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The evaluation of vehicles real emissions circulating in urban areas is a basic activity for planning and management of implemented traffic measures aiming at emission control and air quality improvement. National, region, and city emission inventories require overall average emission estimation based on modeling technique with a few input parameters such as fleet composition and mission profile, represented by average speed. But in the field of emission modeling an important open issue is the very expensive costs of experimental campaigns needed to obtain driving cycle statistically representative of driving behavior, also if only in a specific link of a network. A possible approach to deal with this problem is represented by the use of traffic microscopic simulation models which are capable to simulate individual car motion on the basis of traffic conditions, road characteristics and management rules.

A plasma ignition system was tested in a GDI engine with the target of combustion efficiency improvement without modifying engine configuration. The plasma was generated by spark discharge and successively sustained to enhance its duration up to 4 ms. The innovative ignition system was tested in an optically accessible single-cylinder DISI engine to investigate the effects of plasma on kernel stability and flame front propagation under low loads and lean mixture (λ≅1.3). The engine was equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio). All experiments were performed at 2000 rpm and 100 bar injection pressure. UV-visible 2D chemiluminescence was applied in order to study the flame front inception and propagation with particular interest in the early combustion stages. A bandpass filter allowed selecting luminous signal due to OH radicals.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

The present work relates to the investigation of the basic oxidation characteristics of iron and aluminium nanoparticles as well as the feasibility of their combustion under both Internal Combustion Engine (ICE)-like and real engine conditions. Based on a series of proof-of-concept experiments, combustion was found to be feasible taking place in a controllable way and bearing similarities to the respective case of conventional fuels. These studies were complimented by relevant in-situ and ex-situ/post-analysis, in order to elaborate the fundamental phenomena occurring during combustion as well as the extent and ‘quality’ of the process. The oxidation mechanisms of the two metallic fuels appear different and -as expected- the energy release during combustion of aluminium is significantly higher than that released in the case of iron.

In the last ten years, the number of natural gas vehicles worldwide has grown rapidly with the biggest contribution coming from the Asia-Pacific and Latin America regions. As natural gas is the cleanest fossil fuel, the exhaust emissions from natural gas spark ignition vehicles are lower than those of gasoline powered vehicles. Moreover, natural gas is less affected by price fluctuations and its resources are more evenly widespread over the globe than to oil. However, as natural gas vehicles are usually bi-fuel gasoline and natural gas, the excellent knock resistant characteristics of natural gas cannot be completely exploited. This paper shows the results of an experimental activity performed on a passenger car fuelled alternatively by gasoline and compressed natural gas (CNG). The vehicle has been tested on a chassis dynamometer over standard (NEDC) and real driving cycles (Artemis CADC), allowing to investigate a wide range of operating conditions.

The present paper describes the results of a cooperative research project between GM Powertrain Europe and Istituto Motori - CNR aimed at studying the capability of GM Combustion Closed-Loop Control (CLCC) in enabling seamless operation with high biodiesel blending levels in a modern diesel engine for passenger car applications. As a matter of fact, fuelling modern electronically-controlled diesel engines with high blends of biodiesel leads to a performance reduction of about 12-15% at rated power and up to 30% in the low-end torque, while increasing significantly the engine-out NOx emissions. These effects are both due to the interaction of the biodiesel properties with the control logic of the electronic control unit, which is calibrated for diesel operation. However, as the authors previously demonstrated, if engine calibration is re-tuned for biodiesel fuelling, the above mentioned drawbacks can be compensated and the biodiesel environmental inner qualities can be fully deployed.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

An experimental campaign was carried out to evaluate the influence of CNG and gasoline on the exhaust emissions and fuel consumption of a bi-fuel passenger car over on-road tests performed in the city of Naples. The chosen route is very traffic congested during the daytime of experimental measurements. An on-board analyzer was used to measure CO, CO2, NOx tailpipe concentrations and the exhaust flow rate. Throughout a carbon balance on the exhaust pollutants, the fuel consumption was estimated. The exact spatial position was acquired by a GPS which allowed to calculate vehicle speed and the traffic condition was monitored by a video camera. Whole trip realized by the vehicle was subdivided in succession of kinematic sequences and the vehicle emissions and fuel consumption were analyzed and presented as value on each kinematic sequence. Moreover, throughout a multivariate statistical analysis of sequences, the driving cycles characterizing the use of vehicle were identified.

With concerns continuing to grow with respect to global warming from greenhouse gases, further regulations are being examined, developed and are expected for the emission of CO2 as an automobile exhaust. Renewable alternate fuels offer the potential to significantly reduce the CO2 impact of transportation. Hydrogen as a spark - ignition (SI) engine fuel provides this potential for significant CO2 reduction when generated from renewable resources. In addition, hydrogen has advantageous combustion properties including a wide flammable mixture range which facilitates lean burning and high dilution, fast combustion energy release and zero CO2 emissions. However, the high burning rates and fast energy release can lead to excessive in-cylinder pressures and temperatures resulting in combustion knock and high NOx emissions at stoichiometric operation.

