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In-cylinder engine modeling is a necessary aspect of combustion research. In particular, simulating heat release connects variable combustion behavior to fuel properties through the 1st Law of Thermodynamics. One extension of such models is to evaluate changes to in-cylinder behavior using the Second Law of Thermodynamics in order to identify the peak period of availability for work extraction. Thus, Second Law models are a useful tool to augment research into alternative fuel usage and optimization. These models also help identify internal irreversibilities that are separate from heat transfer and exhaust gas losses. This study utilizes a multi-zone 1st and 2nd Law Heat Release model to characterize the changes in combustion behavior of a number of neat fuels used in a single-cylinder compression ignition (CI) engine.

Engine manufacturers are considering the implementation of thermodynamic cycles for Waste Heat Recovery (WHR) in order to increase Internal Combustion Engine (ICE) system thermal efficiency. For these secondary cycles, the literature illustrates the preference of Organic Rankine Cycles (ORC's) due to its simplicity and efficient recovery of the medium grade waste heat found in engine exhaust. This paper simulates the heat recovery capacity of eight dry fluids (butane, pentane, hexane, cyclopentane, benzene, toluene, R245fa, and R123) for an ORC based on the exhaust from a single-cylinder diesel engine-generator operating under five different loading conditions. The model, developed using REFPROP and the Matlab Optimization Toolbox, represents the physical components using isentropic pump and expander efficiencies, along with two-zone heat exchangers. All fluids present cycle efficiencies between 10-15%, with the heaviest hydrocarbons generating the largest amount of work.

With the rapid growth of biodiesel production, it is prudent to research ways to improve its operation and performance in an engine, especially concerning fuel economy and exhaust emissions. This requires a thorough understanding of both the biodiesel production and engine operating processes. Completion of a published study of the impact of biodiesel fuel properties on engine operation indicated that it is difficult to draw conclusions about the exact causes of increased NOx emissions with respect to biodiesel properties without the capability of measuring engine cylinder pressures. As improvements were made to the authors' laboratory, a system to monitor and record pressure inside a diesel engine during operation was constructed to test dissimilar fuels. In the current work, three different fuels were tested in order to investigate combustion phasing, emissions, and fuel consumption as a function of fuel properties such as density, viscosity, Cetane Number, and energy content.

The main issues related to the vibration response and acoustic noise emission of a new liquid fuelled fuel cell APU (auxiliary power unit) system are discussed and analyzed. These problems are being addressed in an on-going research project. The APU is comprised of several critical subsystems including the fuel processing system, fuel stack, heat exchanger, compressor, as well as high-pressure and low-pressure components. The vibration concern deals with the design of a two-stage isolation mount system to shield these critical parts from the shock and steady-state dynamics coming through the truck frame during on-road traveling conditions. A lumped parameter dynamic model is formulated for use in optimizing the mount stiffnesses and locations. Acoustic concerns are primarily related to exterior noise levels when the truck is at a rest stop. To address those issues, experimental studies are conducted to quantify the main sources and paths for noise.

Biodiesel is a potential alternative to Ultra Low Sulfur Diesel (ULSD); however, it often suffers from increased fuel consumption in comparison to ULSD when injection timings and/or pressures are similar. To decrease fuel consumption, increasing biodiesel injection pressure has been found to mitigate the issues associated with its relatively high viscosity and lower energy content. When doing so, the literature indicates decreased emissions, albeit with potentially greater nitrogen oxide (NOx) emissions in contrast to ULSD. In order to better understand the trade-off between fuel consumption and NOx emissions, this study explores the influence of fuel injection pressure on ULSD, Waste Cooking Oil (WCO) biodiesel, and their blends in a single-cylinder compression ignition (CI) engine. In particular, fuel injection pressures and timings for WCO biodiesel and blended fuels are adjusted to attempt to mimic the in-cylinder pressure profile of operation using ULSD.

The use of Compressed Natural Gas (CNG) has demonstrated the potential to decrease Particulate Matter (PM) and nitrogen oxide (NOx) emissions simultaneously when used in a dual-fuel application with diesel fuel functioning as the ignition source. However, some authors do find that NOx emissions can increase. One postulation is that the conflicting results in the literature may be due to the difference in composition of natural gas around the world. Therefore, in order to investigate if CNG composition influences combustion performance and emissions, four unique mixtures of CNG were tested (i.e., 87% to 96% methane) while minimizing the combined difference of the density, heating value, and constant pressure specific heat of each mixture. This was accomplished at moderate energy substitution ratios (up to 40%) in a single cylinder engine operating at various loads.

