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Journal Article

Removal of NOx from Diesel Exhausts: The New “Enhanced NH3-SCR” Reaction

2010-04-12
2010-01-1181
Ammonia/urea-SCR is a mature technology, applied worldwide for the control of NOx emissions in combustion exhausts from thermal power plants, cogeneration units, incinerators and stationary diesel engines and more recently also from mobile sources. However a greater DeNOx activity at low temperatures is desired in order to meet more and more restrictive legislations. In this paper we report transient and steady state data collected over commercial Fe-ZSM-5 and V₂O₅-WO₃/TiO₂ catalysts showing high NOx reduction efficiencies in the 200 - 350°C T-range when NO and ammonia react with nitrates, e.g., in the form of an aqueous solution of ammonium nitrate. Under such conditions a new reaction occurs, the so-called "Enhanced SCR" reaction, 2 NH₃ + 2 NO + NH₄NO₃ → 3 N₂ + 5 H₂O.
Journal Article

Fatigue Behavior of Aluminum Alloys under Multiaxial Loading

2014-04-01
2014-01-0972
Fatigue behavior of aluminum alloys under multiaxial loading was investigated with both cast aluminum A356-T6 and wrought alloy 6063-T6. The dominant multiaxial fatigue crack preferentially nucleates from flaws like porosity and oxide films located near the free surface of the material. In the absence of the flaws, the cracking/debonding of the second phase particles dominates the crack initiation and propagation. The number of cracked/debonded particles increases with the number of cycles, but the damage rate depends on loading paths. Among various loading paths studied, the circle loading path shows the shortest fatigue life due to the development of complex dislocation substructures and severe stress concentration near grain/cell boundaries and second phase particles.
Journal Article

Towards the Use of Eulerian Field PDF Methods for Combustion Modeling in IC Engines

2014-04-01
2014-01-1144
Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.
Technical Paper

Polycyclic Aromatic Hydrocarbons Evolution and Interactions with Soot Particles During Fuel Surrogate Combustion: A Rate Rule-Based Kinetic Model

2021-09-05
2021-24-0086
Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).
Journal Article

Automatic Transmission Gear Ratio Optimization and Monte Carlo Simulation of Fuel Consumption with Parasitic Loss Uncertainty

2015-04-14
2015-01-1145
This investigation utilizes energy analysis and statistical methods to optimize step gear automatic transmissions gear selection for fuel consumption. A full factorial matrix of simulations using energy analysis was performed to determine the optimal number of gears and gear ratios that provide the best fuel consumption performance for a particular vehicle - engine application. The full factorial matrix setup as a design of experiment (DOE) was applied to five vehicle applications, each with two engines to examine the potential differences that variations in road load and engine characteristics might have on optimal transmission gearing selection. The transmission gearing options considered in the DOE were number of gears, launch gear ratio and top gear ratio. Final drive ratio was also included due to its global influence on vehicle performance and powertrain operating speeds and torque.
Journal Article

Study of the Combustion Characteristics of a HCCI Engine Coupled with Oxy-Fuel Combustion Mode

2017-03-28
2017-01-0649
The present work proposed to implement oxy-fuel combustion mode into a homogeneous charge compression ignition engine to reduce complexity in engine emissions after-treatment and lower carbon dioxide emission. The combination of oxy-fuel combustion mode with homogeneous charge compression ignition engine can be further optimized by the utilization of direct high temperature and pressure water injection to improve cycle performance. A retrofitted conventional diesel engine coupled with port fuel injection and direct water injection is utilized in this study. A self-designed oxygen and carbon dioxide mixture intake system with flexible oxygen fraction adjustment ability is implemented in the test bench to simulate the adoption of exhaust gas recirculation. Water injection system is directly installed in the combustion chamber with a modified high speed solenoid diesel injector.
Journal Article

Experimental and Numerical Study of Flame Kernel Formation Processes of Propane-Air Mixture in a Pressurized Combustion Vessel

2016-04-05
2016-01-0696
Fuel lean combustion and exhaust gas dilution are known to increase the thermal efficiency and reduce NOx emissions. In this study, experiments are performed to understand the effect of equivalence ratio on flame kernel formation and flame propagation around the spark plug for different low turbulent velocities. A series of experiments are carried out for propane-air mixtures to simulate engine-like conditions. For these experiments, equivalence ratios of 0.7 and 0.9 are tested with 20 percent mass-based exhaust gas recirculation (EGR). Turbulence is generated by a shrouded fan design in the vicinity of J-spark plug. A closed loop feedback control system is used for the fan to generate a consistent flow field. The flow profile is characterized by using Particle Image Velocimetry (PIV) technique. High-speed Schlieren visualization is used for the spark formation and flame propagation.
Journal Article

