Search Results

In recognizing the potential for large, damaging impacts from climate change, California enacted Executive Order S-03-05, requiring a reduction in statewide greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050. Given that the transportation light-duty vehicle (LDV) segment accounts for 28% of the state's GHG emissions today, it will be difficult to meet the 2050 goal unless a portfolio of near-zero carbon transportation solutions is pursued. Because it takes decades for a new propulsion system to capture a large fraction of the passenger vehicle market due to vehicle fleet turn-over rates, it is important to accelerate the introduction of these alternatives to ensure markets enter into early commercial volumes (10,000s) between 2015 and 2020. This report summarizes the results and conclusions of a modeling exercise that simulated GHG emissions from the LDV sector to 2050 in California.

Life-cycle assessments (LCA) of biodistillate fuels are becoming increasingly important for policy decisions regarding alternative fuels. However, due to the data-intensive and assumptive nature of LCAs, rarely do two different studies produce comparable results. To add to the complexity, effects of indirect land use changes are now being incorporated into LCA models. This development is influencing policy decisions and generating much controversy. A literature survey of 55 different LCA studies of bio-distillate fuels was conducted. The comparison of energy requirements and global warming potential (GWP) impacts of these studies help to illustrate which data inputs and assumptions most strongly affect the results, and wherein the major discrepancies lie. Life-cycle energy results are typically reported as energy return (ER), meaning the heating value of the biofuel divided by the total fossil energy inputs to produce the fuels.

Biodistillate transportation fuels include biodiesel (produced via transesterification of animal fats and vegetable oils) and renewable diesel (produced via catalytic hydroprocessing of the same feedstocks). Production and use of biodistillates are increasing dramatically, both in the U.S. and globally. This paper describes the policy drivers prompting growth of biodistillate fuels in the U.S., Europe, and selected other countries. Trends in fuel production volumes and feedstocks supplies are presented for these fuels. Current feedstocks are dominated by soybean oil in the U.S. and rapeseed oil in Europe. However, there is much interest in developing alternative, non-edible feedstocks such as jatropha and microalgae. Currently, biodiesel is the dominant biodistillate in use, though interest in renewable diesel is increasing. This paper describes different conversion processes used to manufacture these fuels, and discusses the pros and cons of each.

A study was conducted by the California Air Resources Board to investigate the effects that altitude has on in-use heavy-duty diesel truck smoke opacities. The understanding of these effects may allow for the establishment of a high altitude opacity standard for diesel trucks operating at or above altitudes of 5800 feet. During a three-week study, 170 heavy-duty diesel trucks were tested at an altitude of 5,820 feet using a test procedure consisting of rolling acceleration and snap idle tests. Eighty-four (84) of these trucks were recaptured and retested at an altitude of 125 feet. Results from a regression analysis indicates that, on average, truck smoke opacities increased by 23 opacity points when tested at altitudes near 6000 feet. Possible high altitude cutpoints and failure rates are also discussed.

The impact of biodiesel and new generation biofuels on emissions from heavy-duty diesel engines was investigated using a California Air Resources Board (CARB) certified diesel fuel as a base fuel. This study was performed on two heavy-duty diesel engines, a 2006 engine and a diesel particle filter (DPF) equipped 2007 engine, on an engine dynamometer over four different test cycles. Emissions from soy-based and animal-based biodiesel, renewable diesel fuel, and gas-to-liquid (GTL) diesel fuel were evaluated at blend levels ranging from 5 to 100%. Consistent with previous studies, particulate matter (PM), hydrocarbons (HC), and carbon monoxide (CO) emissions generally showed increasing reductions with increasing biodiesel and renewable/GTL diesel fuel blend levels for the non-DPF equipped engine. The levels of these reductions were generally comparable to those found in previous studies performed using more typical Federal diesel fuels.

The sampling protocol proposed by the international PMP program for determination of particle emissions from clean light-duty vehicles was applied to the emissions from a California heavy-duty trap-equipped diesel truck. CARB is interested in developing opinions about the potential of this new European approach for emission determination and in exploring its utility for use in California. In this exercise, the use of various commercially available instruments for counting and sizing particles in the context of the PMP recommendations are explored. A single vehicle on a chassis dynamometer was exercised over steady-state and transient cycles. Multiple measurements of gaseous, mass, and particle emissions were collected in order to determine statistical significance. The PMP approach yielded particle emission measurements with higher precision and accuracy than the reference mass-based emission measurement.

Heavy-duty vehicles account for approximately 30 percent of the oxides of nitrogen (NOx) and 65 percent of the particulate matter (PM) emissions from the entire California on-road fleet, despite the fact that these vehicles comprise only 2 percent of the same. To meet legislative mandates to reduce excess smoke emissions from in-use heavy-duty diesel-powered vehicles, the Air Resources Board (ARB or Board) adopted, in December 1997, amendments to the regulations governing the operation and enforcement of the Heavy-Duty Vehicle Inspection Program (HDVIP or the “roadside” program) and the Periodic Smoke Inspection Program (PSIP or the “fleet” program). The initial roadside program was adopted in November 1990 in response to Senate Bill (SB) 1997 (stat. 1988, ch. 1544, Presley), and enforced from 1991 to 1993. It was suspended in October 1993, when the Board redirected staff to investigate reformulated fuels issues.

