Search Results

This paper presents a new substrate for Lean NOx Traps (LNT) which enables high NOx conversion efficiency, even after long-term aging, when using alkali metals as the NOx adsorber. When a conventional metal honeycomb is used as the LNT substrate, the chromium in the metal substrate migrates into the washcoat and reacts with the alkali metals after thermal aging. In order to help prevent this migration, we have developed a new substrate where a fine -alumina barrier is precipitated to the surface of the metal substrate. The new substrate is highly capable of preventing migration of chromium into the washcoat and greatly enhances the NOx conversion. The durability of the new substrate and emission test using a test vehicle are also examined.

In recent years, catalyst systems such as a lean NOx trap (LNT) catalyst system and a urea selective catalytic reduction (SCR) system have been developed to obtain cleaner diesel emissions. At Nissan, we developed an emission control system for meeting Tier 2 Bin 5 requirements in 2003. On the basis of that technology, a new HC-NOx trap catalyst system has now been developed that complies with the SULEV standards without increasing the catalyst volume and precious metal loading. Compliance with the SULEV standards requires a further reduction of HC (NMHC) emissions by 84% and NOx by 60% compared with the emission performance Tier 2 Bin 5 compliant catalyst system. Consequently high conversion performance for both HCs and NOx is needed. An investigation of HC emission behavior under the FTP75 mode showed that a reduction of cold-phase HCs was critical for meeting the standard. Large quantities of HCs above C4 are emitted in the cold state.

It is generally known that NOx reacts with unburned gasoline, olefins in particular, to form sludge precursors. In this study, the authors investigated the process by which NOx and unburned gasoline mix into the engine oil and analyzed the mechanism whereby stop and go driving accelerates sludge formation. It has been found that NOx detected in the engine oil as nitrite ions mixes into the oil in the crankcase. The NOx concentration in the engine oil increases rapidly when the crankcase gas temperature is nearly equal to the dew point of the water vapor in the crankcase. Unburned gasoline is mainly absorbed into the oil through the oil film on the cylinder walls and the oil in the ring grooves. During low-temperature engine operation in stop-go driving (i.e., when the vehicle is stopped), NOx and unburned gasoline are absorbed into the engine oil and, in high-temperature engine operation (i.e., when the vehicle is moving), NOx and unburned gasoline are released from the oil.

The field of diesel combustion research is producing numerous reports on studies of premixed combustion, which promises simultaneous reduction of both NOx and soot, in order to meet increasingly stringent regulations on harmful emissions from automobiles. However, although premixed combustion can simultaneously reduce both NOx and soot, certain issues have been pointed out, including the fact that it emits greater quantities of unburned HC and CO gases and the fact that it limits the operating range. Furthermore, this combustion method sets the ignition delay longer with the aim of promoting the mixing of fuel and air. This raises issues with the product due to the combustion instability and sensitivity to the uneven fuel properties that are found on the market, the capability of the engine response under transient conditions, the deterioration in combustion noise, and so on.

A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.

The mixture formation by fuel spray impingement (OSKA system) was applied to a small direct-injection diesel engine in order to reduce the wall quenching- induced emissions, i.e., the emissions of THC and soluble organic fractions (SOF). Experiments were carried out using a single-cylinder engine, fitted with various piston cavity geometries, ran under a wide range of compression ratios and fuel injection specifications. The piston cavity was designed as a centrally located reentrant type. The combination of the high squish flow and the weak penetration of the OSKA spray was very effective in reducing harmful emissions. A short ignition delay, under the retarded fuel injection timing, was obtained because of the high compression ratio. The OSKA DI diesel engine showed reduced NOx, smoke, and THC emissions without deterioration of the fuel consumption compared to modern DI diesel engines used in automotive applications.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Experimental investigations were conducted with a direct-injection diesel engine to improve exhaust emission, especially nitrogen oxide (NOx) and particulate matter (PM), without increasing fuel consumption. As a result of this work, a new combustion concept, called Modulated Kinetics (MK) combustion, has been developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion, respectively. The characteristics of a new combustion concept were investigated using a single cylinder DI diesel engine and combustion photographs. The low compression ratio, EGR cooling and high injection pressure was applied with a multi-cylinder test engine to accomplish premixed combustion at high load region. Combustion chamber specifications have been optimized to avoid the increase of cold-start HC emissions due to a low compression ratio.

