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Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.

Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

An ongoing goal of the Powertrain Control Research Laboratory (PCRL) at the University of Wisconsin-Madison has been to expand and improve the ability of the single cylinder internal combustion research engine to represent its multi-cylinder engine counterpart. To date, the PCRL single cylinder engine test system is able to replicate both the rotational dynamics (SAE #2004-01-0305) and intake manifold dynamics (SAE #2006-01-1074) of a multi cylinder engine using a single cylinder research engine. Another area of interest is the replication of multi-cylinder engine cold start emissions data with a single-cylinder engine test system. For this replication to occur, the single-cylinder engine must experience heat transfer to the engine coolant as if it were part of a multi-cylinder engine, in addition to the other multi-cylinder engine transient effects.

With concerns continuing to grow with respect to global warming from greenhouse gases, further regulations are being examined, developed and are expected for the emission of CO2 as an automobile exhaust. Renewable alternate fuels offer the potential to significantly reduce the CO2 impact of transportation. Hydrogen as a spark - ignition (SI) engine fuel provides this potential for significant CO2 reduction when generated from renewable resources. In addition, hydrogen has advantageous combustion properties including a wide flammable mixture range which facilitates lean burning and high dilution, fast combustion energy release and zero CO2 emissions. However, the high burning rates and fast energy release can lead to excessive in-cylinder pressures and temperatures resulting in combustion knock and high NOx emissions at stoichiometric operation.

A one-dimensional model simulating the oxidation of CO, HC, and NO was developed to predict the gaseous emissions downstream of a diesel oxidation catalyst (DOC). The model is based on the conservation of mass, species, and energy inside the DOC and draws on past research literature. Steady-state experiments covering a wide range of operating conditions (exhaust temperatures, flow rates and gaseous emissions) were performed, and the data were used to calibrate and validate the model. NO conversion efficiencies of 50% or higher were obtained at temperatures between 300°C and 350°C. CO conversion efficiencies of 85% or higher and HC conversion efficiencies of 75% or higher were found at every steady state condition above 200°C. The model agrees well with the experimental results at temperatures from 200°C to 500°C, and volumetric flow rates from 8 to 42 actual m3/min.

The purpose of the European « SPACE LIGHT » (Whole SPACE combustion for LIGHT duty diesel vehicles) 3-year project launched in 2001 is to research and develop an innovative Homogeneous internal mixture Charged Compression Ignition (HCCI) for passenger cars diesel engine where the combustion process can take place simultaneously in the whole SPACE of the combustion chamber while providing almost no NOx and particulates emissions. This paper presents the whole project with the main R&D tasks necessary to comply with the industrial and technical objectives of the project. The research approach adopted is briefly described. It is then followed by a detailed description of the most recent progress achieved during the tasks recently undertaken. The methodology adopted starts from the research study of the in-cylinder combustion specifications necessary to achieve HCCI combustion from experimental single cylinder engines testing in premixed charged conditions.

A study was conducted to assess the effects of a water-diesel fuel emulsion with and without an oxidation catalytic converter (OCC) on steady-state heavy-duty diesel engine emissions. Two OCCs with different metal loading levels were used in this study. A 1988 Cummins L10-300 heavy-duty diesel engine was operated at the rated speed of 1900 rpm and at 75% and 25% load conditions (EPA modes 9 and 11 respectively) of the 13 mode steady-state test as well as at idle. Raw exhaust emissions' measurements included total hydrocarbons (HC), oxides of nitrogen (NOx) and nitric oxide (NO). Diluted exhaust measurements included total particulate matter (TPM) and its primary constituents, the soluble organic (SOF), sulfate (SO42-) and the carbonaceous solids (SOL) fractions. Vapor phase organic compounds (XOC) were also analyzed. The SOF and XOC samples were analyzed for selected polynuclear aromatic hydrocarbons (PAHs).

The development of thermally durable zeolite NH3/Urea-SCR formulations coupled with that of high porosity filters substrates has opened the way to integrate PM and NOx control into a single device, namely an SCR-coated Diesel Particulate Filter (SCRF). A few experimental works are already present in the literature regarding SCRF systems, mainly addressing the DeNOx performances of the system (in both presence and absence of soot) under both steady state and transient conditions. The purpose of the present work is to perform a simulation study focused on phenomena which are expected to play key roles in SCRF systems, such as coupling of reaction and diffusion phenomena, soot effect on DeNOx activity, SCR coating effect on soot regeneration and filtration efficiency and competition between soot oxidation and DeNOx processes involving NO2.