In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc. was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20% biodiesel (B20), and 99% biodiesel (B99) on consecutive days.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

Six laboratories capable of chassis-testing heavy-duty vehicles participated in a crosscheck program designed to compare emissions results from a Ford L-9000. The single-axle vehicle was shipped to each laboratory and tested through a series of UDDS and steady-state cycles. The resulting data were compared statistically using reproducibility and repeatability analyses. Although one lab produced some results that significantly differed from the other five, the remaining labs produced comparable results. TPM, CO and THC were the most variable while NOX and CO2 were most stable. Lab differences included atmospheric and environmental conditions, road-load curve application and drivers. Comparison of steady state and transient tests suggest that driver variability is not a major factor.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

The measurement of SO2 levels in vehicle exhaust can provide important information in understanding the relative contribution of sulfur and sulfate from fuel vs. oil source to PM. For this study, a differential optical absorption spectrometer (DOAS) that can measure SO2 down to 20 ppbV in real-time was built and evaluated. The DOAS consisted of an extractive sampling train, a cylindrical sampling cell with a single-path design to minimize cell volume, a spectrometer, and a deuterium lamp light source with a UVC range of ∼200-230 nanometer (nm). Laboratory tests showed detection limits were approximately in the range of 12 to 15 ppbV and showed good linearity over SO2 concentration ranges of 20 to 953 ppbV. Interference tests showed some interference by NO and by NH3, at levels of 300 ppmV and 16.6 ppmV, respectively.

Biodiesel is a renewable transportation fuel consisting of fatty acid methyl esters (FAME), generally produced by transesterification of vegetable oils and animal fats. The effects of biodiesel usage upon vehicle emissions have been investigated by numerous groups. A consensus view has developed that emissions of hydrocarbons (HC), carbon monoxide (CO) and fine particulate matter (PM) can be reduced by use of biodiesel, while oxides of nitrogen (NOx) increase slightly. This paper provides a review of the literature regarding the effects of biodiesel upon emissions of these four criteria pollutants. The emissions database was restricted to studies in which both biodiesel and a conventional diesel fuel were tested under identical dynamometer conditions. Both heavy-duty (HD) and light-duty (LD) engines/vehicles were considered.

Diesel vehicles are significant sources of NOx and PM emissions, and to a lesser extent, emissions of CO, HC, and toxic species. For many years, biodiesel fuel (and blends of biodiesel) has been promoted as a “clean fuel” alternative to conventional diesel. Based upon previous reviews by EPA, a common understanding has arisen that biodiesel usage reduces CO, HC, and PM emissions significantly, but increases NOx emissions slightly. This paper discusses a recent review of 94 published reports, from the period of 2000-2008. Assessments were made of the emissions impacts of biodistillate fuels from various engine types, operating conditions, control technologies, and fuel type. In each situation, emissions from the biodistillate case were compared with emissions from a reference diesel fuel case.

A novel in situ method was performed for measuring emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. The test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. The exhaust configurations were a stock original equipment manufacturer (OEM) muffler and a Thermo King pDPF™ diesel particulate filter. The two TRU engine operating speeds were high and low, as controlled by the TRU user interface. Test results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine operating speeds. Separately, the application of a Thermo King pDPF reduced regulated emissions, in some cases almost entirely. Finally, the application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine operating speed, but with an increase in oxides of nitrogen (NOx) at low engine speed.

This paper covers work performed for the California Air Resources Board and US Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on four in-use off-road two-stroke motorcycles and all-terrain vehicles utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.

Two additive blends proposed for improving the flame luminosity in neat methanol fuel were investigated to determine the effect of these additives on the exhaust emissions in a dual-fueled Volkswagen Jetta. The two blends contained 4 percent toluene plus 2 percent indan in methanol and 5 percent cyclopentene plus 5 percent indan in methanol. Each blend was tested for regulated and unregulated emissions as well as a speciation of the exhaust hydrocarbons resulting from use of each fuel. The vehicle exhaust emissions from these two fuel blends were compared to the Coordinating Research Council Auto-Oil national average gasoline (RF-A), M100, and M85 blended from RF-A. Carter Maximum Incremental Reactivity Factors were applied to the speciated hydrocarbon emission results to determine the potential ozone formation for each fuel. Toxic emissions as defined in the 1990 Clean Air Act were also compared for each fuel.

Vehicle exhaust emissions measurements are reported for full-size panel vans operating on four alternative motor fuels and control gasoline. The emissions tests produced data on in-use vans. The vans were taken directly from commercial delivery service for testing as they accumulated mileage over a 24-month period. The alternative fuels tested were compressed natural gas, propane gas, California Phase 2 reformulated gasoline (RFG), and methanol (M-85 with 15 percent RFG). The control gasoline for the emissions tests was an industry average unleaded blend (RF-A). The vehicle technologies tested represent those options available in 1992 that were commercially available from Ford, Chrysler, and Chevrolet or which these manufacturers agreed to provide as test vans for daily use in commercial service by FedEx.

California is considering adopting an enhanced Inspection and Maintenance (I&M) program (commonly referred to as Smog Check II) beginning with the 1996 calendar year. This program will utilize a targeting scheme to identify vehicles likely to be high emitters and send these vehicles to centralized testing facilities. The remaining fleet of vehicles will be sent to decentralized testing facilities. At these facilities, vehicles will be subjected to steady state loaded mode dynamometer based tests. Simultaneously, all 1996 and later model year passenger cars, light- and medium-duty trucks sold in California will be equipped with an On-Board Diagnostic (OBDII) system. This system is designed to monitor critical emission related components and activate a Malfunction Indicator Light (MIL) when a failure or a drift in calibration is likely to cause emissions to exceed 1.5 times the vehicle certification standards.