Search Results

Diesel NOx emissions control utilizing combined Lean NOx Trap (LNT) and so-called passive or in-situ Selective Catalytic Reduction (SCR) catalyst technologies (i.e. with reductant species generated by the LNT) has been the subject of several previous papers from our laboratory [ 1 - 2 ]. The present study focuses on hydrocarbon (HC) emissions control via the same LNT+SCR catalyst technology under FTP driving conditions. HC emissions control can be as challenging as NOx control under both current and future federal and California/Green State emission standards. However, as with NOx control, the combined LNT+SCR approach offers advantages for HC emission control over LNT-only aftertreatment. The incremental conversion obtained with the SCR catalyst is shown, both on the basis of vehicle and laboratory tests, to result primarily from HC adsorbed on the SCR catalyst during rich LNT purges that reacts during subsequent lean engine operation.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

A head gasket is a component that sits between the engine block/liner and cylinder head(s) in an internal combustion engine. Its purpose is to seal high pressure combustion gasses in the cylinders and to seal coolant and engine oil. It is the most critical sealing application in an engine. As a general practice, the load deflection(L/D) characteristic is generated by the gasket manufacturer for edge molded or composite gasket types. However, in the case of a solid-sheet metallic gasket, where the gasket is expected to undergo localized yielding to provide adequate conformance and sealing, usually supplier may not be able to provide the required L/D curve due to difficulties to experimentally separate the large loads and small displacements from the elastic loads and deflections of the experimental apparatus. In absence of L/D curve, the typical analysis approach is to model gasket as 3D continuum elements available in ansys by considering nonlinear material and frictional contacts.

The main objective of the current paper was to investigate the fluid flow and pressure loss characteristics of DPF substrates with asymmetric channels utilizing 3-D Computational Fluid Dynamics (CFD) methods. The ratio of inlet to outlet channel width is 1.2. First, CFD results of velocity and static pressure distributions inside the inlet and outlet channels are discussed for the baseline case with both forward and reversed exhaust flow. Results were also compared with the regular DPF of same cell structure and wall material properties. It was found that asymmetrical channel design has higher pressure loss. The lowest pressure loss was found for the asymmetrical channel design with smaller inlet channels. Then, the effects of DPF length and filter wall permeability on pressure loss, flow and pressure distributions were investigated.

Oxidation of NO to NO₂ over a Diesel Oxidation Catalyst (DOC) plays an important role in different types of aftertreatment systems, by enhancing NOx storage on adsorber catalysts, improving the NOx reduction efficiency of SCR catalysts, and enabling the passive regeneration of Diesel Particulate Filters (DPF). The presence of hydrocarbon (HC) species in the exhaust is known to affect the NO oxidation performance over a DOC; however, specific details of this effect, including its underlying mechanism, remain poorly understood. Two major pathways are commonly considered to be responsible for the overall effect: NO oxidation inhibition, due to the presence of HC, and the consumption of the NO₂ produced by reaction with hydrocarbons. In this work we have attempted to decouple these two pathways, by adjusting the catalyst inlet concentrations of NO and NO₂ to the thermodynamic equilibrium levels and measuring the composition changes over the catalyst in the presence of HC species.

Urea-selective catalytic reduction (SCR) after-treatment systems are used for reducing oxides of nitrogen (NOx) emissions in medium and heavy duty diesel vehicles. This paper addresses control-oriented modeling, starting from first-principles, of SCR after-treatment systems. Appropriate simplifications are made to yield governing equations of the Urea-SCR. The resulting nonlinear partial differential equations (PDEs) are discretized and linearized to yield a family of linear finite-dimensional state-space models of the SCR at different operating points. It is further shown that this family of models can be reduced to three operating regions. Within each region, parametric dependencies of the system on physical mechanisms are derived. Further model reduction is shown to be possible in each of the three regions resulting in a second-order linear model with sufficient accuracy.

A process for creating a Customer Correlated, Accelerated, Life Test is presented. This process, which results in a model for predicting reliability, has been applied to a cold weather piston scuff problem. In this paper, the authors will discuss development of frequency distributions for customer environmental and operational use, establishment of customer based failure criteria, development of an accelerated test based on degradation, selection of testing strategies, data analyses, and measurement techniques.

The 1977 Clean Air Act Amendments allow the U.S. Environmental Protection Agency to set high altitude emission standards for 1981-83, but specify that any such standards may not be more stringent than comparable sea level standards -- relative to 1970 emission levels. Since available high altitude emission data from 1970 models were incomplete and controversial, the Motor Vehicle Manufacturers Association contracted with Automotive Testing Laboratories, Inc. to test a fleet of 25 1970 cars. Results of the test program showed average increases in emissions at Denver's altitude, compared to sea level, to be about 30% for evaporative HC, 57 to 60% for exhaust HC, 215 to 247% for CO and -46 to -47% for NOx. Corresponding HC and CO exhaust emission baselines would be 6.4 to 6.6 and 108 to 118 g/mi respectively.