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In order to reduce fine particle emission, a diesel particulate filter (DPF) has begun to be equipped to a diesel engine. During regeneration of DPF, nanoparticles are known to be formed downstream of DPF. VOCs emission during regeneration is of interest in view of toxicity and formation mechanism of nanoparticles. A heavy duty diesel engine equipped with DPF was investigated to measure particle and VOCs emissions using PTR-TOFMS (Proton Transfer Reaction - Time of Flight Mass Spectrometer). PTR-TOFMS is a new on-line mass spectrometer using chemical ionization and its application to engine exhaust measurements is new. During active regeneration of the DPF, fine particle emission was increased by nucleation. But VOCs as well as THC emissions increased prior to particle increase. After the regeneration the particle and VOCs emissions decreased immediately to the level of normal operation.

Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.

In-cylinder total sampling technique utilizing a single-cylinder diesel engine equipped with hydraulic valve actuation system has been developed. In this study, particulate matter (PM) included in the in-cylinder sample gas was collected on a quartz filter, and the polycyclic-aromatic hydrocarbons (PAHs) component and soot were subsequently quantified by thermal desorption-gas chromatograph mass spectrometry (TD-GCMS) and a carbon analyzer, respectively. Cylinder-averaged histories of PAHs and soot were obtained by changing the sampling timing. It was found that decreasing intake oxygen concentration suppresses in-cylinder soot oxidation, and the fuel with higher aromatic and naphthenic contents accelerates soot production.