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HC emission standards will be tightened during the 1990's in the US. A key issue in reducing HC emission is improving the warm-up characteristics of catalysts during the cold start of engines. For this purpose, studies are under way on reduction of heat mass of ceramic substrates. Reduction of cell walls in substrates to thickness smaller than the current thickness of 12mil or 6mil has resulted in reduced heat mass, and also reduced flow restriction of substrates. The warm-up characteristics of low bulk density catalysts are better than those of high bulk density, i.e., the warm-up characteristics of thinner wall or lower cell density catalysts are better than those of thicker wall or higher cell density catalysts. A relationship between geometric surface area and warm-up characteristics is observed.

A new type of catalytic converter has been developed for the coming TLEV (Transitional Low Emission Vehicle) standards. It is a “Front Curve Catalytic Converter (FCCC)” using a curved cordierite ceramic honeycomb substrate. During this development, an optimum location and volume of the front curve catalytic converter were determined from the view points of thermal deterioration of the catalyst and hydrocarbon conversion performance. Based on CAE (Computer Aided Engineering) analysis, the best curvature radius of the substrate was selected to minimize a pressure drop of the front curve catalytic converter. The emission conversion and light-off performances of the front curve catalytic converter were compared with a conventional straight design. A series of durability tests; hot vibration, engine dynamometer and vehicle fleet tests were also conducted to confirm the reliability of the new front curve catalytic converter.