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Catalyzed Particulate Filter Passive Oxidation Study with ULSD and Biodiesel Blended Fuel

2012-06-18
The development of PM and NOx reduction system with the combination of DOC included DPF and SCR catalyst in addition to the AOC sub-assembly for NH3 slip protection is described. DPF regeneration strategy and manual regeneration functionality are introduced with using ITH, HCI device on the EUI based EGR, VGT 12.3L diesel engine at the CVS full dilution tunnel test bench. With this system, PM and NOx emission regulation for JPNL was satisfied and DPF regeneration process under steady state condition and transient condition (JE05 mode) were successfully fulfilled. Manual regeneration process was also confirmed and HCI control strategy was validated against the heat loss during transient regeneration mode. Presenter Seung-il Moon
Journal Article

Enabling Flex Fuel Vehicle Emissions Testing – Test Cell Modifications and Data Improvements

2009-04-20
2009-01-1523
The challenges of flex-fuel vehicle (FFV) emissions measurements have recently come to the forefront for the emissions testing community. The proliferation of ethanol blended gasoline in fractions as high as 85% has placed a new challenge in the path of accurate measures of NMHC and NMOG emissions. Test methods need modification to cope with excess amounts of water in the exhaust, assure transfer and capture of oxygenated compounds to integrated measurement systems (impinger and cartridge measurements) and provide modal emission rates of oxygenated species. Current test methods fall short of addressing these challenges. This presentation will discuss the challenges to FFV testing, modifications made to Ford Motor Company’s Vehicle Emissions Research Laboratory test cells, and demonstrate the improvements in recovery of oxygenated species from the vehicle exhaust system for both regulatory measurements and development measurements.
Journal Article

Laboratory Study of Soot, Propylene, and Diesel Fuel Impact on Zeolite-Based SCR Filter Catalysts

2009-04-20
2009-01-0903
Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.
Journal Article

Modeling of Thermophoretic Soot Deposition and Hydrocarbon Condensation in EGR Coolers

2009-06-15
2009-01-1939
EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40–90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature.
Journal Article

Effect of Unburned Methyl Esters on the NOx Conversion of Fe-Zeolite SCR Catalyst

2009-11-02
2009-01-2777
Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.
Journal Article

Measurement of Diesel Spray Formation and Combustion upon Different Nozzle Geometry using Hybrid Imaging Technique

2014-04-01
2014-01-1410
High pressure diesel sprays were visualized under vaporizing and combusting conditions in a constant-volume combustion vessel. Near-simultaneous visualization of vapor and liquid phase fuel distribution were acquired using a hybrid shadowgraph/Mie-scattering imaging setup. This imaging technique used two pulsed LED's operating in an alternative manner to provide proper light sources for both shadowgraph and Mie scattering. In addition, combustion cases under the same ambient conditions were visualized through high-speed combustion luminosity measurement. Two single-hole diesel injectors with same nozzle diameters (100μm) but different k-factors (k0 and k1.5) were tested in this study. Detailed analysis based on spray penetration rate curves, rate of injection measurements, combustion indicators and 1D model comparison have been performed.
Journal Article

Development and Demonstration of LNT+SCR System for Passenger Car Diesel Applications

2014-04-01
2014-01-1537
The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.
Technical Paper

Gasoline Particulate Filter Characterization Focusing on the Filtration Efficiency of Nano-Particulates Down to 10 nm

2020-09-15
2020-01-2212
With Post Euro 6 emission standards in discussion, stricter particulate number (PN) targets as well as a decreased PN cut-off size from 23 to 10 nm are expected. Sub-23 nm particulates are considered particularly harmful to human health, but are not yet taken into account in the current vehicle certification process. Not considering sub-23 nm particulates during the development process could lead to significant additional efforts for Original Equipment Manufacturers (OEM) to comply with future Post Euro 6 PN emission limits. It is therefore essential to increase knowledge about the formation and filtration of particulates below 23 nm. In the present study, a holistic Gasoline Particulate Filter (GPF) characterization has been carried out on an engine test bench under varying boundary conditions and on a burner bench with a novel ash loading methodology.
Journal Article

Exhaust Manifold Durability Subject to Splash Quenching

2015-04-14
2015-01-1735
Exhaust manifold design is one of the more challenging tasks for the engine engineer due to the harsh thermal and severe vibration environment. Extremely high exhaust gas temperatures and dynamic loading combine to subject the manifold to high cyclic stress when the material has reduced fatigue strength due to the high temperature. A long service life before a fatigue failure is the objective in exhaust manifold design. Accumulation of fatigue damage can occur from dynamic loading and thermal loading combined. Thermal mechanical fatigue (TMF) is a primary mechanism for accumulating fatigue damage. TMF typically occurs when a vehicle driving cycle has operating conditions that repeatedly change the exhaust gas temperature between hot and cold. Another way to experience temperature cycling is through splash quenching. Splash quenching was analyzed and found to rapidly accumulate fatigue damage.
Journal Article