Diesel knock and ringing combustion in compression ignition (CI) engines are largely an unavoidable phenomenon and are partially related to the overall effectiveness of the fuel injection process. Modern electronic fuel injection systems have been effective at reducing the intensity of knock in CI engines, largely through optimization of fuel injection timing, as well as higher operating pressures that promote enhanced fuel and air mixing. In this effort, a single-cylinder CI engine was tested under a number of different combustion strategies, including a comparison of mechanical and electronic injection systems, increasing fuel injection pressures for biodiesel fuels, and the usage of dual-fuel combustion with compressed natural gas (CNG). Using in-cylinder pressure traces and engine operational data, the difference in injection mechanisms, fuel preparation, and their effects on knock intensity is clearly illustrated.

Utilizing a higher compression ratio in a Compression Ignition (CI) engine grants an obvious advantage of improved thermal efficiency. However, the resulting combustion temperatures promote dissociation ensuing in increased nitrogen oxide (NOx) emissions. Unfortunately, due to the inherent properties of CI combustion, it is difficult to achieve simultaneous reduction of NOx and particulate matter (PM) through conventional combustion methods. Taking a different route though accomplishing Homogeneous Charge Compression Ignition (HCCI) in CI engines will largely eliminate NOx and PM; however, combustion can result in a significant increase in hydrocarbon (HC) and carbon monoxide (CO) emissions due to the low volatility of diesel fuel. Hence, this work attempts another avenue of Low Temperature Combustion (LTC) by employing Pre-mixed Charge Compression Ignition (PCI) combustion on a comparatively higher compression ratio (21.2) single cylinder CI engine.

The recent increase in natural gas availability has made compressed natural gas (CNG) an option for fueling the transportation sector of the United States economy. In particular, CNG is advantageous in dual-fuel operation alongside ultra low sulfur diesel (ULSD) for compression ignition (CI) engines. This work investigates the usage of natural gas mixtures at varying Energy Substitution Rates (ESRs) within a high compression ratio single-cylinder CI engine, including performance and heat release modeling of dual-fuel combustion. Results demonstrate the differing behavior of utilizing CNG at various substitution rates.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Autoignition delay times of diesel, methanol, biodiesel, and 50 wt%, 25 wt%, and 10 wt% biodiesel in methanol were measured in a constant-volume combustor. The autoignition delay times of biodiesel are similar to diesel and confirm the utility of biodiesel as a direct diesel alternative. While methanol has poor ignition characteristics, the 50 wt% blend performed similar to diesel. The 25 wt% and 10 wt% blends had ignition delay times between those of methanol and biodiesel. Methanol and biodiesel have a synergy in blends where the favorable ignition delay times of biodiesel and lower viscosity and cost of methanol combine to provide a better fuel.

Alternative fuels based on biomass have typically been specified in ways which substantially limit allowable compositions. These specifications are unlike those for petroleum based fuels which include mixtures comprised of hundreds of different compounds. Such narrow biofuel specifications are clearly disadvantageous by restricting any flexibility of using different biofuels to minimize costs and offset price fluctuations. This paper focuses on critical performance criteria for diesel fuels and provides experimental data on several, non-conventional biofuels. Experimental data includes the physical properties and ignition delay times of new, lower cost sugar formulations. The objective of this work is to develop specifications on volumetric heating value, viscosity, and ignition properties as well as other properties for compression ignition biofuels. Proposed fuel specifications would not include compositions, thereby allowing a variety of feedstocks to be used.

A Pore Fuel Injector Deposit (PFID) test has been developed which provides repeatable results. The test can discriminate gasolines with differing fuel injector fouling tendencies in vehicles. Results confirm previous work that added mono-and diolefins increase deposit growth. The test is also able to evaluate the performance of additives. Other factors found to affect injector deposit formation include: injector soak temperature, injector soak pressure, weeping vs non-weeping injectors, and the presence of oxygen around the injector pintle. The PFID test can be run in about one quarter the time needed to evaluate fuels in vehicle and dynamometer tests.(1)

As climate change drives the exploration into new and alternative fuels, biodiesel has emerged as a promising alternative to traditional diesel fuel. To further increase the viability of biodiesel, a unique system at the University of Kansas utilizes glycerin, the primary byproduct of biodiesel production, for power generation. This system converts glycerin into a hydrogen-rich gas (syngas) that is sent to an engine-generator system in one continuous flow process. The current setup allows for running the engine-generator system on pure propane, reformed propane, or reformed glycerin, with each fuel serving a unique purpose. This paper discusses upgrades in pure propane operation that serves the intent of preheating the engine prior to syngas operation and establishing the baseline energy requirement for fueling the system.

