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Premixed Charge Compression Ignition (PCCI), a Low Temperature Combustion (LTC) strategy for diesel engines is of increasing interest due to its potential to simultaneously reduce soot and NOx emissions. However, the influence of mixture preparation on combustion phasing and heat release rate in LTC is not fully understood. In the present study, the influence of injection timing on mixture preparation, combustion and emissions in PCCI mode is investigated by experimental and computational methods. A sequential coupling approach of 3D CFD with a Stochastic Reactor Model (SRM) is used to simulate the PCCI engine. The SRM accounts for detailed chemical kinetics, convective heat transfer and turbulent micro-mixing. In this integrated approach, the temperature-equivalence ratio statistics obtained using KIVA 3V are mapped onto the stochastic particle ensemble used in the SRM.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

Fundamental understanding of the sources of fuel-derived Unburned Hydrocarbon (UHC) emissions in heavy duty diesel engines is a key piece of knowledge that impacts engine combustion system development. Current emissions regulations for hydrocarbons can be difficult to meet in-cylinder and thus after treatment technologies such as oxidation catalysts are typically used, which can be costly. In this work, Computational Fluid Dynamics (CFD) simulations are combined with engine experiments in an effort to build an understanding of hydrocarbon sources. In the experiments, the combustion system design was varied through injector style, injector rate shape, combustion chamber geometry, and calibration, to study the impact on UHC emissions from mixing-controlled diesel combustion.

On-road comparisons were made between a federal reference method mobile emissions laboratory (MEL) and a portable emissions measurement system (PEMS) to support validation of the engine “Not To Exceed” (NTE) emissions design and to evaluate the accuracy of PEMS. Three different brake specific emissions calculation equations (methods) were used as part of this research, with method one directly using engine speed and torque, and methods two and three including ECM fuel consumption and carbon balance fuel consumption. The brake specific NOx emissions for the particular PEMS unit utilized in this program were consistently higher than those for the MEL. The brake specific (bs) NOx NTE deltas were +0.63±0.31 g/kW-h (0.47±0.23 g/hp-h), +0.55±0.17 g/kW-h (0.41±0.13 g/hp-h), and +0.54±0.17g/kW-h (0.40±0.13g/hp-h) for methods one, two, and three respectively.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

Low-temperature combustion of diesel fuel was studied in a heavy-duty, single-cylinder, optical engine employing a 15-hole, dual-row, narrow-included-angle nozzle (10 holes × 70° and 5 holes × 35°) with 103-μm-diameter orifices. This nozzle configuration provided the spray targeting necessary to contain the direct-injected diesel fuel within the piston bowl for injection timings as early as 70° before top dead center. Spray-visualization movies, acquired using a high-speed camera, show that impingement of liquid fuel on the piston surface can result when the in-cylinder temperature and density at the time of injection are sufficiently low. Seven single- and two-parameter sweeps around a 4.82-bar gross indicated mean effective pressure load point were performed to map the sensitivity of the combustion and emissions to variations in injection timing, injection pressure, equivalence ratio, simulated exhaust-gas recirculation, intake temperature, intake boost pressure, and load.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

Ducted fuel injection (DFI) is a developing technology for reducing in-cylinder soot formed during mixing-controlled combustion in diesel compression ignition engines. Fuel injection through a small duct has the effect of extending the lift-off length (LOL) and reducing the equivalence ratio at ignition. In this work, the feasibility of DFI to reduce soot and to enable leaner lifted-flame combustion (LLFC) is investigated for a single diesel jet injected from a 138 μm orifice into engine-like (60-120 bar, 800-950 K) quiescent conditions. High-speed imaging and natural luminosity (NL) measurements of combusting sprays were used to quantify duct effects on jet penetration, ignition delay, LOL, and soot emission in a constant pressure high-temperature-pressure vessel (HTPV). At the highest ambient pressure and temperatures tested, soot luminosity was reduced by as much as 50%.

Fuel is a significant portion of the operating cost for an on-highway diesel engine and fuel economy is important to the economics of shipping most goods in North America. Cat® ACERT™ engine technology is no exception. Ball bearings have been applied to the series turbochargers for the Caterpillar heavy-duty, on-highway diesel truck engines in order to reduce mechanical loss for improved efficiency and lower fuel consumption. Over many years of turbocharger development, much effort has been put into improving the aerodynamic efficiency of the compressor and turbine stages. Over the same span of time, the mechanical bearing losses of a turbocharger have not experienced a significant reduction in power consumption. Most turbochargers continue to use conventional hydrodynamic radial and thrust bearings to support the rotor. While these conventional bearings provide a low cost solution, they do create significant mechanical loss.

