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Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.

Dual fuel (CI) engines provide an excellent means of maintaining high thermal efficiency and power while reducing emissions, particularly in situations where the primary fuel does not exhibit good auto-ignition characteristics. This is especially true of diesel engines operating on natural gas; usually in stationary applications such as distributed power generation. However, because two fuels are needed, the reliability of the engine is compromised. Therefore, this paper describes the first phase of a project that is to eventually manufacture dimethyl ether (DME) from natural gas and supply it to the pilot injector of a dual fuel engine. A chemical pilot plant has been built and operated, demonstrating an intermediate step in the production of DME from natural gas. DME is manufactured from methanol for pilot injection into a dual fuel engine operating with natural gas as the main fuel.

It is beneficial but challenging to operate spark-ignition engines under highly lean and dilute conditions. The unstable ignition behavior can result in downgraded combustion performance in engine cylinders. Numerical approach is serving as a promising tool to identify the ignition requirements by providing insight into the complex physical/chemical phenomena. An effort to simulate the early stage of flame kernel initiation in lean and dilute fuel/air mixture has been made and discussed in this paper. The simulations are set to validate against laboratory results of spark ignition behavior in a constant volume combustion vessel. In order to present a practical as well as comprehensive ignition model, the simulations are performed by taking into consideration the discharge circuit analysis, the detailed reaction mechanism, and local heat transfer between the flame kernel and spark plug.

A model process to produce dimethylether (DME) from natural gas (NG) was simulated in a one-pass mode (no material recycle), assuming steady-state and chemical and physical equilibrium. NG conversion to synthesis gas (syngas) via steam reforming resulted in stoichiometric numbers of 2.97 along with vapor mole fraction extremes for carbon dioxide, methane, and water. These concentrations formed an eight-trial simulation grid of syngas compositions. Simulation of DME production was performed in a dual reactor configuration with methanol formation as the intermediate compound. Solutions resulting from the subsequent adiabatic dehydration of the methanol-rich phase showed a consistent DME composition (88%). The resulting solutions and unreacted syngas streams from simulation were examined for applicability to a dual-fuel NG/DME CI engine.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost versus diesel fuel has increased interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim for development for these NG engines is to realize fuel cost savings and increase operating range while reduce harmful emissions and maintaining durability. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for light duty LD, and MD engines with widespread use in the US and Europe [1]. However, this technology exhibits poor thermal efficiency and is load limited due to knock phenomenon that has prohibited its use for HD engines. Spark Ignited Direct Injection (SIDI) can be used to create a partially stratified combustion (PSC) mixture of NG and air during the compression stroke.

The characteristics of combustion knock metrics over a number of engine cycles can be an essential reference for knock detection and control in internal combustion engines. In a Spark-Ignition (SI) engine, the stochastic nature of combustion knock has been shown to follow a log-normal distribution. However, this has been derived from experiments done with gasoline only and applicability of log-normal distribution to dual-fuel combustion knock has not been explored. To evaluate the effectiveness and accuracy of log-normal distributed knock model for methane-gasoline blended fuel, a sweep of methane-gasoline blend ratio was conducted at two different engine speeds. Experimental investigation was conducted on a single cylinder prototype SI engine equipped with two fuel systems: a direct injection (DI) system for gasoline and a port fuel injection (PFI) system for methane.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

A diesel piloted natural gas engine's performance varies depending on operating conditions and has performed best under medium to high loads. It can often equal or better the fuel conversion efficiency of a diesel-only engine in this operating range. This paper presents a study performed on a multi-cylinder Cummins ISB 6.7L diesel engine converted to run stoichiometric natural gas/diesel micro-pilot combustion with a maximum diesel contribution of 10%. This study systematically quantifies and ranks the sensitivity of control factors on combustion and performance while operating at medium loads. The effects of combustion control parameters, including the pilot start of injection, pilot injection pressure, pilot injection quantity, exhaust gas recirculation, and global equivalence ratio, were tested using a design of experiments orthogonal matrix approach.

When fuel at elevated temperatures is injected into an ambient environment at a pressure lower than the saturation pressure of the fuel, the fuel vaporizes in the nozzle and/or immediately upon exiting the nozzle; that is, it undergoes flash boiling. It is characterized by a two-phase flow regime co-located with primary breakup, which significantly affects the spray characteristics. Under flash boiling conditions, the near nozzle spray angle increases, which can lead to shorter penetration because of increased entrainment. In a multi-hole injector this can cause other impacts downstream resulting from the increased plume to plume interactions. To study the effect of injector temperature and injection pressure with real fuels, an experimental investigation of the spray characteristics of a summer grade gasoline fuel with 10% ethanol (E10) was conducted in an optically accessible constant volume spray vessel.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost compared to diesel fuel has heightened interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim for development for these NG engines is to realize fuel cost savings and reduce harmful emissions while maintaining durability. Transforming part of the vehicle fleet to NG is a path to reduce dependence on crude oil. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for MD and HD engines with widespread use in the US and Europe. But this technology exhibits poor cycle efficiency and is load limited due to knock phenomenon. Direct Injection of NG during the compression stroke promises to deliver improved thermal efficiency by avoiding excessive premixing and extending the lean limits which helps to extend the knock limit.

