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Prior work by various OEMs has identified the ability of phosphorus-containing compounds to interfere with the efficiency of modern emissions control systems utilized by gasoline-powered vehicles. Considering the growing societal concerns about ecological effects of exhaust emissions, greenhouse gas emissions and related global climatic changes, it becomes desirable to examine the effect of reduced phosphorous (P) deposits in various vehicle makes, models and types of service, over the lifetime of a vehicle's operation. This paper assesses advantages and disadvantages of various methods to examine the path of P transfer throughout exhaust catalytic systems. Test types discussed include examples of bench testing focusing on catalyst compatibility, dyno mileage accumulation and field trial examinations.

Using a seven-step quality improvement process, some of the engine build-up factors adversely influencing the severity and precision of the Sequence VI dynamometer test were examined. Insights from engineering (theory) and database (statistical) analyses enabled a 23 factorial experiment to identify oil ring tension, piston ring side clearance, and piston fit as critical parameters in a 3-oil, 9-engine, 28-test program. High ring tension was shown to emphasize the friction reducing capability of higher performing oils and the deficiency of a lower performing oil. Interactions were noted. A helpful correlation of test severity with the engine calibration indicators was shown.

There is concern over water-in-oil emulsion formation in passenger cars in the field. Crankcase pressure measurements in the ASTM Sequence IID rust test have been used to indicate possible emulsion formation tendencies of lubricants. This paper presents the development of a short duration emulsion fleet test procedure which demonstrates low car-to- car variability and correlates well with a previous fourmonth winter emulsion fleet test. Physical emulsion characteristics and used oil analyses are described. Evaluation of both Sequence IID reference oils and commercial oils in this field test reveals a lack of correlation between Sequence IID crankcase pressure results and field performance. The new procedure has been applied to investigate the impact of additive and base oil variations on the emulsion-forming tendencies of lubricants in the field. Base oil variables such as viscosity grade, composition, and volatility were evaluated.

Motorcycle manufacturers have recognized that highly friction modified passenger car oils can be deleterious to clutch performance, leading to clutch slippage. To address this issue, a JASO specification for four-stroke motorcycle oils was developed in 1999, categorizing oils into high friction oils termed JASO MA and low friction oils termed JASO MB. The high friction oils were preferred for most motorcycles where the engine oil also lubricates the clutch and gears. New motorcycle transmission technologies have increased the number of dry clutch applications which has led to an increased demand for JASO MB oils to improve fuel efficiency. While JASO MB oils contain friction modifiers to improve initial fuel economy, the motorcycle specifications have not addressed the fuel economy durability of motorcycle oils.

Our basic understanding of the chemical and physical nature of soot, its interaction with lubricant components and its role in promoting wear and oil thickening in heavy duty diesel engines continues to grow. Our current study in the GM 6.5L engine focuses on examining the effects of variations in base stock type (Group I vs. Group II), viscosity index improver or viscosity modifier (VM) chemistry (OCP vs. dispersant OCP), zinc dithiophosphate (ZDP) type and dispersant type (low MW vs. high MW) on roller follower wear, viscosity growth and other measured responses. In this study, more robust fluids were tested producing very low wear results and minimal viscosity increase of the lubricant. Fluids containing dispersant OCP (DOCP) and high MW dispersant produced a lower degree of wear, whereas varying the ZDP type (1° vs. 2°) showed no effect on wear. The use of Group II base stocks was associated with significantly lower viscosity increases.

Water-emulsified diesel fuel technology has been proven to reduce nitrogen oxides (NOx) and particulate matter (PM) simultaneously at relatively low cost compared to other pollution-reducing strategies. While the mechanisms which result in these reductions have been postulated, the development of new analytical tools to measure in-cylinder soot formation using optically accessible engines can lead to a deeper understanding of combustion and the chemical and physical mechanisms when water is present during combustion. In this study, an optically accessible single cylinder engine was used to study how water brought into the combustion chamber via an emulsified fuel changes the combustion process and thereby reduces emissions. In-cylinder measurements of relative soot concentrations were used to determine the effect of water-emulsified fuel on soot formation.

