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Previous work has shown that it may be advantageous to use gasoline type fuels with long ignition delays compared to today's diesel fuels in compression ignition engines. In the present work we investigate if high volatility is also needed along with low cetane (high octane) to get more premixed combustion leading to low NO and smoke. A single-cylinder light-duty compression ignition engine is run on four fuels in the diesel boiling range and three fuels in the gasoline boiling range. The lowest cetane diesel boiling range fuel (DCN = 22) also has very high aromatic content (75%vol) but the engine can be run on this to give very low NO (≺ 0.4 g/kWh) and smoke (FSN ≺ 0.1), e.g,. at 4 bar and 10 bar IMEP at 2000 RPM like the gasoline fuels but unlike the diesel fuels with DCNs of 40 and 56. If the combustion phasing and delay are matched for any two fuels at a given operating condition, their emissions behavior is also matched regardless of the differences in volatility and composition.

Experiments on a modern DI Diesel engine were carried out: The engine was fuelled with standard Diesel fuel, RME and a mixture of 85% standard Diesel fuel, 5% RME and 10% higher alcohols under low load conditions (4 bar IMEP). During these experiments, different external EGR levels were applied while the injection timing was chosen in a way to keep the location of 50% heat release constant. Emission analysis results were in accordance with widely known correlations: Increasing EGR rates lowered NOx emissions. This is explained by a decrease of global air-fuel ratio entailing longer ignition delay. Local gas-fuel ratio increases during ignition delay and local combustion temperature is lowered. Exhaust gas analysis indicated further a strong increase of CO, PM and unburned HC emissions at high EGR levels. This resulted in lower combustion efficiency. PM emissions however, decreased above 50% EGR which was also in accordance with previously reported results.

An HSDI Diesel engine was fuelled with standard Swedish environmental class 1 Diesel fuel (MK1), Soy methyl ester (B100) and n-heptane (PRF0) to study the effects of both operating conditions and fuel properties on engine performance, resulting emissions and spray characteristics. All experiments were based on single injection diesel combustion. A load sweep was carried out between 2 and 10 bar IMEPg. For B100, a loss in combustion efficiency as well as ITE was observed at low load conditions. Observed differences in exhaust emissions were related to differences in mixing properties and spray characteristics. For B100, the emission results differed strongest at low load conditions but converged to MK1-like results with increasing load and increasing intake pressures. For these cases, spray geometry calculations indicated a longer spray tip penetration length. For low-density fuels (PRF0) the spray spreading angle was higher.

A diesel engine developed for an international market must be able to run on different fuels considering the diesel fuel qualities and the increasing selection of biofuels in the world. This leads to the question of how different fuels perform relative to a standard diesel fuel when not changing the hardware settings. In this study five fuels (Japanese diesel, MK3, EN590 with 10% RME, EN590 with 30% RME and pure RME) have been compared to a reference diesel fuel (Swedish MK1) when run on three different speeds and three different loads at each speed. The experiments are run on a Scania 13l Euro5 engine with standard settings for Swedish MK1 diesel. In general the differences were not large between the fuels. NO x usually increased compared to MK1 and then soot decreased as would be expected. The combustion efficiency increased with increased RME contents of the fuel but the indicated efficiency was not influenced by RME except for at higher loads.

Previous work has showed that it may be advantageous to use fuels of lower cetane numbers compared to today's diesel fuels in compression ignition engines. The benefits come from the longer ignition delays that these fuels have. There is more time available for the fuel and air to mix before combustion starts which is favourable for achieving low emissions of NOx and smoke though premixing usually leads to higher emissions of CO and unburned hydrocarbons. In the present work, operation of a single-cylinder light-duty compression ignition engine on four different fuels of different octane numbers, in the gasoline boiling range, is compared to running on a diesel fuel. The gasoline fuels have research octane numbers (RON) of 91, 84, 78, and 72. These are compared at a low load/low speed condition (4 bar IMEP / 1200 rpm) in SOI sweeps as well as at a higher load and speeds (10 bar IMEP / 2000 and 3000 rpm) in EGR sweeps.

A study on the modeling of fuel sprays in diesel engines will be presented. First, modeling of non-reacting diesel spray formation is studied in Fluent and Star-CD. The main objective however is to model combustion of the spray using a generic approach. This is achieved by applying a detailed chemistry tabulation method, called FGM (Flamelet Generated Manifold). Using this approach will make additional ignition modeling, which is conventional, obsolete. The FGM method is implemented in Fluent and Star-CD. Subsequently, constant volume spray combustion and full engine cycle simulations are performed. Spray formation is modeled with Lagrangian type models that are available in Fluent and Star-CD, and also with a 1D Euler-Euler spray model that is implemented and applied in 3D Fluent simulations. The results are compared with EHPC (Eindhoven High Pressure Cell) experiments, data from Sandia National Laboratories and IFP (Institut Français du Pétrole).