The increased availability of natural gas (NG) in the United States (US), and its relatively low cost compared to diesel fuel has heightened interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim is to realize fuel cost savings and reduce harmful emissions, while maintaining durability. This is a potential path to help the US reduce dependence on crude oil. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for MD and HD engines with widespread use in the US and Europe; however, this technology exhibits poor cycle efficiency and is load limited due to knock phenomenon. Direct Injection of NG during the compression stroke promises to deliver improved thermal efficiency by avoiding excessive premixing and extending the lean limits which helps to extend the knock limit.

A constant volume spray and combustion vessel utilizing the pre-burn mixture procedure to generate pressure, temperature, and composition characteristic of near top dead center (TDC) conditions in compression ignition (CI) engines was modified with post pre-burn gas induction to incorporate premixed methane gas prior to diesel injection to simulate processes in dual fuel engines. Two variants of the methane induction system were developed and studied. The first used a high-flow modified direct injection injector and the second utilized auxiliary ports in the vessel that are used for normal intake and exhaust events. Flow, mixing, and limitations of the induction systems were studied. As a result of this study, the high-flow modified direct injection injector was selected because of its controlled actuation and rapid closure. Further studies of the induction system post pre-burn were conducted to determine the temperature limit of the methane auto-ignition.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost compared to diesel fuel has heightened interest in the conversion of medium duty (MD) and heavy duty (HD) diesel engines to NG fuel and combustion systems (compressed or liquefied). The intention is to realize fuel cost savings and reduce harmful emissions, while maintaining or improving overall vehicle fuel economy. This is a potential path to help the US achieve energy diversity and reduce dependence on crude oil. Traditionally, port-injected, premixed NG spark-ignited combustion systems have been used for medium and heavy duty engines with widespread use in the US and Europe. But this technology exhibits poor cycle efficiency and is load limited due to knock phenomenon. Direct Injection of NG during the compression stroke promises to deliver improved thermal efficiency by avoiding premixing and extending the lean limits which helps to extend the knock limit.

A three phase catalytic mathematical model was developed for analysis and optimization of the volatile reactor assembly (VRA) used on International Space Station (ISS) Water Processor. The Langmuir-Hinshelwood Hougen-Watson (L-H) expression was used to describe the surface reaction rate. Small column experiments were used to determine the L-H rate parameters. The test components used in the experiments were acetic acid, acetone, ethanol, 1-propanol, 2-propanol and propionic acid. These compounds are the most prevalent ones found in the influent to the VRA reactor. The VRA model was able to predict performance of small column data and experimental data from the VRA flight experiment.

Optical and laser diagnostics enable in-depth spray characterization in regards to macroscopic spray characteristics and in-situ fuel mixture quality information, which are needed in understanding the spray injection process and for spray model development, validation and calibration. Use of fuel surrogates in spray researches is beneficial in controlling fuel parameters, developing spray and combustion kinetic models, and performing laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of a single and multi-component surrogate in comparison to a gasoline with 10% ethanol under gasoline direct injection (GDI) engine conditions. In addition, the effect of fuel tracers on spray evolution and vaporization is also investigated. Both diethyl-methyl-amine/fluorobenzene as a laser-induced exciplex (LIEF) fluorescence tracer pair and 3-pentanone as a laser-induced fluorescence (LIF) tracer are examined.

The medium and heavy-duty powertrain industry trend is to reduce reliance on diesel fuel and is aligned with continued efforts of achieving ultra-low emissions and high brake efficiencies. Compression Ignition (CI) of late cycle Directly Injected (DI) Natural Gas (NG) shows the potential to match diesel performance in terms of brake efficiency and power density, with the benefit of utilizing a lower carbon content fuel. A primary challenge is to achieve stable ignition of directly injected NG over a wide engine speed and load range without the need for a separate ignition source. This project aims to demonstrate the CI of DI NG through experimental studies with a Single Cylinder Research Engine (SCRE), leading to the development of a mono-fueled NG engine with equivalent performance to that of current diesel technology, 25% lower CO2 emissions, and low engine out methane emissions.