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Technical Paper

Palladium/Rhodium Dual-Catalyst LEV 2 and Bin 4 Close-Coupled Emission Solutions

2007-04-16
2007-01-1263
Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.
Technical Paper

A Comparison of Extruded Powder Metal Heating Elements and Metallic Foil Heating Elements

1996-10-01
962081
California Ultra Low Emission Vehicle (ULEV) standards call for a significant reduction in the amount of harmful gases that enter the environment from vehicle exhaust. The Electrically Heated Catalyst (EHC) is a possible solution to reduce emissions. A competitive analysis benchmarking study was completed in order to find an optimum EHC design that will perform to ULEV standards. Four suppliers submitted samples and the EHC designs were rigorously tested for temperature, pressure drop, and emissions performance while being aged at different levels.
Technical Paper

Palladium and Platinum/Rhodium Dual-Catalyst Emission Solutions for Close-Coupled or Underfloor Applications

2000-03-06
2000-01-0860
Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.
Technical Paper

Multiple Environment Accelerated Reliability Test Development

1999-10-10
1999-01-3387
The four major discriminators for products in the market place are Technology, Quality,1 Cost and Delivery. Effective measurement systems and initial design quality have the largest impact on delivered field quality, program development cost and timing, as well as customer enthusiasm. System-level reliability testing methods have a major impact on the business health of any product. The implementation of laboratory forced failure testing in simultaneously applied energy environments has the largest influence for "designing in" field reliability and lowering development cost. Clearly a policy change from success based testing to forced failure testing has had the largest impact on results for the consumer.
Technical Paper

Powertrains of the Future: Reducing the Impact of Transportation on the Environment

1999-03-01
1999-01-0991
Tomorrow's winning powertrain solutions reside in those technology combinations providing optimized propulsion systems with zero emissions and no cost or performance penalty compared with today's vehicles. The recent Kyoto Protocol for CO2 reduction and the California Air Resources Board (CARB) thrust for zero emission vehicles along with the European Regulatory community, motivate car manufacturers to adopt new light body structures with low aerodynamic drag coefficients, low-rolling resistance and the highest efficiency powertrains. The environmental equation expresses car manufacturers aptitude and desire to create zero emission vehicles at acceptable levels of performance unlike limited range electrical powered vehicle products. The cheapest solution to the environmental equation remains the conventional internal combustion engine ($30 to $50 per kW).
Technical Paper

Advanced Engine Management Using On-Board Gasoline Partial Oxidation Reforming for Meeting Super-ULEV (SULEV) Emissions Standards

1999-08-17
1999-01-2927
This paper first reports on the benchmarking of a gasoline- fueled vehicle currently for sale in California that is certified to ULEV standards. Emissions data from this vehicle indicate the improvements necessary over current technology to meet SULEV tailpipe standards. Tests with this vehicle also show emissions levels with current technology under off-cycle conditions representative of real-world use. We then present Delphi's strategy of on-board partial oxidation (POx) reforming with gasoline-fueled, spark-ignition engines. On-board reforming provides a source of hydrogen fuel. Tests were run with bottled gas simulating the output of a POx reformer. Results show that an advanced Engine Management System with a small on-board reformer can provide very low tailpipe emissions both under cold start and warmed-up conditions using relatively small amounts of POx gas. The data cover both normal US Federal Test Procedure (FTP) conditions as well as more extreme, off-cycle operation.
Technical Paper

Global Hybrid Electric Vehicle Markets and Missions

1999-08-17
1999-01-2946
Most large automobile manufacturers are considering adding hybrid electric vehicles (HEV) to their product portfolio for environmental reasons. Some, like Toyota, Nissan and Honda, have already begun producing or have plans for producing hybrids. Skeptics in the industry see these efforts as mostly intended to enhance the automaker's environmental image at a cost that is not recoverable in the marketplace. Few in the automotive industry claim a sound economic basis for hybrids, and furthermore are repelled by the disruption of existing systems they promise. To test the validity of the industry's generally negative view of HEV economics, this paper establishes a logical, mission-based classification for HEV system architecture and performs a present value analysis for the three classes.
Technical Paper

Individual Cylinder Fuel Control with a Switching Oxygen Sensor

1999-03-01
1999-01-0546
In this paper we discuss in detail an algorithm that addresses cylinder-to-cylinder imbalance issues. Maintaining even equivalence-ratio (ϕ) control across all the cylinders of an engine is confounded by imbalances which include fuel-injector flow variations, fresh-air intake maldistribution and uneven distribution of Exhaust Gas Re-circulation (EGR). Moreover, in markets that are growing increasingly cost conscious, with ever tightening emissions regulations, correcting for such mismatches must not only be done, but done at little or no additional cost. To address this challenge, we developed an Individual Cylinder Fuel Control (ICFC) algorithm that estimates each cylinder's individual ϕ and then compensates to correct for any imbalance using only existing production hardware. Prior work in this area exists1,2, yet all disclosed production-intent work was performed using wide-range oxygen sensors, representing cost increases.
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