Water-emulsified diesel fuel technology has been proven to reduce nitrogen oxides (NOx) and particulate matter (PM) simultaneously at relatively low cost compared to other pollution-reducing strategies. The value of this technology is that it requires absolutely no engine adjustments or modifications to reduce harmful emissions. Technologies that break the NOx -particulate trade-off are virtually non-existent, therefore understanding how the water contained in an emulsified fuel can reduce both NOx and PM simultaneously is critical. To understand this phenomenon, emulsified fuels with varying water levels (0 to 20%) were evaluated in a multi-cylinder marine engine using three different injection timings. This testing in an actual engine confirms that as the water level is increased the amount of NOx and PM are reduced without compromising engine performance.

The use of a copper diesel fuel additive in an emission control system improves particulate oxidation. This expands the operability of available systems by reducing the particulate mass loading and related external energy consumption required during regeneration. Easier, more frequent regenerations improve overall engine/system efficiency and reduce thermal stress on filtration media. Procedures for optimizing additive use are presented. In addition, the results from a health study are reviewed.

This paper describes the development of a image analysis system that can be used to rate injectors from the Cummins L10 Injector Depositing Test. In the procedure, injectors are mounted on a computer controlled turntable and scanned using a CCD camera focused on the labyrinth flow area of the injector. The scanned monochrome images are processed and assigned an average gray scale rating. Results from the image analysis system are compared to the modified CRC Piston and Ring Rating method currently used within the Cummins test procedure. To do this, a series of injectors that have been rated by trained raters at a recent workshop were also rated via the image analysis system. The image analysis system ratings demonstrated a strong correlation (R = 0.85) to the CRC ratings. Using these same injectors, the image analysis method shows improvements in repeatability and reproducibility of approximately 50% over the current procedure.

The regenerative characteristics of a diesel particulate filter have been experimentally examined. The effect of particulate accumulation on system backpressure was of primary interest. To improve particulate regeneration, a copper compound was added to the fuel. The test results demonstrate that copper-containing fuel additives improve the regeneration characteristics of the filter, maintaining system backpressure at an acceptable level. Improved regeneration performance is expected to extend the operating range and life of the filter system. A model describing regeneration characteristics was developed to indicate the benefits of fuel copper concentration in controlling system backpressure.

Piston ring land deposit formation is a key performance criterion in the ASTM Sequence IIIE engine test. Because engine testing of lubricant formulation variables is expensive, a ring land deposit bench test was developed replicating the Sequence IIIE bulk oxidation and deposit formation mechanisms. Following an initial bulk oxidation of the candidate oils, deposits similar in chemical composition and morphology to Sequence IIIE ring land deposits are produced in a modified panel coker apparatus. Good correlation with the ASTM Sequence IIIE engine test has been established. Lubricant additive and base oil effects on oxidation control and deposit formation have been investigated. Their influences on lubricant formulation strategy are discussed.

The technology has been developed which will allow manufacturers to produce cars capable of running on methanol/gasoline blends with a methanol content up to 85% (i.e., M85). These cars will operate on varying methanol/gasoline ratios without any adjustments from the driver. The dual-fuel capability is attractive since vehicle use will not be handicapped by a restricted fuel distribution system. In addition, it provides the option of running on an environmentally “cleaner” fuel where it is available. The advent of fuel-flexible vehicles encourages the development of lubricants which will satisfy the demands of both fuels. The unique properties of methanol, however, increase the challenges of meeting the lubricant performance needs. Field and engine dynamometer testing have been aimed at understanding the response of key lubricant variables with M85. Short-trip, cold-weather conditions have been of particular concern.

A test was developed by the Cummins Engine Company to evaluate Diesel fuel quality and potential additive effects. This test utilizes a Cummins L10 Diesel engine with a PT fuel system and stepped plunger injectors. A modified CRC rating system is used to quantify deposit levels. This paper further investigates the L10 Injector Depositing Test and will focus on Diesel fuel and additive variables. In the original work, the bulk of the data was collected on an industry standard reference fuel, Cat 1-H, as opposed to commercially available Diesel fuels. Commercially available Diesel fuel varies in composition with regard to sulfur level, percent aromatics, final distillation end point, and cetane number. To evaluate these fuel properties and their possible effects on injector deposit formation, two test matrices were designed. The first experiment is a 12-run fractional factorial design with four factors: additive level, sulfur, aromatics, and 90 percent distillation point (T90).

