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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

High pressure diesel sprays were visualized under vaporizing and combusting conditions in a constant-volume combustion vessel. Near-simultaneous visualization of vapor and liquid phase fuel distribution were acquired using a hybrid shadowgraph/Mie-scattering imaging setup. This imaging technique used two pulsed LED's operating in an alternative manner to provide proper light sources for both shadowgraph and Mie scattering. In addition, combustion cases under the same ambient conditions were visualized through high-speed combustion luminosity measurement. Two single-hole diesel injectors with same nozzle diameters (100μm) but different k-factors (k0 and k1.5) were tested in this study. Detailed analysis based on spray penetration rate curves, rate of injection measurements, combustion indicators and 1D model comparison have been performed.

In the present paper, two different methodologies are adopted and critically integrated to analyze the knock behavior of a last generation small size spark ignition (SI) turbocharged VVA engine. Particularly, two full load operating points are selected, exhibiting relevant differences in terms of knock proximity. On one side, a knock investigation is carried out by means of an Auto-Regressive technique (AR model) to process experimental in-cylinder pressure signals. This mathematical procedure is used to estimate the statistical distribution of knocking cycles and provide a validation of the following 1D-3D knock investigations. On the other side, an integrated numerical approach is set up, based on the synergic use of 1D and 3D simulation tools. The 1D engine model is developed within the commercial software GT-Power™. It is used to provide time-varying boundary conditions (BCs) for the 3D code, Star-CD™.

The easiest way to identify knock conditions during the operation of a SI engine is represented by the knowledge of the in-cylinder pressure. Traditional techniques like MAPO (Maximum Amplitude Pressure Oscillation) based method rely on the frequency domain processing of the pressure data. This technique may present uncertainties due to the correct specification of some model parameters, like the band-pass frequency range and the crank angle window of interest. In this paper two innovative techniques for knock detection, which make use of the in-cylinder pressure, are explained in detail, and the results are compared with those coming from the MAPO method. The first procedure is based on the use of statistical analysis by applying an Auto Regressive (AR) technique, while the second technique makes use of the Discrete Wavelet Transform (DWT). The data useful for the analysis have been acquired on a high compression ratio four cylinder, spark ignition engine.

In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.

In recent years, the increase of gasoline fuel injection pressure is a way to improve thermal efficiency and lower engine-out emissions in GDI homogenous combustion concept. The challenge of controlling particulate formation as well in mass and number concentrations imposed by emissions regulations can be pursued improving the mixture preparation process and avoiding mixture inhomogeneity with ultra-high injection pressure values up to 100 MPa. The increase of the fuel injection pressure in GDI homogeneous systems meets the demand for increased injector static flow, while simultaneously improves the spray atomization and mixing characteristics with consequent better combustion performance. Few studies quantify the effects of high injection pressure on transient gasoline spray evolution. The aim of this work was to simulate with OpenFOAM the spray morphology of a commercial gasoline injected in a constant volume vessel by a prototypal GDI injector.

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

The common realization of the necessity to reduce the use of mineral sources is promoting the use of alternative fuels. Big efforts are being made to replace petroleum derivatives in the internal combustion engines (ICEs). For this purpose it is mandatory to evaluate the behavior of non-conventional fuels in the ICEs. The optical diagnostics have proven to be a powerful tool to analyze the processes that take place inside the engine. In particular, 2d imaging in the infrared range can reveal new details about the effect of the fuel properties since this technique is still not very common. In this work, a comparison between commercial diesel fuel and two non-conventional fuels has been made in an optically accessible diesel engine. The non-conventional fuels are: the first generation biofuel Rapeseed Methyl Ester (RME) and an experimental blend of diesel and a fuel with high glycerol content (HG).

In this paper, a high performance V12 spark-ignition engine is experimentally investigated at test-bench in order to fully characterize its behavior in terms of both average parameters, cycle-by-cycle variations and knock tendency, for different operating conditions. In particular, for each considered operating point, a spark advance sweep is actuated, starting from a knock-free calibration, up to intense knock operation. Sequences of 300 consecutive pressure cycles are measured for each cylinder, together with the main overall engine performance, including fuel flow, torque, and fuel consumption. Acquired data are statistically analyzed to derive the distributions of main indicated parameters, in order to find proper correlations with ensemble-averaged quantities. In particular, the Coefficient of Variation (CoV) of IMEP and of the in-cylinder peak pressure (pmax) are correlated to the average combustion phasing and duration (MFB50 and Δθb), with a good coefficient of determination.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

The modeling of fuel sprays under well-characterized conditions relevant for heavy-duty Diesel engine applications, allows for detailed analyses of individual phenomena aimed at improving emission formation and fuel consumption. However, the complexity of a reacting fuel spray under heavy-duty conditions currently prohibits direct simulation. Using a systematic approach, we extrapolate available spray models to the desired conditions without inclusion of chemical reactions. For validation, experimental techniques are utilized to characterize inert sprays of n-dodecane in a high-pressure, high-temperature (900 K) constant volume vessel with full optical access. The liquid fuel spray is studied using high-speed diffused back-illumination for conditions with different densities (22.8 and 40 kg/m3) and injection pressures (150, 80 and 160 MPa), using a 0.205-mm orifice diameter nozzle.

