Search Results

A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.

As emissions regulations around the world become more stringent, emerging markets are seeking alternative strategies that align with local infrastructures and conditions. A Lean NOx Catalyst (LNC) is developed that achieves up to 60% NOx reduction with ULSD as its reductant and ≻95% with ethanol-based fuel reductants. Opportunities exist in countries that already have an ethanol-based fuel infrastructure, such as Brazil, improving emissions reduction penetration rates without costs and complexities of establishing urea infrastructures. The LNC performance competes with urea SCR NOx reduction, catalyst volume, reductant consumption, and cost, plus it is proven to be durable, passing stationary test cycles and adequately recovering from sulfur poisoning. Controls are developed and applied on a 7.2L engine, an inline 6-cylinder non-EGR turbo diesel.

The low-NOx standard for heavy-duty trucks proposed by the California Air Resources Board will require rapid warm-up of the aftertreatment system (ATS). Several different aftertreatment architectures and technologies, all based on selective catalytic reduction (SCR), are being considered to meet this need. One of these architectures, the close-coupled SCR (ccSCR), was evaluated in this study using two different physics-based, 1D models; the simulations focused on the first 300 seconds of the cold-start Federal Test Procedure (FTP). The first model, describing a real, EuroVI-compliant engine equipped with series turbochargers, was used to evaluate a ccSCR located either i) immediately downstream of the low-pressure turbine, ii) in between the two turbines, or iii) in a by-pass around the high pressure turbine.