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The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.

CO2 emission constraints taking effect from 2020 lead to further investigations of technologies to lower knock sensitivity of gasoline engines, main limiting factor to increase engine efficiency and thus reduce fuel consumption. Moreover the RDE cycle demands for higher power operation, where fuel enrichment is needed for component protection. To achieve high efficiency, the engine should be run at stoichiometric conditions in order to have better emission control and reduce fuel consumption. Among others, water injection is a promising technology to improve engine combustion efficiency, by mainly reducing knock sensitivity and to keep high conversion rates of the TWC over the whole engine map. The comprehension of multiple thermodynamic effects of water injection through 3D-CFD simulations and their exploitation to enhance the engine combustion efficiency is the main purpose of the analysis.

Increasing the efficiency of modern gasoline engines (with direct injection and spark-ignition - DISI) requires innovative approaches. The reduction of the engine displacement, accompanied by an increase of the mean pressure, is limited by the tendency of increasing combustion anomalies. Conventional methods for knock mitigation, on the contrary, have a negative effect on consumption and efficiency. A promising technology to solve these conflicting objectives is the injection of water. Both the indirect and the direct water injection achieve a significant reduction in the load temperature. The fuel enrichment can be reduced, whereby the operating range of the exhaust aftertreatment can be extended. In addition, water injection paves the way for an increase in the geometric compression ratio, which leads to an efficiency advantage even at partial load.