Search Results

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.

The topic of CO₂ and fuel consumption reductions from vehicles is a very broad and complex issue, encompassing vehicle regulations, biofuel mandates, and a vast assortment of engine and vehicle technologies. This paper attempts to provide a high-level review of all these issues. Reducing fuel consumption appears not to be driven by the amount of hydrocarbon reserves, but by energy security and climate change issues. Regarding the latter, a plan was proposed by the United Nations for upwards of 80% CO₂ reductions from 1990 levels by 2050. Regulators are beginning to respond by requiring ~25% reductions in CO₂ emissions from light-duty vehicles by 2016 in major world markets, with more to come. The heavy-duty sector is poised to follow. Similarly, fuel policy is aimed at energy diversity (security) and climate change impacts. Emerging biofuel mandates require nominally 5-10% CO₂ life cycle emissions reductions by 2020.

India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).

This review paper summarizes major developments in vehicular emissions regulations and technologies from 2014. The paper starts with the key regulatory advancements in the field, including newly proposed Non-Road Mobile Machinery regulations for 2019-20 in Europe, and the continuing developments towards real driving emissions (RDE) standards. An expert panel in India proposed a roadmap through 2025 for clean fuels and tailpipe regulations. LD (light duty) and HD (heavy-duty) engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are demonstrating more than 50% brake thermal efficiency using methods that can reasonably be commercialized. Next, NOx control technologies are summarized, including SCR (selective catalytic reduction), lean NOx traps, and combination systems. Emphasis is on durability and control.

This review paper summarizes major and representative developments in vehicular emissions regulations and technologies from 2015. The paper starts with the key regulatory advancements in the field, including newly proposed Euro 6 type regulations for Beijing, China, and India in the 2017-20 timeframe. Europe is continuing developments towards real driving emissions (RDE) standards with the conformity factors for light-duty diesel NOx ramping down to 1.5X by 2021. The California heavy duty (HD) low-NOx regulation is advancing and may be proposed in 2017/18 for implementation in 2023+. LD (light duty) and HD engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas regulations. LD gasoline concepts are achieving 45% BTE (brake thermal efficiency or net amount of fuel energy gong to the crankshaft) and closing the gap with diesel.

A production calibrated GTDI 1.6L Ford Fusion was used to demonstrate low HC, CO, NOx, PM (particulate mass), and PN (particulate number) emissions using advanced catalyst technologies with newly developed high porosity substrates and coated GPFs (gasoline particulate filters). The exhaust system consisted of 1.2 liters of TWC (three way catalyst) in the close-coupled position, and 1.6L of coated GPF in the underfloor position. The catalysts were engine-aged on a dynamometer to simulate 150K miles of road aging. Results indicate that ULEV70 emissions can be achieved at ∼$40 of PGM, while also demonstrating PM tailpipe performance far below the proposed California Air Resources Board (CARB) LEV III limit of 1 mg/mi. Along with PM and PN analysis, exhaust system backpressure is also presented with various GPF designs.

Diesel particle filters (DPF) have become a standard aftertreatment component for all current and future on-road diesel engines used in the US. In Europe the introduction of EUVI is expected to also result in the broad implementation of DPF's. The anticipated general trend in engine technology towards higher engine-out NOx/PM ratios results in a somewhat changing set of boundary conditions for the DPF predominantly enabling passive regeneration of the DPF. This enables the design of a novel filter concept optimized for low pressure drop, low thermal mass for optimized regeneration and fast heat-up of a downstream SCR system, therefore reducing CO₂ implications for the DPF operation. In this paper we will discuss results from a next-generation cordierite DPF designed to address these future needs.

This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2011. First, the paper covers the key regulatory developments in the field, including proposed criteria pollutant tightening in California; and in Europe, the newly proposed PN (particle number) regulation for direct injection gasoline engines, test cycle development, and in-use testing discussions. The proposed US LD (light-duty) greenhouse gas (GHG) regulation for 2017-25 is reviewed, as well as the finalized, first-ever, US HD (heavy-duty) GHG rule for 2014-17. The paper then gives a brief, high-level overview of key emissions developments in LD and HD engine technology, covering both gasoline and diesel. Emissions challenges include lean NOx remediation for diesel and lean-burn gasoline to meet both the emerging NOx and GHG regulations.

This review article summarizes major and representative developments in vehicle emissions regulations, engine efficiency, and emission control from 2017. The article starts with the key regulatory developments in the field, including newly proposed European light-duty (LD) CO2 regulations (15 and 30% cuts in 2025 and 2030, respectively, from 2020 levels) and technical improvements of the Euro 6 real driving emissions (RDE) regulations. China finalized their new energy vehicle (NEV) mandates for 2019 and 2020. LD and heavy-duty (HD) engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas (GHG) regulations. Several LD gasoline concepts are achieving 10-15% and some up to 35% reductions relative to gasoline direct injection (GDI) engines of today.

Gaseous and particle emissions from a gasoline direct injection (GDI) and a port fuel injection (PFI) vehicle were measured at various ambient temperatures (22°C, -7°C, -18°C). These vehicles were driven over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and 10% by volume ethanol (E10). Emissions were analyzed to determine the impact of ambient temperature on exhaust emissions over different driving conditions. Measurements on the GDI vehicle with a gasoline particulate filter (GPF) installed were also made to evaluate the GPF particle filtration efficiency at cold ambient temperatures. The GDI vehicle was found to have better fuel economy than the PFI vehicle at all test conditions. Reduction in ambient temperature increased the fuel consumption for both vehicles, with a much larger impact on the cold-start FTP-75 drive cycle observed than for the hot-start US06 drive cycle.