A Sectoral Approach to Modelling Wall Heat Transfer in Exhaust Ports and Manifolds for Turbocharged Gasoline Engines

2016-04-05
2016-01-0202
A new approach is presented to modelling wall heat transfer in the exhaust port and manifold within 1D gas exchange simulation to ensure a precise calculation of thermal exhaust enthalpy. One of the principal characteristics of this approach is the partition of the exhaust process in a blow-down and a push-out phase. In addition to the split in two phases, the exhaust system is divided into several sections to consider changes in heat transfer characteristics downstream the exhaust valves. Principally, the convective heat transfer is described by the characteristic numbers of Nusselt, Reynolds and Prandtl. However, the phase individual correlation coefficients are derived from 3D CFD investigations of the flow in the exhaust system combined with Low-Re turbulence modelling. Furthermore, heat losses on the valve and the seat ring surfaces are considered by an empirical model approach.
Journal Article

Effect of Thermal Exposure Time on the Relaxation of Residual Stress in High Pressure Die Cast AM60

2016-04-05
2016-01-0423
Magnesium alloys are becoming more commonly used for large castings with sections of varying thicknesses. During subsequent processing at elevated temperatures, residual stresses may relax and become a potential mechanism for part distortion. This study was conducted to quantify the effects of thermal exposure on residual stresses and relaxation in a high pressure die cast magnesium (AM60) alloy. The goal was to characterize relaxation of residual stresses at temperatures that are commonly experienced by body components during a typical paint bake cycle. A residual stress test sample design and quench technique developed for relaxation were used and a relaxation study was conducted at two exposure temperatures (140°C and 200°C) over a range of exposure times (0.25 to 24 hours). The results indicate that a significant amount of residual stress relaxation occurred very rapidly during exposure at both exposure temperatures.
Journal Article

Dynamic Misfire Threshold Determination Based On Zone-Level and Buffer-Level Adaptations for Internal Combustion Engines

2017-03-28
2017-01-0599
Misfire is generally defined as be no or partial combustion during the power stroke of internal combustion engine. Because a misfired engine will dramatically increase the exhaust emission and potentially cause permanent damage to the catalytic converters, California Air Resources Board (CARB), as well as most of other countries’ on-board diagnostic regulations mandates the detection of misfire. Currently almost all the OEMs utilize crankshaft position sensors as the main input to their misfire detection algorithm. The detailed detection approaches vary among different manufacturers. For example, some chooses the crankshaft angular velocity calculated from the raw output of the crankshaft positon sensor as the measurement to distinguish misfires from normal firing events, while others use crankshaft angular acceleration or the associated torque index derived from the crankshaft position sensor readings as the measurement of misfire detection.
Journal Article

Fast Simulation of Wave Action in Engine Air Path Systems Using Model Order Reduction

2016-04-05
2016-01-0572
Engine downsizing, boosting, direct injection and variable valve actuation, have become industry standards for reducing CO2 emissions in current production vehicles. Because of the increasing complexity of the engine air path system and the high number of degrees of freedom for engine charge management, the design of air path control algorithms has become a difficult and time consuming process. One possibility to reduce the control development time is offered by Software-in-the-Loop (SIL) or Hardware-in-the-Loop (HIL) simulation methods. However, it is significantly challenging to identify engine air path system simulation models that offer the right balance between fidelity, mathematical complexity and computational burden for SIL or HIL implementation.
Journal Article

Lubricant-Derived Ash Impact on Gasoline Particulate Filter Performance

2016-04-05
2016-01-0942
The increasing use of gasoline direct injection (GDI) engines coupled with the implementation of new particulate matter (PM) and particle number (PN) emissions regulations requires new emissions control strategies. Gasoline particulate filters (GPFs) present one approach to reduce particle emissions. Although primarily composed of combustible material which may be removed through oxidation, particle also contains incombustible components or ash. Over the service life of the filter the accumulation of ash causes an increase in exhaust backpressure, and limits the useful life of the GPF. This study utilized an accelerated aging system to generate elevated ash levels by injecting lubricant oil with the gasoline fuel into a burner system. GPFs were aged to a series of levels representing filter life up to 150,000 miles (240,000 km). The impact of ash on the filter pressure drop and on its sensitivity to soot accumulation was investigated at specific ash levels.
Journal Article