A Progress Review on Soot Experiments and Modeling in the Engine Combustion Network (ECN)

2016-04-05
2016-01-0734
The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.
Journal Article

Model-Based Control of BMEP and NOx Emissions in a Euro VI 3.0L Diesel Engine

2017-09-04
2017-24-0057
A model-based approach to control BMEP (Brake Mean Effective Pressure) and NOx emissions has been developed and assessed on a FPT F1C 3.0L Euro VI diesel engine for heavy-duty applications. The controller is based on a zero-dimensional real-time combustion model, which is capable of simulating the HRR (heat release rate), in-cylinder pressure, BMEP and NOx engine-out levels. The real-time combustion model has been realized by integrating and improving previously developed simulation tools. A new discretization scheme has been developed for the model equations, in order to reduce the accuracy loss when the computational step is increased. This has allowed the required computational time to be reduced to a great extent.
Technical Paper

Simulation Analysis of Early and Late Miller Cycle Strategies Influence on Diesel Engine Combustion and Emissions

2020-04-14
2020-01-0662
Based on the working model of a diesel engine, the influence of 2 Miller cycle strategies-Early Intake Valve Closure (EIVC) and Late Intake Valve Closure (LIVC) on the combustion and emissions of diesel engine was analyzed. Then the working condition of each Miller cycle strategies on the engine under the rated speed was optimized through the adjust of the valve timing, boost pressure and the injection timing. The research found that both delaying and advancing the closure timing of the intake valve can decrease the pressure and temperature during compression stroke, prolonging the ignition delay. However, due to the decrease of the working media inside the cylinder, the average in-cylinder temperature and soot emissions will increase, which can be alleviated by raising the boost pressure and the resulting compensation of the intake loss.
Technical Paper

Effect of Hydrous Ethanol Combined with EGR on Performance of GDI Engine

2020-04-14
2020-01-0348
In recent years, particulate matters (PM) emissions from gasoline direct injection (GDI) engines have been gradually paid attention to, and the hydrous ethanol has a high oxygen content and a fast burning rate, which can effectively improve the combustion environment. In addition, Exhaust gas recirculation (EGR) can effectively reduce engine NOx emissions, and combining EGR technology with GDI engines is becoming a new research direction. In this study, the effects of hydrous ethanol gasoline blends on the combustion and emission characteristics of GDI engines are analyzed through bench test. The results show that the increase of the proportion of hydrous ethanol can accelerate the burning rate, shorten the combustion duration by 7°crank angle (CA), advance the peak moment of in-cylinder pressure and rate of heat release (RoHR) and improve the combustion efficiency. The hydrous ethanol gasoline blends can effectively improve the gaseous and PM emissions of the GDI engine.
Technical Paper

Numerical Optimization of a SCR System Based on the Injection of Pure Gaseous Ammonia for the NOx Reduction in Light-Duty Diesel Engines

2020-04-14
2020-01-0356
Selective Catalytic Reduction (SCR) systems are nowadays widely applied for the reduction of NOx emitted from Diesel engines. The typical process is based on the injection of aqueous urea in the exhaust gases before the SCR catalyst, which determines the production of the ammonia needed for the catalytic reduction of NOx. However, this technology is affected by two main limitations: a) the evaporation of the urea water solution (UWS) requires a sufficiently high temperature of the exhaust gases and b) the formation of solid deposits during the UWS evaporation is a frequent phenomenon which compromise the correct operation of the system. In this context, to overcome these issues, a technology based on the injection of gaseous ammonia has been recently proposed: in this case, ammonia is stored at the solid state in a cartridge containing a Strontium Chloride salt and it is desorbed by means of electrical heating.
Technical Paper

Characteristics of Transient NOx Emissions of HEV under Real Road Driving

2020-04-14
2020-01-0380
To meet the request of China National 6b emission regulations which will be officially implemented in China, firstly including the RDE emission test limits, the transient emissions on real road condition are paid more attention. A non-plug-in hybrid light-duty gasoline vehicles (HEV) sold in the Chinese market was selected to study real road emissions employed fast response NOx analyzer from Cambustion Ltd. with a sampling frequency of 100Hz, which can measure the missing NO peaks by standard RDE gas analyzer now. Emissions from PEMS were also recorded and compared with the results from fast response NOx analyzer. The concentration of NOx emissions before and after the Three Way Catalyst (TWC) of the hybrid vehicle were also sampled and analyzed, and the working efficiency of the TWC in real road driving process was investigated.
Technical Paper