This study reports gaseous and particle (ultrafine and black carbon (BC)) emissions from a turbofan engine core on standard Jet A-1 and three alternative fuels, including 100% hydrothermolysis synthetic kerosene with aromatics (CH-SKA), 50% Hydro-processed Esters and Fatty Acid paraffinic kerosene (HEFA-SPK), and 100% Fischer Tropsch (FT-SPK). Gaseous emissions from this engine for various fuels were similar but significant differences in particle emissions were observed. During the idle condition, it was observed that the non-refractory mass fraction in the emitted particles were higher than during higher engine load condition. This observation is consistent for all test fuels. The 100% CH-SKA fuel was found to have noticeable reductions in BC emissions when compared to Jet A-1 by 28-38% by different BC instruments (and 7% in refractory particle number (PN) emissions) at take-off condition.

The exhaust emissions from small engines in general and marine engines in particular have come under scrutiny over the past few years as new exhaust emission regulations have been proposed and put into force. The standard method for exhaust emission sampling of outboard marine engines is to analyze raw exhaust in the exhaust manifold of the engine. In this study a total dilution sampling system for the gaseous emissions, similar to what is used for light and heavy duty vehicles and engines, and a separate water sampling method were used to evaluate the exhaust emissions from stock two and four stroke outboard marine engines.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

Gasoline-electric hybrid vehicle technology has been gaining widespread acceptance and has the potential to reduce emissions through reduced fuel consumption. In this study, particulate matter number and mass emission rates, organic and elemental carbon compositions, and number-based size distributions were measured from four gasoline-electric hybrid vehicles (2005 Ford Escape Hybrid, 2004 Toyota Prius, 2003 Honda Civic Hybrid, and 2000 Honda Insight). In addition, one small conventional gasoline vehicle (2002 SmartCar) was tested. The vehicles were driven over five driving cycles and at steady-state speeds of 40 and 80 km/h. Each test was performed at 20°C and at -18°C. Testing took place at the Environmental Science & Technology Centre of Environment Canada using conventional chassis dynamometer procedures. Average distance based emission rates are given for each vehicle under each test condition.

With stricter emissions standards, low back pressure requirements, and 100,000 mile durability specifications, ceramic catalysts have undergone significant developments over the past few years. The thrust in the ceramics area has centered on thin-wall structures to minimize back pressure and on high cell density for rapid light-off in close-coupled applications. The thin-wall structures are extruded from low expansion cordierite ceramic with adequate strength and thermal shock resistance equivalent to those of standard cordierite substrate. Examples of thin-wall substrate include 350XT which is extruded from a very low expansion dense cordierite ceramic, and 400/4 and 600/4 cell structures extruded from a low expansion modified cordierite ceramic. This paper will focus on the high fatigue resistance, excellent conversion efficiency, and low back pressure of 350 XT substrates with advanced washcoat system.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled “Clean Diesel Demonstration Program” has been initiated by NY City Transit under the supervision of NY State DEC and with active participation from several industrial partners. Under this program, several NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter system and are operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses are being evaluated over a 8-9 month period for operations, maintainability and durability of the particulate filter.

This paper gives a comprehensive overview of the current state-of-the-art in diesel emission control. The nature of diesel particulates is summarized. The variety of diesel particulate filter regeneration strategies that will become so important to filter application are reviewed. Filter retrofit and durability issues are addressed. DeNOx catalysts, SCR, NOx traps for diesel, and non-thermal plasma methods are summarized. Integrated NOx/PM systems are described. And reduction of exhaust toxics is discussed. The paper covers all major conferences in the year 2000 that occurred in the US and Europe. US and Europe.

To establish performance trends in ultra thin wall substrates and help support their selection criteria for designing catalytic converter systems, the light-off behavior of five Ultra Thin Wall ceramic substrates and two catalysts on an engine dynamometer are hereby examined. Modeling predictions are also compared to the engine results and the trends and implications are discussed. To quantify the performance of these different systems, light-off tests were performed on an engine dynamometer using a simulated FTP cycle. Five systems were evaluated (600/4, 600/3, 600/2, 900/2 and 1200/2) each with two different catalyst formulations. Engine bench aging was used to simulate typical aged conditions in the converter systems. Second by second emissions data for temperature, hydrocarbons and carbon monoxide, were used to evaluate the relative performances of the substrates.

In urban areas, particulate emission from diesel engines is one of the pollutants of most concern. As a result, particulate emission control from urban bus diesel engines using particle filter technology is being evaluated at several locations in the US. A project entitled, “Clean Diesel Vehicle Air Quality Project” has been initiated by NY City Transit under the supervision of NYSDEC and with active participation from several industry partners. Under this program, 25 NY City transit buses with DDC Series 50 engines have been equipped with continuously regenerating diesel particulate filter systems and have been operating with ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000. These buses were evaluated over a 9 month period for operations, maintainability and durability of the particulate filter.

To meet the future emission targets for Diesel engines, one trend is the use of Catalyzed Diesel Particulate Filters (CDPF). Catalyzing the filter, however, alters filter behavior. In particular, alteration in filter permeability imparts a significant change in the filter's performance. To understand the impact of the catalyst coating on a DPF, engine tests have been conducted to measure the pressure drop across DPFs with different catalyst coatings, cell densities, and soot loadings. The tests were performed over a range of engine speeds and loads, with a corresponding range in exhaust flow rates and temperatures. A pressure drop model based on previous work for uncatalyzed filters has been modified and validated for CDPFs. To achieve optimum design for DPF's, a parametric study comparing the influence of catalyst, cell density, wall thickness, filter length and diameter was done.