Rapidly Pulsed Reductants in Diesel NOx Reduction by Lean NOx Traps: Effects of Mixing Uniformity and Reductant Type

2016-04-05
2016-01-0956
Lean NOx Traps (LNTs) are one type of lean NOx reduction technology typically used in smaller diesel passenger cars where urea-based Selective Catalytic Reduction (SCR) systems may be difficult to package . However, the performance of lean NOx traps (LNT) at temperatures above 400 C needs to be improved. The use of Rapidly Pulsed Reductants (RPR) is a process in which hydrocarbons are injected in rapid pulses ahead of a LNT in order to expand its operating window to higher temperatures and space velocities. This approach has also been called Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) by Toyota. There is a vast parameter space which could be explored to maximize RPR performance and reduce the fuel penalty associated with injecting hydrocarbons. In this study, the mixing uniformity of the injected pulses, the type of reductant, and the concentration of pulsed reductant in the main flow were investigated.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

Evaluation of Non-Contiguous PM Measurements with a Resistive Particulate Matter Sensor

2017-03-28
2017-01-0952
The resistive particulate matter sensor (PMS) is rapidly becoming ubiquitous on diesel vehicles as a means to diagnose particulate filter (DPF) leaks. By design the device provides an integrated measure of the amount of PM to which it has been exposed during a defined measurement period within a drive cycle. The state of the art resistive PMS has a large deadband before any valid output related to the accumulated PM is realized. As a result, most DPF monitors that use the PMS consider its output only as an indicator that a threshold quantity of PM has amassed rather than a real-time measure of concentration. This measurement paradigm has the unfortunate side effect that as the PM OBD threshold decreases, or the PMS is used on a vehicle with a larger exhaust volume flow, a longer measurement is required to reach the same PM sensor output. Longer PMS measurement times lead to long particulate filter monitoring durations that may reduce filter monitor completion frequency.
Journal Article

CFD Driven Parametric Design of Air-Air Jet Pump for Automotive Carbon Canister Purging

2017-03-28
2017-01-1316
A jet pump (also known as ejector) uses momentum of a high velocity jet (primary flow) as a driving mechanism. The jet is created by a nozzle that converts the pressure head of the primary flow to velocity head. The high velocity primary flow exiting the nozzle creates low pressure zone that entrains fluid from a secondary inlet and transfers the total flow to desired location. For a given pressure of primary inlet flow, it is desired to entrain maximum flow from secondary inlet. Jet pumps have been used in automobiles for a variety of applications such as: filling the Fuel Delivery Module (FDM) with liquid fuel from the fuel tank, transferring liquid fuel between two halves of the saddle type fuel tank and entraining fresh coolant in the cooling circuit. Recently, jet pumps have been introduced in evaporative emission control system for turbocharged engines to remove gaseous hydrocarbons stored in carbon canister and supply it to engine intake manifold (canister purging).
Technical Paper

Engine and Aftertreatment Co-Optimization of Connected HEVs via Multi-Range Vehicle Speed Planning and Prediction

2020-04-14
2020-01-0590
Connected vehicles (CVs) have situational awareness that can be exploited for control and optimization of the powertrain system. While extensive studies have been carried out for energy efficiency improvement of CVs via eco-driving and planning, the implication of such technologies on the thermal responses of CVs (including those of the engine and aftertreatment systems) has not been fully investigated. One of the key challenges in leveraging connectivity for optimization-based thermal management of CVs is the relatively slow thermal dynamics, which necessitate the use of a long prediction horizon to achieve the best performance. Long-term prediction of the CV speed, unlike the short-range prediction based on vehicle-to-infrastructure (V2I) and vehicle-to-vehicle (V2V) communications-based information, is difficult and error-prone.
Technical Paper

Relevance of Exhaust Aftertreatment System Degradation for EU7 Gasoline Engine Applications

2020-04-14
2020-01-0382
Exhaust aftertreatment systems must function sufficiently over the full useful life of a vehicle. In Europe this is currently defined as 160.000 km. With the introduction of Euro 7 it is expected that the required mileage will be extended to 240.000 km. This will then be consistent with the US legislation. In order to quantify the emission impact of exhaust system degradation, an Euro 7 exhaust aftertreatment system is aged by different accelerated approaches: application of the Standard Bench Cycle, the ZDAKW cycle, a novel ash loading method and borderline aging. The results depict the impact of oil ash on the oxygen storage capacity. For tailpipe emissions, the maximum peak temperatures are the dominant aging factor. The cold start performance is effected by both, thermal degradation and ash accumulation. An evaluation of this emission increase requires appropriate benchmarks.
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