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The design and development of an instrument for the measurement of total hydrocarbons in diesel exhaust are described, and its ability to measure steady-state and transient hydrocarbon emissions is indicated. The two-section system comprises a sampling train and flame-ionization detector and a chromatograph electrometer, recorder and backpressure regulator. A mixture of 40% H2 and 60% He was found to be the best fuel for low O2 response with the system. The method has been used for more than a year in evaluating hydrocarbon emissions from a wide variety of diesel engines under a number of typical operating conditions. The greatest advantage of the high-temperature system is its potential for expressing the total hydrocarbon content in diesel exhaust.

In an attempt to characterize emissions from small air-cooled utility engines, five gasoline-fueled models were operated over a variety of speeds and loads, and important exhaust constituents were measured. These emissions included hydrocarbons, CO, CO2, NO, O2, aldehydes, light hydrocarbons, particulates, and smoke. Emissions of SOx were estimated on the basis of the fuel consumed; evaporative losses of hydrocarbons were also estimated. The impact of small engine emissions was calculated on the basis of the test results and information on national engine populations and usage. From these data, it appears that the 50 million or more small engines currently being used account for only a small part of pollutants from all sources.

The research program on which this paper is based included both laboratory emission measurements and extrapolation of results to the national population of heavy-duty farm, construction, and industrial engines. Emission tests were made on four gasoline engines and eight diesel engines typical of those used in F, C, and I equipment. Gaseous and particulate emissions were measured during engine operation on well-accepted steady-state procedures, and diesel smoke was measured during both steady-state conditions and the Federal smoke test cycle. Emissions measured were hydrocarbons, CO, CO2, NO, NOx, O2, aliphatic aldehydes, light hydrocarbons, particulate, and smoke. Emission of sulfur oxides (SOx) was estimated on the basis of fuel consumed, and both evaporative and blowby hydrocarbons were also estimated where applicable (gasoline engines only). Data on emissions obtained from this study were compared with those available in the literature, where possible.

Seven motorcycles, ranging in size from 100 to 1200 cm3, were tested for emissions characterization purposes. They were operated on the federal seven-mode test procedure (for 1971 and older light-duty vehicles), the federal LA-4 test procedure (for 1972 and later LDVs), and under a variety of steady-state conditions. Four of the machines tested had 4-stroke engines, and the other three had 2-stroke engines. Emissions which were measured included hydrocarbons, CO, CO2, NO, NOx, O2, aldehydes, light hydrocarbons, particulates, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbon losses were also estimated. Crankcase “blowby” emissions from one 4-stroke machine were measured. The impact of motorcycles on national pollutant totals was estimated, based on the test results and information from a variety of sources on national population and usage of motorcycles.

This paper describes a research program on exhaust emissions from snowmobile engines, including both emissions characterization and estimation of national emissions impact. Tests were conducted on three popular 2-stroke twins and on one rotary (Wankel) engine. Emissions that were measured included total hydrocarbons, (paraffinic) hydrocarbons by NDIR, CO, CO2, NO (by two methods), NOx, O2, aldehydes, light hydrocarbons, particulate, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbons were projected to be negligible for actual snowmobile operation. During emissions tests, intake air temperature was controlled to approximately -7°C (20°F), and room air at approximately 24°C (75°F) was used for engine cooling. Based on test results and the best snowmobile population and usage data available, impact of snowmobile emissions on a national scale was computed to be minimal.

To characterize exhaust emissions from water-cooled 2-stroke outboard motors (the predominant type), four new motors were tested on dynamometer stands. The engines ranged from 4-65 hp in size, and operating conditions were chosen along lines of simulated boat loading. All the measurements were taken at steady-state conditions. Emission concentrations were measured in raw exhaust gas and after the gases had been bubbled through water in a specially constructed tank. Constituents measured included hydrocarbons, CO, CO2, NO, NOx, O2, light hydrocarbons, and aldehydes. Emissions of sulfur oxides (SOx) were estimated on the basis of fuel consumed, and all the exhaust emissions data were used with available information on population and usage of motors to estimate exhaust emission factors and national exhaust emissions impact.