The main goal of this paper is to acquire more insight into the relationship between wall and piston impingement of liquid fuel and unburnt hydrocarbon emissions (UHC) emissions, under early direct injection (EDI) premixed charge compression ignition (PCCI) operating conditions. To this end, the vaporization process is modeled for various operating conditions using a commercial CFD code (StarCD). Predicted values for liquid core penetration, or liquid length LL , have been successfully checked against experimental data from literature over a wide range of operating conditions. Next, the correlation between the CFD results for wall and piston impingement and measured UHC emissions is studied. The diesel fuel used in the experiments is modeled as n-dodecane and n-heptadecane, representing the low and high end of the diesel boiling range, respectively. A distinction is made between liquid spray impingement on the piston surface and cylinder liner.

Partially premixed combustion (PPC) has the potential of high efficiency and simultaneous low soot and NOx emissions. Running the engine in PPC mode with high octane number fuels has the advantage of a longer premix period of fuel and air which reduces soot emissions, even at higher loads. The problem is the ignitability at low load and idle operating conditions. The objective of this study is investigation of the low load limitations with gasoline fuels with octane numbers RON 69 and 87. Measurements with diesel fuel were also taken as reference. The experimental engine is a light duty diesel engine equipped with a fully flexible valve train system. Trapped hot residual gases using negative valve overlap (NVO) is the main parameter of interest to potentially increase the attainable operating region of high octane number gasoline fuels.

Partially Premixed Combustion (PPC) has the potential of simultaneously providing high engine efficiency and low emissions. Previous research has shown that with proper combination of Exhaust-Gas Recirculation (EGR) and Air-Fuel equivalence ratio, it is possible to reduce engine-out emissions while still keeping the engine efficiency high. In this paper, the effect of changes in intake pressure (boost) and EGR fraction on PPC engine performance (e.g. ignition delay, burn duration, maximum pressure rise rate) and emissions (carbon monoxide (CO), unburned hydrocarbon (UHC), soot and NOX) was investigated in a single-cylinder, heavy-duty diesel engine. Swedish diesel fuel (MK1), RON 69 gasoline fuel and 99.5 vol% ethanol were tested. Fixed fueling rate and single injection strategy were employed.

Partially premixed combustion (PPC) is intended to improve fuel efficiency and minimize the engine-out emissions. PPC is known to have the potential to reduce emissions of nitrogen oxides (NOx) and soot, but often at the expense of increased emissions of unburned hydrocarbons (HC) and carbon monoxide (CO). PPC has demonstrated remarkable fuel flexibility and can be operated with a large variety of liquid fuels, ranging from low-octane, high-cetane diesel fuels to high-octane gasolines and alcohols. Several research groups have demonstrated that naphtha fuels provide a beneficial compromise between functional load range and low emissions. To increase the understanding of the influence of individual fuel components typically found in commercial fuels, such as alkenes, aromatics and alcohols, a systematic experimental study of 15 surrogate fuel mixtures of n-heptane, isooctane, toluene and ethanol was performed in a light-duty PPC engine using a design of experiment methodology.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

Partially Premixed Combustion, PPC, with 50% Exhaust Gas Recirculation (EGR) at lean combustion conditions λ =1.5, has shown good efficiency and low emissions in a heavy-duty single-cylinder engine. To meet emission requirements in all loads and transient operation, aftertreatment devices are likely needed. Reducing λ to unity, when a three-way catalyst can be applied, extremely low emissions possibility exists for stoichiometric PPC. In this study, the possibility to operate clean PPC from lean condition to stoichiometric equivalence ratio with reasonable efficiency and non-excessive soot emission was investigated. Two EGR rates, 48% and 38% with two fuel rates were determined for 99.5 vol% ethanol in comparison with one gasoline fuel and Swedish diesel fuel (MK1). Engine was operated at 1250 rpm and 1600 bar injection pressure with single injection. Results revealed that efficiency was reduced and soot emission increased from lean PPC to stoichiometric PPC operation.

An interest in measuring ion current in Homogeneous Charge Compression Ignition (HCCI) engines arises when one wants to use a cheaper probe for feedback of the combustion timing than expensive piezo electric pressure transducers. However the location of the ion current probe, in this case a spark plug, is of importance for both signal strength and the crank angle position where the signal is obtained. Different fuels will probably affect the ion current in both signal strength and timing and this is the main interest of this investigation. The measurements were performed on a Scania D12 engine in single cylinder operation and ion current was measured at 7 locations simultaneously. By arranging this setup there was a possibility to investigate if the ion current signals from the different spark plug locations would correlate with the fact that, for this particular engine, the combustion starts at the walls and propagates towards the centre of the combustion chamber.

