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This paper describes the third generation of the partial zero emission vehicle (P-ZEV) technology originally adopted on the Nissan Sentra CA sold in California. The 2000 Nissan Sentra CA became the world's first gasoline-fueled car to qualify for P-ZEV credits from the California Air Resources Board (CARB). The third-generation P-ZEV system has been substantially reduced in size and cost, compared with the Sentra CA system, enabling it to be used on high-volume models. This system complies with the P-ZEV requirements, including those for zero evaporative emissions and Onboard Diagnostics II (OBD-II). To achieve a more compact and lower-cost system, an ultra-thin-walled catalyst substrate, the world's first to attain a 1.8-mil wall thickness, has been adopted along with catalysts that display excellent low-temperature activity. As a result, low-temperature catalyst activity has been significantly improved.

Hydrocarbons and other organic materials emitted from S.I. engines cause ozone to form in the air. Since each species of organic materials has a different reactivity, exhaust components affect ozone formation in different ways. The effects of exhaust emission control devices and fuel properties on speciated emissions and ozone formation were examined by measuring speciated emissions with a gas chromatograph and a high-performance liquid chromatograph. In the case of gasoline fuels, catalyst systems with higher conversion rates such as close-coupled catalyst systems are effective in reducing alkenes and aromatics which show high reactivities to ozone formation. With deterioration of the catalyst, non-methane organic gas (NMOG) emission increases, but the specific reactivity of ozone formation tends to decrease because of the increase in alkane contents having low MIR values.

Gas chromatographic methods for analyzing hydrocarbon species in vehicle exhaust emissions were compared in terms of their collection efficiency, detection limit, repeatability and number of species detected using cylinder gas and tailpipe emission samples. The main methods compared were a Tenax cold trap injection (TCT) method (C5-C12 HCs) and a cold trap injection (CTI) method (C2-C4 HCs; C5-C12 HCs). Our own direct (DIR) method was used to confirm the collection efficiencies. Both methods yielded good results, but the CTI method showed low collection efficiency for some C2-C4 HCs. Measurement of individual species is needed with this method for accurate analysis of tailpipe emissions. Both the CTI method and the TCT method combined with the DIR method for determining C2-C4 HCs yielded nearly the same ozone specific reactivity values for the NMHC species analyzed.

In 1994, the California Air Resources Board implemented low-emission vehicle (LEV) standards with the aim of improving urban air quality. One feature of the LEV standards is the increasingly tighter regulation of non-methane organic gases (NMOG), taking into account ozone formation, in addition to the existing control of non-methane hydrocarbons (NMHC). Hydrocarbons and other organic gases emitted by S.I. engines have been identified as a cause of atmospheric ozone formation. Since the reactivity of each chemical species in exhaust emissions differs, the effect on ozone formation varies depending on the composition of the exhaust gas components. This study examined the effect of different engine types, fuel atomization conditions, turbulence and emission control systems on emission species and specific reactivity. This was done using gas chromatographs and a high-performance liquid chromatograph to analyze exhaust emission species that affect ozone formation.

New technologies are needed to reduce cold-start emissions in order to meet the more stringent regulations that will go into effect in Europe (EC2000 or EC2005) and in California (ULEV), especially for larger engines such as 6- and 8-cylinder units. One new technology in this regard is the electrically heated catalyst (EHC). However, the use of EHCs alone is not sufficient to achieve the necessary reduction in emissions. This paper discusses techniques for effectively combining the elements of an EHC system, including the introduction of secondary air into the exhaust, improved control of the air/fuel ratio, and an electric power supply method for EHCs. It is shown that it is more effective to promote exothermic reactions in the exhaust manifold than at the EHC. A suitable method for this purpose is to introduce secondary air into the exhaust near the exhaust valves.

Fuel economy can be improved by reducing engine displacement, thanks to the resulting smaller friction losses and pumping losses. However, smaller engines frequently operate at high-engine speed and high-load, when pressure on the accelerator increases during acceleration and at high speed. To protect exhaust system components from thermal stress, exhaust gas temperature is reduced by fuel enrichment. To improve fuel economy, it is important to increase the frequency of stoichiometric operation at high-engine speed and high-load. Usually, the start timing of fuel enrichment is based upon temperature requirements to protect the catalyst. In the high-engine speed and high-load zone, the threshold temperature of catalyst protection is attained after some time because of the heat mass. Therefore, stoichiometric operation can be maintained until the catalyst temperature reaches the threshold temperature.

A compact, high-performance and durable metal-supported catalyst has been developed by using the properties of the metal support effectively. The advantages of the metal-surpported catalyst against the ceramic-supported one are higher geometrical surface area, higher heat conductivity and thinner wall thickness. Higher geometlical surface area and higher heat conductivity lead to higher conversion efficiency after durability test and it allows reduction in catalyst volume. And the thinner wall thickness lowers gas flow resistance. But also, the metal-supported catalyst has the disadvantage of larger heat expansion and it requires special structure and material.

A new gasoline-fueled Super Ultra Low Emissions Vehicle (SULEV) technology has been developed that meets the California Air Resources Board's (CARB) most stringent tailpipe emission levels and zero evaporative emissions, while fulfilling all On-Board Diagnostic II (OBD II) requirements. This paper will describe the various new technologies used in achieving the SULEV standards, such as the HC trap system with an ultra-thin wall substrate for the improvement of catalyst light-off time, and an electrically actuated swirl control valve for reducing cold-start emissions. In addition, a control approach to stabilizing NOx emissions will also be discussed.

Compared with in-line 4-cylinder engines, V-6 engines show a slower rise in exhaust gas temperature, requiring a longer time for catalysts to become active, and they also emit higher levels of engine-out emissions. In this study, The combination of a new type of catalyst, and optimized ignition timing and air-fuel ratio control achieved quicker catalyst light-off. Additionally, engine-out emissions were substantially reduced by using a swirl control valve to strengthen in-cylinder gas flow, adopting electronically controlled exhaust gas recirculation (EGR), and reducing the crevice volume by decreasing the top land height of the pistons. A vehicle incorporating these emission reduction technologies reduced the emission level through the first phase of the Federal Test Procedure (FTP) by 60-70% compared with the Tier 1 vehicle.

This paper describes new technologies for achieving exhaust emission levels much below the SULEV standards in California, which are the most stringent among the currently proposed regulations in the world. Catalyst light-off time, for example, has been significantly reduced through the adoption of a catalyst substrate with an ultra-thin wall thickness of 2 mil and a catalyst coating specifically designed for quicker light-off. A highly-efficient HC trap system has been realized by combining a two-stage HC trap design with an improved HC trap catalyst. The cold-start HC emission level has been greatly reduced by an electronically actuated swirl control valve with a high-speed starter. Further, an improved Air Fuel Ratio (AFR) control method has achieved much higher catalyst HC and NOx conversion efficiency.