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Particulate filters (PF) are a highly effective after-treatment device that reduces particulate matter emissions, a rising environmental concern in the automotive industry. However, accumulation of solid particles during the PF filtration process increases engine backpressure considerably, which can have a negative impact on engine efficiency, acoustics, and gaseous emissions. In this area, an accurate pressure drop model helps to better understand the effect of accumulated solid particles in the PF on engine backpressure, aiding in design and regeneration considerations without physical testing. These effects are further improved on board the vehicle using a single equation pressure drop model with a relatively low computational cost. This article presents a thorough history of PF pressure drop models and their advancements.

With the rapid growth of biodiesel production, it is prudent to research ways to improve its operation and performance in an engine, especially concerning fuel economy and exhaust emissions. This requires a thorough understanding of both the biodiesel production and engine operating processes. Completion of a published study of the impact of biodiesel fuel properties on engine operation indicated that it is difficult to draw conclusions about the exact causes of increased NOx emissions with respect to biodiesel properties without the capability of measuring engine cylinder pressures. As improvements were made to the authors' laboratory, a system to monitor and record pressure inside a diesel engine during operation was constructed to test dissimilar fuels. In the current work, three different fuels were tested in order to investigate combustion phasing, emissions, and fuel consumption as a function of fuel properties such as density, viscosity, Cetane Number, and energy content.

Biodiesel is a potential alternative to Ultra Low Sulfur Diesel (ULSD); however, it often suffers from increased fuel consumption in comparison to ULSD when injection timings and/or pressures are similar. To decrease fuel consumption, increasing biodiesel injection pressure has been found to mitigate the issues associated with its relatively high viscosity and lower energy content. When doing so, the literature indicates decreased emissions, albeit with potentially greater nitrogen oxide (NOx) emissions in contrast to ULSD. In order to better understand the trade-off between fuel consumption and NOx emissions, this study explores the influence of fuel injection pressure on ULSD, Waste Cooking Oil (WCO) biodiesel, and their blends in a single-cylinder compression ignition (CI) engine. In particular, fuel injection pressures and timings for WCO biodiesel and blended fuels are adjusted to attempt to mimic the in-cylinder pressure profile of operation using ULSD.

The use of Compressed Natural Gas (CNG) has demonstrated the potential to decrease Particulate Matter (PM) and nitrogen oxide (NOx) emissions simultaneously when used in a dual-fuel application with diesel fuel functioning as the ignition source. However, some authors do find that NOx emissions can increase. One postulation is that the conflicting results in the literature may be due to the difference in composition of natural gas around the world. Therefore, in order to investigate if CNG composition influences combustion performance and emissions, four unique mixtures of CNG were tested (i.e., 87% to 96% methane) while minimizing the combined difference of the density, heating value, and constant pressure specific heat of each mixture. This was accomplished at moderate energy substitution ratios (up to 40%) in a single cylinder engine operating at various loads.

Utilizing a higher compression ratio in a Compression Ignition (CI) engine grants an obvious advantage of improved thermal efficiency. However, the resulting combustion temperatures promote dissociation ensuing in increased nitrogen oxide (NOx) emissions. Unfortunately, due to the inherent properties of CI combustion, it is difficult to achieve simultaneous reduction of NOx and particulate matter (PM) through conventional combustion methods. Taking a different route though accomplishing Homogeneous Charge Compression Ignition (HCCI) in CI engines will largely eliminate NOx and PM; however, combustion can result in a significant increase in hydrocarbon (HC) and carbon monoxide (CO) emissions due to the low volatility of diesel fuel. Hence, this work attempts another avenue of Low Temperature Combustion (LTC) by employing Pre-mixed Charge Compression Ignition (PCI) combustion on a comparatively higher compression ratio (21.2) single cylinder CI engine.

