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An Experimental Analysis on Diesel/n-Butanol Blends Operating in Partial Premixed Combustion in a Light Duty Diesel Engine

2012-06-18
This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.
Journal Article

Removal of NOx from Diesel Exhausts: The New “Enhanced NH3-SCR” Reaction

2010-04-12
2010-01-1181
Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.
Journal Article

A Scale Adaptive Filtering Technique for Turbulence Modeling of Unsteady Flows in IC Engines

2015-04-14
2015-01-0395
Swirling flows are very dominant in applied technical problems, especially in IC engines, and their prediction requires rather sophisticated modeling. An adaptive low-pass filtering procedure for the modeled turbulent length and time scales is derived and applied to Menter' original k - ω SST turbulence model. The modeled length and time scales are compared to what can potentially be resolved by the computational grid and time step. If the modeled scales are larger than the resolvable scales, the resolvable scales will replace the modeled scales in the formulation of the eddy viscosity; therefore, the filtering technique helps the turbulence model to adapt in accordance with the mesh resolution and the scales to capture.
Journal Article

An In-Cycle based NOx Reduction Strategy using Direct Injection of AdBlue

2014-10-13
2014-01-2817
In the last couple of decades, countries have enacted new laws concerning environmental pollution caused by heavy-duty commercial and passenger vehicles. This is done mainly in an effort to reduce smog and health impacts caused by the different pollutions. One of the legislated pollutions, among a wide range of regulated pollutions, is nitrogen oxides (commonly abbreviated as NOx). The SCR (Selective Catalytic Reduction) was introduced in the automotive industry to reduce NOx emissions leaving the vehicle. The basic idea is to inject a urea solution (AdBlue™) in the exhaust gas before the gas enters the catalyst. The optimal working temperature for the catalyst is somewhere in the range of 300 to 400 °C. For the reactions to occur without a catalyst, the gas temperature has to be at least 800 °C. These temperatures only occur in the engine cylinder itself, during and after the combustion.
Technical Paper

Numerical Assessment of an After-Treatment System Equipped with a Burner to Speed-Up the Light-Off during Engine Cold Start

2021-09-05
2021-24-0089
In the next years, the upcoming emission legislations are expected to introduce further restrictions on the admittable level of pollutants from vehicles measured on homologation cycles and real drive tests. In this context, the strict control of pollutant emissions at the cold start will become a crucial point to comply with the new regulation standards. This will necessarily require the implementation of novel strategies to speed-up the light-off of the reactions occurring in the after-treatment system, since the cold start conditions are the most critical one for cumulative emissions. Among the different possible technological solutions, this paper focuses on the evaluation of the potential of a burner system, which is activated before the engine start. The hypothetical burner exploits the lean combustion of an air-gasoline mixture to generate a high temperature gas stream which is directed to the catalyst section promoting a fast heating of the substrate.
Journal Article

Experimental and Numerical Study of Flame Kernel Formation Processes of Propane-Air Mixture in a Pressurized Combustion Vessel

2016-04-05
2016-01-0696
Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.
Technical Paper

Experimental and Numerical Assessment of Active Pre-chamber Ignition in Heavy Duty Natural Gas Stationary Engine

2020-04-14
2020-01-0819
Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.
Technical Paper

Numerical Optimization of a SCR System Based on the Injection of Pure Gaseous Ammonia for the NOx Reduction in Light-Duty Diesel Engines

2020-04-14
2020-01-0356
Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.
Journal Article

Ethanol-Diesel Fumigation in a Multi-Cylinder Engine

2008-04-14
2008-01-0033
Fumigation was studied in a 12 L six-cylinder heavy-duty engine. Port-injected ethanol was ignited with a small amount of diesel injected into the cylinder. The setup left much freedom for influencing the combustion process, and the aim of this study was to find operation modes that result in a combustion resembling that of a homogeneous charge compression ignition (HCCI) engine with high efficiency and low NOx emissions. Igniting the ethanol-air mixture using direct-injected diesel has attractive properties compared to traditional HCCI operation where the ethanol is ignited by pressure alone. No preheating of the mixture is required, and the amount of diesel injected can be used to control the heat release rate. The two fuel injection systems provide a larger flexibility in extending the HCCI operating range to low and high loads. It was shown that cylinder-to-cylinder variations present a challenge for this type of combustion.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Journal Article