Considerable amounts (400 ∼ 600 thousand tons) of waste vegetable oil in Japan are still flushed down the drain every year. Utilization of waste vegetable oil for diesel fuel leads to two advantages for environmental protection, to reduce CO2 emission from engines and to avoid water pollution of rivers. In this study, combustion characteristics of waste vegetable oil methyl ester (WME) are investigated in detail by not only engine test run but also observation of burning flames in a visual engine. As results indicate, WME shows rather better combustion state in the visual engine and lower smoke emission from a high-speed DI test engine than gas oil. Moreover, by emulsifying WME with water, further improvement of combustion and more than 18 % reduction of NOx emission is carried out.

When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.

Experimental investigations were previously conducted with a direct-injection diesel engine with the aim of reducing exhaust emissions, especially nitrogen oxides (NOx) and particulate matter (PM). As a result of that work, a combustion concept, called Modulated Kinetics (MK) combustion, was developed that reduces NOx and smoke simultaneously through low-temperature combustion and premixed combustion to achieve a cleaner diesel engine. In subsequent work, it was found that applying a low compression ratio was effective in expanding the MK combustion region on the high-load side. The MK concept was then combined with an exhaust after-treatment system and applied to a test vehicle. The results indicated the attainment of ULEV emission levels, albeit in laboratory evaluations. In the present work, the combination of the MK combustion concept and certain fuel properties has been experimentally investigated with the aim of reducing exhaust emissions further.

This paper describes the third generation of the partial zero emission vehicle (P-ZEV) technology originally adopted on the Nissan Sentra CA sold in California. The 2000 Nissan Sentra CA became the world's first gasoline-fueled car to qualify for P-ZEV credits from the California Air Resources Board (CARB). The third-generation P-ZEV system has been substantially reduced in size and cost, compared with the Sentra CA system, enabling it to be used on high-volume models. This system complies with the P-ZEV requirements, including those for zero evaporative emissions and Onboard Diagnostics II (OBD-II). To achieve a more compact and lower-cost system, an ultra-thin-walled catalyst substrate, the world's first to attain a 1.8-mil wall thickness, has been adopted along with catalysts that display excellent low-temperature activity. As a result, low-temperature catalyst activity has been significantly improved.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.

This paper describes the emission reduction technologies applied to 4- and 6-cylinder engines used on Japanese market models certified as ultra-low emission vehicles (U-LEVs) in Japan. To qualify for this rigorous U-LEV certification, a vehicle must reduce hydrocarbon (HC) and nitrogen oxide (NOx) emissions by an additional 75% from the levels mandated by Japan's 2000 exhaust emission regulations. Nearly all Nissan Japanese models fitted with a gasoline engine, ranging from in-line 4-cylinder engines to V6 engines, have now been certified as U-LEVs. This has been accomplished by further improving the emission reduction technologies that were developed for the Sentra CA, which was launched in the U.S. market in 2000 as the world's first gasoline-fueled vehicle to qualify for Partial Zero Emission Vehicle (P-ZEV) credits from the California Air Resources Board. The specific new technologies involved are as follows.

The reduction of fuel consumption is of great importance to automobile manufacturers. As a prospective means to achieve fuel economy, lean burn is being investigated at various research organizations and automobile manufacturers and a number of studies on lean-burn technology have been reported to this date. This paper describes the development of a four-valve lean-burn engine; especially the improvement of the combustion, the development of an engine management system, and the achievement of vehicle test results. Major themes discussed in this paper are (1) the improvement of brake-specific fuel consumption under partial load conditions and the achievement of high output power by adopting an optimized swirl ratio and a variable-swirl system with a specially designed variable valve timing and lift mechanism, (2) the development of an air-fuel ratio control system, (3) the improvement of fuel economy as a vehicle and (4) an approach to satisfy the NOx emission standard.

For reduction of NOx and soot emission with conventional diesel diffusion combustion, the authors focused on enhancement of the rate of injection (hereafter referred to as RoI) to improve air availability, thus enhancing the fuel distribution and atomization. In order to increase opening ramp of the RoI (hereafter referred to as fast injection rate), a hydraulic circuit was improved and nozzle geometries were optimized to make the greatest use of the advantages of the hydraulic circuit. Two different common rail injectors were prepared for this research. One is a mass production-type injector with piezo actuator that achieved the EURO-V exhaust gas emission standards, and the other is a prototype injector equipped with the new hydraulic circuit. The nozzle needle of the prototype injector is directly actuated by high-pressure fuel from common rail to improve the RoI.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.