime using schlieren imaging and laser Doppler velocimetry (LDV). This transparent duct is intended to simulate the intake port of an internal combustion engine fueled by gaseous mixture, and the jet is issued from a round nozzle. The schlieren images show that the relative small size of the duct would confine the development of the transverse jet, and the interaction among jet and sidewalls strongly influences the mixing process between jet and crossflow. The mean velocity and turbulence fields have been studied in detail through LDV measurements, at both center plane and several cross sections. The well-known flow feature formed by a counter rotating vortex pair (CVP) has been observed, which starts to appear at the jet exit section and persists far downstream contributing to enhancing mixing process.

Particulate emission reduction has long been a challenge for diesel engines as the diesel diffusion combustion process can generate high levels of soot which is one of the main constituents of particulate matter. Gasoline engines use a pre-mixed combustion process which produces negligible levels of soot, so particulate emissions have not been an issue for gasoline engines, particularly with modern port fuel injected (PFI) engines which provide excellent mixture quality. Future European and US emissions standards will include more stringent particulate limits for gasoline engines to protect against increases in airborne particulate levels due to the more widespread use of gasoline direct injection (GDI). While GDI engines are typically more efficient than PFI engines, they emit higher particulate levels, but still meet the current particulate standards.

This paper is focused on the development and application of a CFD methodology that can be applied to predict the fuel-air mixing process in stratified charge, sparkignition engines. The Eulerian-Lagrangian approach was used to model the spray evolution together with a liquid film model that properly takes into account its effects on the fuel-air mixing process into account. However, numerical simulation of stratified combustion in SI engines is a very challenging task for CFD modeling, due to the complex interaction of different physical phenomena involving turbulent, reacting and multiphase flows evolving inside a moving geometry. Hence, for a proper assessment of the different sub-models involved a detailed set of experimental optical data is required. To this end, a large experimental database was built by the authors.

Waste heat from a heavy-duty truck diesel engine is analyzed employing the first and second law of thermodynamics. A hybrid energy system is proposed, with the diesel cycle being hybridized with an organic Rankine cycle for waste heat recovery (ORC-WHR). The charge air cooler and EGR cooler(s) are integrated in the ORC loop as pre-heaters and the ORC working fluid serves as the coolant for these coolers. A supercritical reciprocating Rankine engine is proposed, which avoids using the high-cost evaporator and is easier for the system packaging. It is demonstrated in a case study that up to 20 % of waste heat from the heavy-duty diesel engine may be recovered by the supercritical ORC-WHR system, making the efficiency for the hybrid energy system be ≥ 50%. Discussion on working fluids for the WHR-ORC system is covered in Part II of this paper.

In Part I of this paper, the organic Rankine cycle for waste heat recovery (ORC-WHR) from the heavy-duty diesel truck engines was discussed. This work is Part II of the paper. The efficiency of the ORC-WHR system varies considerably with thermodynamic properties of the working fluid. In this work, characteristics of candidate working fluids are discussed on the basis of the thermodynamic theory. The discussion covers inorganic and organic fluids for both pure fluids and binary-mixture fluids. On the basis of the characteristics of the working fluids, the thermal efficiency for the ORC-WHR system is analyzed. Discussions and conclusions of this paper are helpful in selecting proper working fluids for the ORC-WHR system and determining a proper temperature range for system operations.