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The occurrence of knock is the most limiting hindrance for modern Spark-Ignition (SI) engines. In order to understand its origin and move the operating condition as close as possible to onset of this potentially harmful phenomenon, a joint experimental and numerical investigation is the most recommended approach. A preliminary experimental activity was carried out at IM-CNR on a 0.4 liter GDI unit, equipped with a flat transparent piston. The analysis of flame front morphology allowed to correlate high levels of flame front wrinkling and negative curvature to knock prone operating conditions, such as increased spark timings or high levels of exhaust back-pressure. In this study a detailed CFD analysis is carried out for the same engine and operating point as the experiments. The aim of this activity is to deeper investigate the reasons behind the main outcomes of the experimental campaign.

Liquids with stable suspensions of nanoscale materials are defined as nanofluids. As reported in recent scientific literature, a very small amount of suspended nanostructures has the potential to enhance the thermo physical, transport and radiative properties of the base fluid. One of the main applications of this technology is in the field of combustion and fuels. In fact, adding nanomaterials (such as metals, oxides, carbides, nitrides, or carbon-based nanostructures) to liquid fuels is able to enhance ignition and combustion. The focus of this research is to gain a fundamental understanding of the characteristics of a nanofluid fuel prepared using carbon nanoparticles (CNPs) and multi-walled carbon nanotubes (MWCNTs) dispersed in butanol. This study starts with the investigation of the optical properties of the mixtures. The transmission spectra of the nanofluids are measured in a wide wavelength range from UV (250 nm) to near IR (800 nm).