The potential of a Homogeneous Charge Compression Ignition (HCCI) engine with variable compression ratio has been experimentally investigated. The experiments were carried out in a single cylinder engine, equipped with a modified cylinder head. Altering the position of a secondary piston in the cylinder head enabled a change of the compression ratio. The secondary piston was controlled by a hydraulic system, which was operated from the control room. Dual port injection systems were used, which made it possible to change the ratio of two different fuels with the engine running. By mixing iso-octane with octane number 100 and normal heptane with octane number 0, it was possible to obtain any octane rating between 0 and 100. By using an electrical heater for the inlet air, it was possible to adjust the inlet air temperature to a selected value.

Premixed Charge Compression Ignition concepts are promising to reduce NOx and soot simultaneously and keeping a high thermal efficiency. Partially premixed combustion is a single fuel variant of this new combustion concepts applying a fuel with a low cetane number to achieve the necessary long ignition delay. In this study, multiple injection strategies are studied in the partially premixed combustion approach to reach stable combustion and ultra-low NOx and soot emission at 15.5 bar gross indicated mean effective pressure. Three different injection strategies (single injection, pilot-main injection, main-post injection) are experimentally investigated on a heavy duty compression ignition engine. A fuel blend (70 vol% n-butanol and 30 vol% n-heptane) was tested. The effects of different pilot and post-injection timing, as well as Exhaust-gas Recirculation rate on different injection strategies investigated.

N-butanol, as a biomass-based renewable fuel, has many superior fuel properties. It has a higher energy content and cetane number than its alcohol competitors, methanol and ethanol. Previous studies have proved that n-butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency when blended with diesel. However, most studies on n-butanol are limited to low blending ratios, which restricts the improvement of emissions. In this paper, 80% by volume of n-butanol was blended with 20% by volume of n-heptane (namely BH80). The influences of various engine parameters (combustion phasing, EGR ratio, injection timing and intake pressure, respectively) on its combustion and emission characteristics are tested at different loads. The results showed that when BH80 uses more than 40% EGR, the emitted soot and nitrogen oxides (NOx) emissions are below the EURO VI legislation.

When applying high amount of EGR (exhaust gas recirculation) in Partially Premixed Combustion (PPC) using diesel fuel, an increase in soot emission is observed as a penalty. To better understand how EGR affects soot particles in the cylinder, a fast gas sampling technique was used to draw gas samples directly out of the combustion chamber in a Scania D13 heavy duty diesel engine. The samples were characterized on-line using a scanning mobility particle sizer for soot size distributions and an aethalometer for black carbon (soot) mass concentrations. Three EGR rates, 0%, 56% and 64% were applied in the study. It was found that EGR reduces both the soot formation rate and the soot oxidation rate, due to lower flame temperature and a lower availability of oxidizing agents. With higher EGR rates, the peak soot mass concentration decreased. However, the oxidation rate was reduced even more.

This study examines fuel auto-ignitability and shows a method for determining fuel performance for HCCI combustion by doing engine experiments. Previous methods proposed for characterizing HCCI fuel performance were assessed in this study and found not able to predict required compression ratio for HCCI auto-ignition (CRAI) at a set combustion phasing. The previous indices that were studied were the Octane Index (OI), developed by Kalghatgi, and the HCCI Index, developed by Shibata and Urushihara. Fuels with the same OI or HCCI Index were seen to correspond to a wide range of compression ratios in these experiments, so a new way to describe HCCI fuel performance was sought. The Lund-Chevron HCCI Number was developed, using fuel testing in a CFR engine just as for the indices for spark ignition (research octane number and motor octane number, RON and MON) and compression ignition (cetane number, CN).

Methanol is today considered a viable green fuel for combustion engines because of its low soot emissions and the possibility of it being produced in a CO2-neutral manner. Methanol as a fuel for combustion engines have attracted interest throughout history and much research was conducted during the oil crisis in the seventies. In the beginning of the eighties the oil prices began to decrease and interest in methanol declined. This paper presents the emission potential of methanol. T-Φ maps were constructed using a 0-D reactor with constant pressure, temperature and equivalence ratio to show the emission characteristics of methanol. These maps were compared with equivalent maps for diesel fuel. The maps were then complemented with engine simulations using a stochastic reactor model (SRM), which predicts end-gas emissions. The SRM was validated using experimental results from a truck engine running in Partially Premixed Combustion (PPC) mode at medium loads.

CO2 regulations on heavy-duty transport are introduced in essentially all markets within the next decade, in most cases in several phases of increasing stringency. To cope with these mandates, developers of engines and related equipment are aiming to break new ground in the fields of combustion, fuel and hardware technologies. In this work, a novel diesel fuel injector, Delphi’s DFI7, is utilized to experimentally investigate and compare the performance of ramped injection rates versus traditional square fueling profiles. The aim is specifically to shift the efficiency and NOx tradeoff to a more favorable position. The design of experiments methodology is used in the tests, along with statistical techniques to analyze the data. Results show that ramped and square rates - after optimization of fueling parameters - produce comparable gross indicated efficiencies.