Investigation of Performance and Emission Characteristics of a Heavy Duty Natural Gas Engine Operated with Pre-Chamber Spark Plug and Dilution with Excess Air and EGR

2012-09-24
2012-01-1980
This article deals with application of turbulent jet ignition technique to heavy duty multi-cylinder natural gas engine for mobile application. Pre-chamber spark plugs are identified as a promising means of achieving turbulent jet ignition as they require minimal engine modification with respect to component packaging in cylinder head and the ignition system. Detailed experiments were performed with a 6 cylinder 9.4 liter turbo-charged engine equipped with multi-point gas injection system to compare performance and emissions characteristics of operation with pre-chamber and conventional spark plug. The results indicate that ignition capability is significantly enhanced as flame development angle and combustion duration are reduced by upto 30 % compared to those with conventional spark plugs at certain operating points.
Journal Article

Sensitivity Analysis Study on Ethanol Partially Premixed Combustion

2013-04-08
2013-01-0269
Partially Premixed Combustion (PPC) is a combustion concept which aims to provide combustion with low smoke and NOx with high thermal efficiency. Extending the ignition delay to enhance the premixing, avoiding spray-driven combustion and controlling the combustion temperature at an optimum level through use of suitable lambda and EGR levels have been recognized as key factors to achieve such a combustion. Fuels with high ignitability resistance have been proven to be a useful to extend the ignition delay. In this work pure ethanol has been used as a PPC fuel. The objective of this research was initially to investigate the required operating conditions for PPC with ethanol. Additionally, a sensitivity analysis was performed to understand how the required parameters for ethanol PPC such as lambda, EGR rate, injection pressure and inlet temperature influence the combustion in terms of controllability, stability, emissions (i.e.
Journal Article

A Fast Crank Angle Resolved Zero-Dimensional NOx Model Implemented on a Field-Programmable Gate Array

2013-04-08
2013-01-0344
In the automotive industry, the piezo-based in-cylinder pressure sensor is getting commercialized and used in production vehicles. For example, the pressure sensor offers the opportunity to design algorithms for estimation of engine emissions, such as soot and NO , during a combustion cycle. In this paper a zero-dimensional NO model for a diesel engine is implemented that will be used in real time. The model is based on the thermal NO formation and the Zeldovich mechanism using two non-geometrical zones: burned and unburned zone. The influence of EGR on combustion temperature was modeled using a well-known thermodynamic identity where specific heat at constant pressure is included. Specific heat will vary with temperature and the gas composition. The model was implemented in LabVIEW using tools specific for an FPGA (Field-Programmable Gate Array).
Journal Article

Comparison of Negative Valve Overlap (NVO) and Rebreathing Valve Strategies on a Gasoline PPC Engine at Low Load and Idle Operating Conditions

2013-04-08
2013-01-0902
Gasoline partially premixed combustion (PPC) has the potential of high efficiency and simultaneous low soot and NOx emissions. Running the engine in PPC mode with high octane number fuels has the advantage of a longer premix period of fuel and air which reduces soot emissions. The problem is the ignitability at low load and idle operating conditions. In a previous study it was shown that it is possible to use NVO to improve combustion stability and combustion efficiency at operating conditions where available boosted air is assumed to be limited. NVO has the disadvantage of low net indicated efficiency due to heat losses from recompressions of the hot residual gases. An alternative to NVO is the rebreathing valve strategy where the exhaust valves are reopened during the intake stroke. The net indicated efficiency is expected to be higher with the rebreathing strategy but the question is if similar improvements in combustion stability can be achieved with rebreathing as with NVO.
Technical Paper

Characterization of Partially Premixed Combustion

2006-10-16
2006-01-3412
Partially Premixed Combustion (PPC) provides the potential of simultaneous reduction of NOx and soot for diesel engines. This work attempts to characterize the operating range and conditions required for PPC. The characterization is based on the evaluation of emission and in-cylinder measurement data of engine experiments. It is shown that the combination of low compression ratio, high EGR rate and engine operation close to stoichiometric conditions enables simultaneous NOx and soot reduction at loads of 8bar, 12bar, and 15bar IMEP gross. The departure from the conventional NOx-soot trade-off curve has to be paid with a decline in combustion efficiency and a rise in HC and CO emissions. It is shown that the low soot levels of PPC come along with long ignition delay and low combustion temperature. A further result of this work is that higher inlet pressure broadens the operating range of Partially Premixed Combustion.
Journal Article