Knock occurrence and fuel enrichment, which is required at high engine speed and load to limit the turbine inlet temperature, are the major obstacles to further increase performance and efficiency of down-sized turbocharged spark ignited engines. A technique that has the potential to overcome these restrictions is based on the injection of a precise amount of water within the mixture charge that can allow to achieve important benefits on knock mitigation, engine efficiency, gaseous and noise emissions. One of the main objectives of this investigation is to demonstrate that water injection (WI) could be a reliable solution to advance the spark timing and make the engine run at leaner mixture ratios with strong benefits on knock tendency and important improvement on fuel efficiency.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Isooctane sprays from a multi-hole GDI injector were investigated in a constant volume chamber by means of high speed imaging techniques. The tests were performed under inert conditions (nitrogen), at temperatures and densities ranging between representative operating conditions of late injection, flash boiling and early injection in a GDI engine. The global parameters of the sprays were obtained by processing Schlieren, Shadowgraph, DBI and Mie-scattering images through an in-house image processing method. Thus, the boundaries of the spray vapor phase can be easily detected with great accuracy, regardless of whether Schlieren or the less sensitive shadowgraph imaging is used. Furthermore, the boundaries of the liquid phase were also obtained from shadowgraph images and compared with those obtained through DBI and scattering. The results show that the signature of the liquid phase in a shadowgraph image can be distinguished from that of the vaporized fuel.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Today, Direct-Injection systems are widely used on Spark-Ignition engines in combination with turbo-charging to reduce the fuel-consumption and the knock risks. In particular, the spread of Gasoline Direct Injection (GDI) systems is mainly related to the use of new generations of multi-hole, high-pressure injectors whose characteristics are quite different with respect to the hollow-cone, low-pressure injectors adopted in the last decade. This paper presents the results of an experimental campaign conducted on the spray produced by a GDI six-holes injector into a constant volume vessel with optical access. The vessel was filled with air at atmospheric pressure. Different operating conditions were considered for an injection pressure ranging from 3 to 20 MPa. For each operating condition, spray images were acquired by a CCD camera and then post processed to evaluate the spray penetration and cone angles.

Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.

An experimental campaign was carried out to evaluate the influence of CNG and gasoline on the exhaust emissions and fuel consumption of a bi-fuel passenger car over on-road tests performed in the city of Naples. The chosen route is very traffic congested during the daytime of experimental measurements. An on-board analyzer was used to measure CO, CO2, NOx tailpipe concentrations and the exhaust flow rate. Throughout a carbon balance on the exhaust pollutants, the fuel consumption was estimated. The exact spatial position was acquired by a GPS which allowed to calculate vehicle speed and the traffic condition was monitored by a video camera. Whole trip realized by the vehicle was subdivided in succession of kinematic sequences and the vehicle emissions and fuel consumption were analyzed and presented as value on each kinematic sequence. Moreover, throughout a multivariate statistical analysis of sequences, the driving cycles characterizing the use of vehicle were identified.

The flow field resulting from injecting a gas jet into a crossflow confined in a narrow square duct has been studied under steady regime using schlieren imaging and laser Doppler velocimetry (LDV). This transparent duct is intended to simulate the intake port of an internal combustion engine fueled by gaseous mixture, and the jet is issued from a round nozzle. The schlieren images show that the relative small size of the duct would confine the development of the transverse jet, and the interaction among jet and sidewalls strongly influences the mixing process between jet and crossflow. The mean velocity and turbulence fields have been studied in detail through LDV measurements, at both center plane and several cross sections. The well-known flow feature formed by a counter rotating vortex pair (CVP) has been observed, which starts to appear at the jet exit section and persists far downstream contributing to enhancing mixing process.

The aim of this paper is the experimental investigation of the effect of direct fuel injection on the combustion process and pollutant formation in a spark ignition (SI) two-wheel engine. The engine is a 250cc single cylinder, four-stroke spark-ignition firstly equipped with a four-valve PFI head and then with GDI one operating with European commercial gasoline and Bio-ethanol. It is equipped with a wide sapphire window in the bottom of the chamber and quartz cylinder. In the combustion chamber, optical techniques based on 2D-digital imaging were used to follow the injection and flame propagation and spectroscopic measurements were carried out in order to evaluate the main radical species. Radical species such as OH and CH were detected and used to follow the chemical phenomena related to the fuel quality. Measurements were carried out at different engine speeds and combustion strategies based on different injection pressures.