Since the advent of P/M technology as a near net shape production process, millions of mechanical components of various shapes and sizes have been produced. Although P/M continues to be one of the fast growing shaping processes, it suffers from the inability to produce intricate geometry's such as internal tapers, threads or recesses perpendicular to pressing direction. In such cases application of machining as a secondary forming operation becomes the preferred alternative. However, machining of P/M parts due to their inherent porosity is known to decrease tool life and increase tool chatter and vibration. Consequently, several attempts have been made to improve the machinability of P/M materials by either addition of machinability enhancing elements such as sulfur, calcium, tellurium, selenium, etc., or by resin impregnation of P/M parts.

Technical groups worldwide have been actively developing specifications and requirements for biodegradable hydraulic fluids for mobile applications. These groups have recognized that an industry-wide specification is necessary due to the increase in environmental awareness in the agriculture, construction, forestry, and mining industries, and to the increasing number of local regulations primarily throughout Europe. Caterpillar has responded to this need by publishing a requirement, Caterpillar BF-1, that may be used by Caterpillar dealers, customers, and industry to help select high-performance biodegradable hydraulic fluids. This requirement was written with the input of several organizations that are known to be involved with the development of similar types of specifications and requirements.

Homogeneous charge compression ignition (HCCI) offers the potential for significant improvements in efficiency with a substantial reduction in emissions. However, achieving heavy-duty (HD) HCCI engine operation at practical loads and speeds presents numerous technical challenges. Successful expansion of the HCCI operating range to include the full range of load and speed must be accomplished while maintaining proper combustion phasing, control of maximum cylinder pressure and pressure rise rates, and low emissions of NOx and particulate matter (PM). Significant progress in this endeavour has been made through a collaborative research effort between Caterpillar and ExxonMobil. This paper evaluates fuel effects on HCCI engine operating range and emissions. Test fuels were developed in the gasoline and diesel boiling range covering a broad range of ignition quality, fuel chemistry, and volatility.

The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.

Past experiments have shown that numerous micro-hole sprays in close proximity produce drop sizes that are sensitive to the nozzle arrangement. Numerical studies have been performed to identify the interaction mechanisms between closely spaced sprays. It is shown that nozzle configurations can lower the drop-gas relative velocity and droplet Weber number, leading to reduced atomization intensity. However, the collisions involving droplets from neighboring sprays have a much greater effect on droplet size. Thus, neighboring sprays primarily interfere with each other through droplet collision.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

Increasingly, the exchanges of data in complex ECM (Electronic Control Module) systems rely on multiple communication networks across various physical and network layers. This has greatly increased system flexibility and provided an excellent medium to create well-defined exchangeable interfaces between components; however this added flexibility comes with increased network complexity. A system-level approach allows for the optimization of data exchange and network configuration as well as the development of a comprehensive network failure strategy. Many current ECM systems utilize complex multi-network communication strategies to exchange and control data to components. Recently, Caterpillar implemented an HIL (Hardware-In-the-Loop) test system that provides an approach for developing and testing a comprehensive ECM network strategy.

Hybrid vehicle engines modified for high exhaust gas recirculation (EGR) are a good choice for high efficiency and low NOx emissions. Such operation can result in an HEV when a downsized engine is used at high load for a large fraction of its run time to recharge the battery or provide acceleration assist. However, high EGR will dilute the engine charge and may cause serious performance problems such as incomplete combustion, torque fluctuation, and engine misfire. An efficient way to overcome these drawbacks is to intensify tumble leading to increased turbulent intensity at the time of ignition. The enhancement of turbulent intensity will increase flame velocity and improve combustion quality, therefore increasing engine tolerance to higher EGR. It is accepted that the detailed experimental characterization of flow field near top dead center (TDC) in an engine environment is no longer practical and cost effective.

Analyzing the combustion characteristics, engine performance, and emissions pathways of the internal combustion (IC) engine requires management of complex and an increasing quantity of data. With this in mind, effective management to deliver increased knowledge from these data over shorter timescales is a priority for development engineers. This paper describes how this can be achieved by combining conventional engine research methods with the latest developments in process informatics and statistical analysis. Process informatics enables engineers to combine data, instrumental and application models to carry out automated model development including optimization and validation against large data repositories of experimental data.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

The NOx reduction performance under lean conditions over γ-alumina was evaluated using a micro-reactor system and a non-thermal plasma-equipped bench test system. Various alumina samples were obtained from alumina manufacturers to assess commercial alumina materials. In addition, γ-alumina samples were synthesized at Caterpillar with a sol-gel technique in order to control alumina properties. The deNOx performances of the alumina samples were compared. The alumina samples were characterized with analytical techniques such as inductively coupled plasma (ICP) emission spectroscopy, temperature programmed desorption (TPD) and surface area measurements (BET) to understand physical and chemical properties. The information derived from these techniques was correlated with the NOx reduction performance to identify key parameters of γ-alumina for optimizing materials for lean-NOx and plasma assisted catalysis.