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OBD requirements for aftertreatment system components require monitoring of the individual system components. One such component can be an NH3-SCR catalyst for NOx reduction. An OBD method that has been suggested is to generate positive or negative spikes in the inlet NH3 concentration, and monitor the outlet NOx transient response. A slow response indicates that the catalyst is maintaining its NH3 storage capacity, and therefore it is probably not degraded. A fast response indicates the catalyst has lost NH3 storage capacity, and may be degraded. The purpose of the work performed at Southwest Research Institute was to assess this approach for feasibility, effectiveness and practicality. The presentation will describe the work performed, results obtained, and implications for applying this method in test laboratory and real-world situations. Presenter Gordon J. Bartley, Southwest Research Institute

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another type such as a modern light-duty. This study was an attempt to compare the performance of several fuels in an identical environment, using the same engine, for direct comparison.

Work was performed to determine the feasibility of operating heavy-duty natural gas engines over a wide range of fuel compositions by evaluating engine performance and emission levels. Heavy-duty compressed natural gas engines from various engine manufacturers, spanning a range of model years and technologies, were evaluated using a diversity of fuel blends. Performance and regulated emission levels from these engines were evaluated using natural gas fuel blends with varying methane number (MN) and Wobbe Index in a dynamometer test cell. Eight natural gas blends were tested with each engine, and ranged from MN 75 to MN 100. Test engines included a 2007 model year Cummins ISL G, a 2006 model year Cummins C Gas Plus, a 2005 model year John Deere 6081H, a 1998 model year Cummins C Gas, and a 1999 model year Detroit Diesel Series 50G TK. All engines used lean-burn technology, except for the ISL G, which was a stoichiometric engine.

The diesel engine can be an effective solution to meet future greenhouse gas and fuel economy standards, especially for larger segment vehicles. However, a key challenge facing the diesel is the upcoming LEV III and Tier 3 emission standards which will require significant reductions in hydrocarbon (HC) and oxides of nitrogen (NOx) emissions. The challenge stems from the fact that diesel exhaust temperatures are much lower than gasoline engines, so the time required to achieve effective emissions control after a cold-start with typical aftertreatment devices is considerably longer. To address this challenge, a novel diesel cold-start emission control strategy was investigated on a 2L class diesel engine. This strategy combines several technologies to reduce tailpipe HC and NOx emissions before the start of the second hill of the FTP75. The technologies include both engine tuning and aftertreatment changes.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Battery temperature variations have a strong effect on both battery aging and battery performance. Significant temperature variations will lead to different battery behaviors. This influences the performance of the Hybrid Electric Vehicle (HEV) energy management strategies. This paper investigates how variations in battery temperature will affect Lithium-ion battery aging and fuel economy of a HEV. The investigated energy management strategy used in this paper is the Equivalent Consumption Minimization Strategy (ECMS) which is a well-known energy management strategy for HEVs. The studied vehicle is a Honda Civic Hybrid and the studied battery, a BLS LiFePO4 3.2Volts 100Ah Electric Vehicle battery cell. Vehicle simulations were done with a validated vehicle model using multiple combinations of highway and city drive cycles. The battery temperature variation is studied with regards to outside air temperature.

Diesel Cylinder Deactivation (CDA) has been shown in previous work to increase exhaust temperatures, improve fuel efficiency, and reduce engine-out NOx for engine loads up to 3 bar BMEP. The purpose of this study is to determine whether or not the turbocharger needs to be altered when implementing CDA on a diesel engine. This study investigates the effect of CDA on exhaust temperature, fuel efficiency, and turbocharger performance in a 15L heavy-duty diesel engine under low-load (0-3 bar BMEP) steady-state operating conditions. Two calibration strategies were evaluated. First, a “stay-hot” thermal management strategy in which CDA was used to increase exhaust temperature and reduce fuel consumption. Next, a “get-hot” strategy where CDA and elevated idle speed was used to increase exhaust temperature and exhaust enthalpy for rapid aftertreatment warm-up.

Dedicated EGR (D-EGR) is an EGR strategy that uses in-cylinder reformation to improve fuel economy and reduce emissions. The entire exhaust of a sub-group of power cylinders (dedicated cylinders) is routed directly into the intake. These cylinders are run fuel-rich, producing H2 and CO (reformate), with the potential to improve combustion stability, knock tolerance and burn duration. A 2.0 L turbocharged D-EGR engine was packaged into a 2012 Buick Regal and evaluated on drive cycle performance. City and highway fuel consumption were reduced by 13% and 9%, respectively. NOx + NMOG were 31 mg/mile, well below the Tier 2 Bin 5 limit and just outside the Tier 3 Bin 30 limit (30 mg/mile).

Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

The most recent 2010 emissions standards for heavy-duty engines have established a tailpipe limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, it is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

Low Temperature Combustion (LTC) engines are promising to improve powertrain fuel economy and reduce NOx and soot emissions by improving the in-cylinder combustion process. However, the narrow operating range of LTC engines limits the use of these engines in conventional powertrains. The engine’s limited operating range can be improved by taking advantage of electrification in the powertrain. In this study, a multi-mode LTC-SI engine is integrated with a parallel hybrid electric configuration, where the engine operation modes include Homogeneous Charge Compression Ignition (HCCI), Reactivity Controlled Compression Ignition (RCCI), and conventional Spark Ignition (SI). The powertrain controller is designed to enable switching among different modes, with minimum fuel penalty for transient engine operations.

Past experimental studies conducted by the current authors on a 13 liter 16.7:1 compression ratio heavy-duty diesel engine have shown that diesel-Compressed Natural Gas (CNG) Reactivity Controlled Compression Ignition (RCCI) combustion targeting low NOx emissions becomes progressively difficult to control as the engine load is increased. This is mainly due to difficulty in controlling reactivity levels at higher loads. For the current study, CFD investigations were conducted in CONVERGE using the SAGE combustion solver with the application of the Rahimi mechanism. Studies were conducted at a load of 5 bar BMEP to validate the simulation results against RCCI experimental data. In the low load study, it was found that the Rahimi mechanism was not able to predict the RCCI combustion behavior for diesel injection timings advanced beyond 30 degCA bTDC. This poor prediction was found at multiple engine speed and load points.

Gasoline Direct Injection (GDI) engines have been widely adopted by manufacturers in the light-duty market due to their fuel economy benefits. However, several studies have shown that GDI engines generate higher levels of particulate matter (PM) emissions relative to port fuel injected (PFI) engines and diesel engines equipped with optimally functioning diesel particulate filters (DPF). With stringent particle number (PN) regulations being implemented in both, the European Union and China, gasoline particulate filters (GPF) are expected to be widely utilized to control particulate emissions. Currently, evaluating GPF technologies on a vehicle can be challenging due to a limited number of commercially available vehicles that are calibrated for a GPF in the United States as well as the costs associated with vehicle procurement and evaluations utilizing a chassis dynamometer facility.

In-cylinder emission controls were the focus for diesel engines for many decades before the emergence of diesel aftertreatment. Even with modern aftertreatment, control of in-cylinder processes remains a key issue for developing diesel vehicles with low tailpipe emissions. A reduction in in-cylinder emissions makes aftertreatment more effective at lower cost with superior fuel economy. This paper describes a study focused on an in-cylinder combustion control approach using a Delphi E3 flexible fuel system to achieve low engine-out NOx and PM emissions. A 2003 model year Detroit Diesel Corporation Series 60 14L heady-duty diesel engine, modified to accept the Delphi E3 unit injectors, and ultra low sulfur fuel were used throughout this study. The process of achieving premixed low temperature combustion within the limited range of parameters of the stock ECU was investigated.

Historically, heavy-duty diesel (HDD) engine designs have evolved along the path of increased power output, improved fuel efficiency and reduced exhaust gas emissions, driven both by regulatory and market requirements. The various technologies employed to achieve this evolution have resulted in ever-increasing engine operating cylinder pressures, higher than for any other class of internal combustion engine. Traditional HDD engine design architecture limits peak cylinder pressure (PCP) to about 200 bar (2900 psi). HDD PCP had steadily increased from the early 1970's until the mid 2000's, at which point the structural limit was reached using traditional methods and materials. Specific power output reversed its historical trend and fell at this time as a result of technologies employed to satisfy new emissions requirements, most notably exhaust gas recirculation (EGR).

Nitrous Oxide (N₂O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 (298-310 times more potent than carbon dioxide (CO₂)). As a result, any aftertreatment system that generates N₂O must be well understood to be used effectively. Under low temperature conditions, N₂O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N₂O formed by the thermal decomposition of ammonium nitrate. Ammonium nitrate and N₂O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO₂). This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO₂ ratio above 1. However, N₂O has also been observed at relatively high temperatures, in the region of 500°C.

Experiments were performed on a 2.4L boosted, MPI gasoline engine, equipped with a low-pressure loop (LPL) cooled EGR system and an advanced ignition system, using fuels with varying anti-knock indices. The fuels were blends of 87, 93 and 105 Anti-Knock Index (AKI) gasoline. Ignition timing and EGR sweeps were performed at various loads to determine the tradeoff between EGR level and fuel octane rating. The resulting engine data was analyzed to establish the relationship between the octane requirement and the level of cooled EGR used in a given application. In addition, the combustion difference between fuels was examined to determine the effect that fuel reactivity, in the form of anti-knock index (AKI), has on EGR tolerance and burn rate. The results indicate that the improvement in effective AKI of the fuel from using EGR is constant across commercial grade gasolines at about 0.5 ON per % EGR.