The increased availability of natural gas (NG) in the United States (US) and its relatively low cost versus diesel fuel has increased interest in the conversion of medium duty (MD) and heavy duty (HD) engines to NG fueled combustion systems. The aim for development for these NG engines is to realize fuel cost savings and increase operating range while reduce harmful emissions and maintaining durability. Traditionally, port-fuel injection (PFI) or premixed NG spark-ignited (SI) combustion systems have been used for light duty LD, and MD engines with widespread use in the US and Europe [1]. However, this technology exhibits poor thermal efficiency and is load limited due to knock phenomenon that has prohibited its use for HD engines. Spark Ignited Direct Injection (SIDI) can be used to create a partially stratified combustion (PSC) mixture of NG and air during the compression stroke.

Partially premixed compression ignition combustion is one of the low temperature combustion techniques which is being actively investigated. This approach provides a significant reduction of both soot and NOx emissions. Comparing to the homogeneous charge compression ignition mode, PPCI combustion provides better control on ignition timing and noise reduction through air-fuel mixture stratification which lowers heat release rate compared to other advanced combustion modes. In this work, CFD simulations were conducted for a low and a high air-fuel mixture stratification cases on a light-duty optical engine operating in PPCI mode. Such conditions for PRF70 as fuel were experimentally achieved by injection timing and spray targeting at similar thermodynamic conditions.

For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.

The automotive industry is striving to adopt model-based engine design and optimization procedures to reduce development time and costs. In this scenario, first-principles gas dynamic models predicting the mass, energy and momentum transport in the engine air path system with high accuracy and low computation effort are extremely important today for performance prediction, optimization and cylinder charge estimation and control. This paper presents a comparative study of two different modeling approaches to predict the one-dimensional unsteady compressible flow in the engine air path system. The first approach is based on a quasi-3D finite volume method, which relies on a geometrical reconstruction of the calculation domain using networks of zero-dimensional elements. The second approach is based on a model-order reduction procedure that projects the nonlinear hyperbolic partial differential equations describing the 1D unsteady flow in engine manifolds onto a predefined basis.

This paper describes the development, application and comparison of two different non-linear numerical codes, respectively based on a 1D and 3D schematization of the geometrical domain, for the prediction of the acoustic behavior of common silencing devices for i.c. engine pulse noise abatement. A white noise approach has been adopted and applied to predict the attenuation curves of silencers in the frequency domain, while a non-reflecting boundary condition was used to represent an anechoic termination. Expansion chambers, Helmholtz and column resonators, Herschel-Quincke tubes have been simulated by both the 1D and the 3D codes and the results compared to the available linear acoustic analytical solutions. Finally, a hybrid approach, in which the CFD code has been integrated with the 1D model, is described and applied to the simulation of a single cylinder engine. The computed results are compared to the measured pressure waves and emitted sound pressure level spectra.

In this paper, computation fluid dynamics (CFD) simulations are employed to describe the effect of flow parameters on the formation of soot and NOx in a heavy duty engine under low load and high load. The complexity of diesel combustion, specially when soot, NOx and other emissions are of interest, requires using a detailed chemical mechanism to have a correct estimation of temperature and species distribution. In this work, Multiple Representative Interactive Flamelets (MRIF) method is employed to describe the chemical reactions, ignition, flame propagation and emissions in the engine. A phenomenological model for soot formation, including soot nucleation, coagulation and oxidation with O2 and OH is incorporated into the flamelet combustion model. Different strategies for modelling NOx are chosen to take into account the longer time scale for NOx formation. The numerical results are compared with experimental data to show the validity of the model for the cases under study.

The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).

An experimental and computational study was performed to evaluate the performance of the CRT™ technology with an off-highway engine with a cooled low pressure loop EGR system. The MTU-Filter 1D DPF code predicts the particulate mass evolution (deposition and oxidation) in a diesel particulate filter (DPF) during simultaneous loading and during thermal and NO2-assisted regeneration conditions. It also predicts the pressure drop across the DPF, the flow and temperature fields, the solid filtration efficiency and the particle number distribution downstream of the DPF. A DOC model was also used to predict the NO2 upstream of the DPF. The DPF model was calibrated to experimental data at temperatures from 230°C to 550°C, and volumetric flow rates from 9 to 39 actual m3/min.

The objective of this research was to study the effects of a CCRT®, henceforth called Diesel Oxidation Catalyst - Catalyzed Particulate Filter (DOC-CPF) system on particulate and gaseous emissions from a heavy-duty diesel engine (HDDE) operated at Modes 11 and 9 of the old Environmental Protection Agency (EPA) 13-mode test cycle Emissions characterized included: total particulate matter (TPM) and components of carbonaceous solids (SOL), soluble organic fraction (SOF) and sulfates (SO4); vapor phase organics (XOC); gaseous emissions of total hydrocarbons (HC), carbon monoxide (CO), oxides of nitrogen (NOx), nitric oxide (NO) and nitrogen dioxide (NO2), oxygen (O2) and carbon dioxide (CO2); and particle size distributions at normal dilution ratio (NDR) and higher dilution ratio (HDR). Significant reductions were observed for TPM and SOL (>90%), SOF (>80%) and XOC (>70%) across the DOC-CPF at both modes.