A Road Load Data Processing Method for Transmission Durability Optimization Development

2020-04-14
2020-01-1062
With increasing pressure from environment problem for reduction in CO2 emissions and stricter fuel targets from road vehicles, new transmission technologies are gaining more attention in different main market. To get suitable road load data for transmission durability development is becoming increasingly important and can shorten the development time of new transmission. This paper presents the procedure and methods of road load data development for durability design of transmission product and optimization based on the real road data measurement, statistical characteristics evaluation and fatigue damage equivalency. Apply this road load data method procedure on 3 type of vehicle which represent conventional vehicle, BEV and HEV.
Journal Article

Multi-Dimensional Modeling of the Soot Deposition Mechanism in Diesel Particulate Filters

2008-04-14
2008-01-0444
A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Journal Article

A Comparison of Experimental and Modeled Velocity in Gasoline Direct-Injection Sprays with Plume Interaction and Collapse

2017-03-28
2017-01-0837
Modeling plume interaction and collapse for direct-injection gasoline sprays is important because of its impact on fuel-air mixing and engine performance. Nevertheless, the aerodynamic interaction between plumes and the complicated two-phase coupling of the evaporating spray has shown to be notoriously difficult to predict. With the availability of high-speed (100 kHz) Particle Image Velocimetry (PIV) experimental data, we compare velocity field predictions between plumes to observe the full temporal evolution leading up to plume merging and complete spray collapse. The target “Spray G” operating conditions of the Engine Combustion Network (ECN) is the focus of the work, including parametric variations in ambient gas temperature. We apply both LES and RANS spray models in different CFD platforms, outlining features of the spray that are most critical to model in order to predict the correct aerodynamics and fuel-air mixing.
Technical Paper

A Study of Crevice HC Mechanism Based on the Transient HC Test Data and the Double Zone Combustion Model

2008-06-23
2008-01-1652
The effectiveness of after-treatment systems depends on the exhaust gas temperature, which is low during cold-start. As a result, Euro III, Euro IV and FTP75 require that the emissions tests include exhaust from the beginning of cold start. It is proved that 50%∼80% of HC and CO emissions are emitted during the cold start and the amount of unburned fuel from the crevices during starting is much higher than that under warmed engine conditions. The piston crevices is the most part of combustion chamber crevices, and results of mathematical simulations show that the piston crevice contribution to HC emissions is expected to increase during cold engine operation. Based on the transient HC test data and the double zone combustion model, this paper presents the study of the crevice HC Mechanism of the first firing cycle at cold start on an LPG SI Engine. A fast-response flame ionization detector (FFID) was employed to measure transient HC emissions of the first firing cycle.
Technical Paper

Design and Simulation of Serial Hybrid Electric Moped Powertrain

2008-06-23
2008-01-1567
According to the requirements of two-wheel vehicle's future market and the characteristic of urban road conditions in China, the advantages and disadvantages of three basic configurations for the Hybrid Electric Vehicle are compared, finally, the serial hybrid configuration is chosen to be applied to hybrid Electric Moped solution. The selection principle of main components of this hybrid powertrain system includes ICE, generator, battery and hub motor, and the optimal match for performance parameters of these components are introduced in this paper. Then, a hybrid system model is established based on AVL-CRUISE. The simulations of fuel efficiency and exhaust emissions for both serial hybrid moped and conventional motorcycle is offered.
Technical Paper

Theoretical and Practical Mechanisms on Lowering Exhaust Emission Levels for Diverse Types of Spark Ignition Engines

2008-06-23
2008-01-1545
The exhaust aftertreatment strategy is one of the most fundamental aspects of spark ignition engine technologies. For various types of engines (e.g., carburetor engine, PFI engine and GDI engine), measuring, purifying, modeling, and control strategies regarding the exhaust aftertreatment systems vary significantly. The primary goal of exhaust aftetreatment systems is to reduce the exhaust emission levels of NOx, HC and CO as well as to lower combustion soot. In general, there is a tradeoff among different engine performance aspects. The exhaust catalytic systems, such as the three way catalyst (TWC) and lean NOx trap (LNT) converters, can be applied together with the development of other engine technologies (e.g., variable valve timing, cold start). With respect to engine soot, some advanced diagnosing techniques are essential to obtain thorough investigation of exhaust emission mechanisms.
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