An Experimental Study of Gaseous Transverse Injection and Mixing Process in a Simulated Engine Intake Port

2013-04-08
2013-01-0561
The flow field resulting from injecting a gas jet into a crossflow confined in a narrow square duct has been studied under steady regime using schlieren imaging and laser Doppler velocimetry (LDV). This transparent duct is intended to simulate the intake port of an internal combustion engine fueled by gaseous mixture, and the jet is issued from a round nozzle. The schlieren images show that the relative small size of the duct would confine the development of the transverse jet, and the interaction among jet and sidewalls strongly influences the mixing process between jet and crossflow. The mean velocity and turbulence fields have been studied in detail through LDV measurements, at both center plane and several cross sections. The well-known flow feature formed by a counter rotating vortex pair (CVP) has been observed, which starts to appear at the jet exit section and persists far downstream contributing to enhancing mixing process.
Journal Article

Investigation of Particle Number Emission Characteristics in a Heavy-Duty Compression Ignition Engine Fueled with Hydrotreated Vegetable Oil (HVO)

2018-04-03
2018-01-0909
Diesel engines are one of the most important power generating units these days. Increasing greenhouse gas emission level and the need for energy security has prompted increasing research into alternative fuels for diesel engines. Biodiesel is the most popular among the alternatives for diesel fuel as it is biodegradable and renewable and can be produced domestically from vegetable oils. In recent years, hydrotreated vegetable oil (HVO) has also gained popularity due to some of its advantages over biodiesel such as higher cetane number, lower deposit formation, storage stability, etc. HVO is a renewable, paraffinic biobased alternative fuel for diesel engines similar to biodiesel. Unlike biodiesel, the production process for HVO involves hydrogen as catalyst instead of methanol which removes oxygen content from vegetable oil.
Technical Paper

Evaluation of the Operating Range of Partially Premixed Combustion in a Multi Cylinder Heavy Duty Engine with Extensive EGR

2009-04-20
2009-01-1127
Partially Premixed Combustion (PPC) is a combustion concept by which it is possible to get low smoke and NOx emissions simultaneously. PPC requires high EGR levels and injection timings sufficiently early or late to extend the ignition delay so that air and fuel mix extensively prior to combustion. This paper investigates the operating region of single injection diesel PPC in a multi cylinder heavy duty engine resembling a standard build production engine. Limits in emissions and fuel consumption are defined and the highest load that fulfills these requirements is determined. Experiments are carried out at different engine speeds and a comparison of open and closed loop combustion control are made as well as evaluation of an extended EGR-cooling system designed to reduce the EGR temperature. In this study the PPC operating range proved to be limited.
Technical Paper

A Physical Two-Zone NOx Model Intended for Embedded Implementation

2009-04-20
2009-01-1509
This paper offers a two-zone NOx model suitable for vehicle on-board, on-line implementation. Similar NOx modeling attempts have previously been undertaken. The hereby suggested method does however offer clear and important benefits over the previously methods, utilizing a significantly different method to handle temperature calculations within the (two) different zones avoiding iterative computation. The new method significantly improves calculation speed and, most important of all, reduces implementation complexity while still maintaining reasonable accuracy and the physical interpretation of earlier suggested methods. The equations commonly used to compute NOx emissions is also rewritten in order to suit a two-zone NOx model. An algorithm which can be used to compute NOx emissions is presented and the intended contribution of the paper is a NOx model, implementation feasible for an embedded system, e.g. embedded processor or embedded electronic hardware (FPGA).
Technical Paper

Partially Premixed Combustion at High Load using Gasoline and Ethanol, a Comparison with Diesel

2009-04-20
2009-01-0944
This paper is the follow up of a previous work and its target is to demonstrate that the best fuel for a Compression Ignition engine has to be with high Octane Number. An advanced injection strategy was designed in order to run Gasoline in a CI engine. At high load it consisted in injecting 54 % of the fuel very early in the pilot and the remaining around TDC; the second injection is used as ignition trigger and an appropriate amount of cool EGR has to be used in order to avoid pre-ignition of the pilot. Substantially lower NOx, soot and specific fuel consumption were achieved at 16.56 bar gross IMEP as compared to Diesel. The pressure rise rate did not constitute any problem thanks to the stratification created by the main injection and a partial overlap between start of the combustion and main injection. Ethanol gave excellent results too; with this fuel the maximum load was limited at 14.80 bar gross IMEP because of hardware issues.
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