The recent increase in natural gas availability has made compressed natural gas (CNG) an option for fueling the transportation sector of the United States economy. In particular, CNG is advantageous in dual-fuel operation alongside ultra low sulfur diesel (ULSD) for compression ignition (CI) engines. This work investigates the usage of natural gas mixtures at varying Energy Substitution Rates (ESRs) within a high compression ratio single-cylinder CI engine, including performance and heat release modeling of dual-fuel combustion. Results demonstrate the differing behavior of utilizing CNG at various substitution rates.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

The modeling of emitted hydrocarbons from internal combustion engines for exhaust aftertreatment devices has remained relatively unchanged since the early 1970s. This older model subdivides the hydrocarbon species into fast, slow, and non-oxidizing components. Current and future regulations from the United States Environmental Protection Agency stretch the abilities of this methodology, necessitating the need for more advanced modeling techniques. To this end, this paper provides a review on the different groups of hydrocarbons in order to provide background and contextual information on the different species expected in diesel emissions. Additionally, this work groups these species into different categories, depending on their chemical make-up, impact on human health, reactivity in the environment, and their prevalence within diesel emissions.

Recently, ozone addition has come under scrutiny as a means of controlling ignition timing for Low Temperature (LTC) combustion, which defeats the NOx-PM tradeoff using a highly dilute, homogeneous mixture. This is because ozone decomposes into atomic oxygen and hydroxyl radicals that influence the early phases of the ignition delay process. In order to understand ozone's influence on combustion better, this work analyzes the effects of ozone-assisted combustion for a single-cylinder, direct-injection Compression Ignition engine via a mechanical pump-line-nozzle fuel system and an electronically controlled common-rail fuel injection system. Experimental outcomes indicate a relatively small influence of ozone for the mechanical injection system with a comparably decreased effect for the common rail system.

Diesel Particulate Filters (DPFs) have become a required aftertreatment device for Compression Ignition engine exhaust cleanup of Particulate Matter (PM). Moreover, with the increased prevalence of Spark Ignition Direct Injection (SIDI) systems, discussions are currently underway regarding the need of Gasoline Particulate Filters to handle the PM emanating from their combustion process. In this area, the two-channel DPF model has been widely successful in predicting the temperature, pressure drop, and species conversion in these devices. Because of the need to simulate compressible flow through the channels and a porous wall, these models have a difficult time achieving real-time predictive results suitable for an Engine Control Unit (ECU). As a result, this effort describes the creation of a lumped DPF model intended for an ECU. Model formulation was based on the standard governing equations, but simplified in order to remove as much computational overhead as possible.

Significant progress towards reducing diesel engine fuel consumption and emissions is possible through the simultaneous Waste Heat Recovery (WHR) and Particulate Matter (PM) filtration in a novel device described here as a Diesel Particulate Filter Heat Exchanger (DPFHX). This original device concept is based on the shell-and-tube heat exchanger geometry, where enlarged tubes contain DPF cores, allowing waste heat recovery from engine exhaust and allowing further energy capture from the exothermic PM regeneration event. The heat transferred to the working fluid on the shell side of the DPFHX becomes available for use in a secondary power cycle, which is an increasingly attractive method of boosting powertrain efficiency due to fuel savings of around 10 to 15%. Moreover, these fuel savings are proportional to the associated emissions reduction after a short warm-up period, with startup emissions relatively unchanged when implementing a WHR system.

A timing sweep to correlate the location of Maximum Brake Torque (MBT) was completed on a single-cylinder, direct injected compression ignition engine that was recently upgraded to a high-pressure rail injection system for better engine control. This sweep included emissions monitoring for carbon dioxide, carbon monoxide, particulate matter, hydrocarbons, and oxides of nitrogen for the calibration of a heat release model, as well as the opportunity to relate MBT timing to brake-specific emissions production. The result of this timing sweep was a relatively linear correlation between injection delay and peak pressure timing. In addition, a number of other MBT timing methodologies were tested indicating their applicability for immediate feedback upon engine testing, particularly mass fraction burned correlations. Emissions were either strongly correlated to MBT timing (with emissions being minimized in the vicinity of MBT), or were completely independent of MBT.