In this paper, a Low Temperature Premixed Combustion (LTPC) was investigated employing a four cylinder D.I. common rail Diesel engine, used for passenger cars on the European market. Experiments were carried out setting the engine speed at 2500 rpm with a fuel amount of 26 mg/str to realize an operating condition close to the point of NEDC at 0.8 MPa of BMEP. The experimental approach was the management of the start of injection, injection pressure and EGR rates as a method to control NOx and soot production. The investigation was first carried out testing engine performances and emissions as set from the commercial engine map. Afterward, engine tests were carried out exploring performances, gaseous and smoke emissions at late start of combustion [10 to 17.5 cad ATDC], injection pressures from 80 to 120 MPa and EGR rates up to 50%.

Hybrid vehicle engines modified for high exhaust gas recirculation (EGR) are a good choice for high efficiency and low NOx emissions. Such operation can result in an HEV when a downsized engine is used at high load for a large fraction of its run time to recharge the battery or provide acceleration assist. However, high EGR will dilute the engine charge and may cause serious performance problems such as incomplete combustion, torque fluctuation, and engine misfire. An efficient way to overcome these drawbacks is to intensify tumble leading to increased turbulent intensity at the time of ignition. The enhancement of turbulent intensity will increase flame velocity and improve combustion quality, therefore increasing engine tolerance to higher EGR. It is accepted that the detailed experimental characterization of flow field near top dead center (TDC) in an engine environment is no longer practical and cost effective.

Idle Speed Control plays a crucial role to reduce fuel consumption that turns in both a direct economic benefit for customers and CO\d reduction particularly important to tackle the progressive global environmental warming. Typically, control strategies available in the automotive literature solve the idle speed control problem acting both on the throttle position and the spark advance, while the Air-Fuel Ratio (AFR), that strongly affects the indicated engine torque, is kept at the stoichiometric value for the sake of emission reduction. Gasoline Direct Injection (GDI) engines, working lean and equipped with proper mechanisms to reduce NOx emissions, overcome this limitation allowing the AFR to be used for the idle speed regulation.

A one-dimensional model simulating the oxidation of CO, HC, and NO was developed to predict the gaseous emissions downstream of a diesel oxidation catalyst (DOC). The model is based on the conservation of mass, species, and energy inside the DOC and draws on past research literature. Steady-state experiments covering a wide range of operating conditions (exhaust temperatures, flow rates and gaseous emissions) were performed, and the data were used to calibrate and validate the model. NO conversion efficiencies of 50% or higher were obtained at temperatures between 300°C and 350°C. CO conversion efficiencies of 85% or higher and HC conversion efficiencies of 75% or higher were found at every steady state condition above 200°C. The model agrees well with the experimental results at temperatures from 200°C to 500°C, and volumetric flow rates from 8 to 42 actual m3/min.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

A study was conducted to assess the effects of a water-diesel fuel emulsion with and without an oxidation catalytic converter (OCC) on steady-state heavy-duty diesel engine emissions. Two OCCs with different metal loading levels were used in this study. A 1988 Cummins L10-300 heavy-duty diesel engine was operated at the rated speed of 1900 rpm and at 75% and 25% load conditions (EPA modes 9 and 11 respectively) of the 13 mode steady-state test as well as at idle. Raw exhaust emissions' measurements included total hydrocarbons (HC), oxides of nitrogen (NOx) and nitric oxide (NO). Diluted exhaust measurements included total particulate matter (TPM) and its primary constituents, the soluble organic (SOF), sulfate (SO42-) and the carbonaceous solids (SOL) fractions. Vapor phase organic compounds (XOC) were also analyzed. The SOF and XOC samples were analyzed for selected polynuclear aromatic hydrocarbons (PAHs).

The NOx reduction performance under lean conditions over γ-alumina was evaluated using a micro-reactor system and a non-thermal plasma-equipped bench test system. Various alumina samples were obtained from alumina manufacturers to assess commercial alumina materials. In addition, γ-alumina samples were synthesized at Caterpillar with a sol-gel technique in order to control alumina properties. The deNOx performances of the alumina samples were compared. The alumina samples were characterized with analytical techniques such as inductively coupled plasma (ICP) emission spectroscopy, temperature programmed desorption (TPD) and surface area measurements (BET) to understand physical and chemical properties. The information derived from these techniques was correlated with the NOx reduction performance to identify key parameters of γ-alumina for optimizing materials for lean-NOx and plasma assisted catalysis.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

A two-zone NOx model intended for 1-D engine simulations was developed and used to model NOx emissions from a 2.5 L single-cylinder engine. The intent of the present work is to understand key aspects of a simple NOx model that are needed for predictive accuracy, including NOx formation and destruction phenomena in a DI Diesel combustion system. The presented two-zone model is fundamentally based on the heat release rate and thermodynamic incylinder data, and uses the Extended Zeldovich mechanism to model NO. Results show that the model responded very well to changes in speed, load, injection timing, and EGR level. It matched measured tail pipe NOx levels within 20%, using a single tuning setup. When the model was applied to varied injection rate shapes, it showed correct sensitivity to speed, load, injection timing, and EGR level, but the absolute level was well outside the target accuracy. The same limitation was seen when applying the Plee NOx model.