A test method has been developed which provides for the rapid measurement of the scuffing performance of diesel fuel using the Ball-On-Cylinder Lubricity Evaluator (BOCLE). A test can be completed in less than one hour. Data has been generated indicating that the method achieves good discrimination between fuels of varying lubricity and correlates well with fuel performance as measured in pump tests.

Accurate, timely field test results are necessary to develop and validate lubricants meeting frequently changing performance requirements. Field tests can also provide valuable information about performance deficiencies (e.g., soot related wear) which are not apparent in laboratory development tests. Since field tests are time intensive and increasingly expensive, it is imperative that the data generated provide meaningful results with reasonable expenditures. The data generation and analysis process are being constantly improved according to the principles of quality management. Part of the process improvement focuses on accurate, realistic treatment of the data since more variation is typically observed in field tests than in laboratory tests. One of the most difficult analytical processes occurs with oil consumption data.

The effects of gasoline composition, as represented in typical regular and premium unleaded gasolines and fuel additives, on Combustion Chamber Deposits (CCD) were investigated in BMW and Ford tests. In addition, the influences of engine lubricant oil and ethanol oxygenate on CCD were examined in Ford 2.3L engine dynamometer tests. Also, additive effects of packages based on mineral oil fluidizers versus synthetic fluidizers were studied in several different engines for CCD. Finally, a new method for evaluating the effect of fluidizers on valve sticking is introduced.

The International Lubricant Standardization and Approval Committee (ILSAC) GF-2 requirements for Passenger Car Motor Oils (PCMOs) will lower phosphorus limits from a maximum of 0.12% allowed by ILSAC GF-1 to a maximum of 0.10%. In effect, the ILSAC GF-2 phosphorus limit removes 17% of the most commonly used antiwear and antioxidant additive in current PCMOs, zinc dialkyldithiophosphate (ZDP). This paper outlines some work in ASTM Sequence V engine dynamometer tests to quantify the effect of reducing the ZDP on valve train wear and sludge formation. Engine data for the Sequence VE, the proposed Sequence VF, and the modified Sequence VE are presented. These three tests summarize the evolution of the Sequence V from the Sequence VE for GF-1 to the dual plug Sequence VE configuration for the GF-2 specification.

Two prominent trends are facing diesel engine builders and their customers, environmental regulations and cost containment. Increasingly stringent exhaust emissions regulations have necessitated major changes in diesel engine design. Combustion temperatures and fuel injection pressures continue to rise. This and other factors, such as lower oil consumption for exhaust particulate reduction, place greater demands on crankcase lubricating oils. Another prominent environmentally related cost factor facing fleet operators is that of waste oil management. The inventory and disposal of used lubricants must now be handled in accordance with regulated guidelines and their associated costs. To compensate, new lubricant categories have been designed in both North America and Europe, such that 1994 and later emission controlled engines will perform as reliably as their earlier counterparts.

Information relative to oil thickening has been developed in road tests. Typical operating temperatures, as well as the length of time required to thicken oils in these tests, are described. A laboratory test procedure has been developed that shows a good degree of correlation with this field service. The effect of test conditions such as jacket temperature and piston ring design on oil thickening in the laboratory are described.

Additives are an integral part of today's fuels. Together with carefully formulated base fuel composition, they contribute to efficiency, dependability and long life of gasoline and diesel engines. As a primer, this paper describes the range of chemical additives formulated for gasoline and diesel fuel and their effects. Specific functions and benefits of additives, typical use levels, and test methods for evaluation are discussed. Additive usage may be divided into three major categories: a) to satisfy desired levels of performance in engines, b) to insure delivery of uncontaminated, on-specification fuels to the end user and c) achieve necessary chemical/physical properties as manufactured by the refiner.