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A new analytical method for the automobile industry has been developed using a pulsed tunable laser system and a Reflectron time-of-flight mass spectrometer. The goal was to achieve the following conditions: High time resolution (〈100ms), high sensitivity (down to 1 ppm), high accuracy (10%) and applicability to most exhaust emission components. The main problem is the large number of components with very different and fast varying concentrations. For a preliminary list of 25 exhaust emission components, all necessary parameters have been determined. First results obtained from a real exhaust gas sample will be presented.

Time-resolved concentrations of formaldehyde and acetaldehyde in the exhaust gas have been investigated during transient motor operation, such as sudden change of speed and load, misfiring and switching off the fuel mixture control. To this purpose, a new laser mass spectrometer has been applied which is capable of measuring the concentrations of individual exhaust compounds with 1 ppm sensitivity at a sampling rate of 50 Hz corresponding to a sampling period of 20 ms. At sudden speed changes, high concentrations of aldehydes are observed, in particular during the phase of decreasing speed, i.e. after closing the throttle valve.