Given the need of the automotive industry to improve fuel efficiency, many companies are moving towards lean burn and low temperature combustion regimes. Critical control of these methods requires an accurate Exhaust Gas Recirculation (EGR) system that can maintain its desired rate and temperature. In this area, the literature illustrates different methodologies to control and monitor this EGR system; however, it lacks a discussion of how the non-linear nature of wave dynamics and time responses of an engine must be taken into account. In order to perform research into the use of EGR for these combustion regimes, an automated, closed-loop EGR system that uses a microprocessor to compute the slope change of the EGR rate and temperature as part of its feedback algorithm was constructed for use in a teaching and research laboratory. The findings illustrate that the system works as intended by replicating known combustion trends with EGR.

Many problems are associated with the large battery operation current, such as battery overheating, lithium plating, and mechanical structural instability of battery materials. All these problems may cause battery safety issues in fuel cell hybrid vehicles (FCHVs), e.g., battery explosions and thermal runaway have been reported and may cause public anxiety about FCHVs. Previous researches on FCHV power management strategy have focused on minimizing fuel consumption. But more attention needs to put on the battery current constraint for analysis of battery state of charge (SOC) and battery state of health (SOH). This research targets optimizing the FCHV battery pack operation within a safe current range through power management strategy to increase the safety of the battery pack while improving battery usage via SOC control. Battery SOH is also evaluated in the study.

Recently, ozone addition has come under scrutiny as a means of controlling ignition timing for Low Temperature (LTC) combustion, which defeats the NOx-PM tradeoff using a highly dilute, homogeneous mixture. This is because ozone decomposes into atomic oxygen and hydroxyl radicals that influence the early phases of the ignition delay process. In order to understand ozone's influence on combustion better, this work analyzes the effects of ozone-assisted combustion for a single-cylinder, direct-injection Compression Ignition engine via a mechanical pump-line-nozzle fuel system and an electronically controlled common-rail fuel injection system. Experimental outcomes indicate a relatively small influence of ozone for the mechanical injection system with a comparably decreased effect for the common rail system.

Significant progress towards reducing diesel engine fuel consumption and emissions is possible through the simultaneous Waste Heat Recovery (WHR) and Particulate Matter (PM) filtration in a novel device described here as a Diesel Particulate Filter Heat Exchanger (DPFHX). This original device concept is based on the shell-and-tube heat exchanger geometry, where enlarged tubes contain DPF cores, allowing waste heat recovery from engine exhaust and allowing further energy capture from the exothermic PM regeneration event. The heat transferred to the working fluid on the shell side of the DPFHX becomes available for use in a secondary power cycle, which is an increasingly attractive method of boosting powertrain efficiency due to fuel savings of around 10 to 15%. Moreover, these fuel savings are proportional to the associated emissions reduction after a short warm-up period, with startup emissions relatively unchanged when implementing a WHR system.

In order to perform cutting-edge engine research that applies to modern Compression Ignition (CI) engines, a sophisticated test cell is needed that allows control of the engine and its auxiliary systems. The primary obstacle to the completion of such a test cell is the up-front expense. This paper covers the construction of a low cost, single-cylinder engine test cell while demonstrating the type of research that can be accomplished along the way. The components necessary for the construction, instrumentation, and operation of such a test cell, neglecting emissions analysis equipment, can be obtained for less than $150,000. The engine utilized, a naturally-aspirated single-cylinder Yanmar L100V, was purchased as an engine-generator package.

A timing sweep to correlate the location of Maximum Brake Torque (MBT) was completed on a single-cylinder, direct injected compression ignition engine that was recently upgraded to a high-pressure rail injection system for better engine control. This sweep included emissions monitoring for carbon dioxide, carbon monoxide, particulate matter, hydrocarbons, and oxides of nitrogen for the calibration of a heat release model, as well as the opportunity to relate MBT timing to brake-specific emissions production. The result of this timing sweep was a relatively linear correlation between injection delay and peak pressure timing. In addition, a number of other MBT timing methodologies were tested indicating their applicability for immediate feedback upon engine testing, particularly mass fraction burned correlations. Emissions were either strongly correlated to MBT timing (with emissions being minimized in the vicinity of MBT), or were completely independent of MBT.