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Diesel engines have been used in large vehicles, locomotives and ships as more efficient alternatives to the gasoline engines. They have also been used in small passenger vehicle applications, but have not been as popular as in other applications until recently. The two main factors that kept them from becoming the major contender in the small passenger vehicle applications were the low power outputs and the noise levels. A combination of improved mechanical technologies such as multiple injection, higher injection pressure, and advanced electronic control has mostly mitigated the problems associated with the noise level and changed the public notion of the Diesel engine technology in the latest generation of common-rail designs. The power output of the Diesel engines has also been improved substantially through the use of variable geometry turbines combined with the advanced fuel injection technology.

The low temperature conditions that occur during high efficiency clean combustion (HECC) often lead to the formation of partially oxidized HC species such as aldehydes, ketones and carboxylic acids. Using the diesel fuels specified by the Fuels for Advanced Combustion Engines (FACE) working group, carbonyl species were collected from the exhaust of a light duty diesel engine operating under HECC conditions. High pressure liquid chromatography - mass spectrometry (LC-MS) was used to speciate carbonyls as large as C 9 . A relationship between carbonyl species formed in the exhaust and fuel composition and properties was determined. Data were collected at the optimum fuel efficiency point for a typical road load condition. Results of the carbonyl analysis showed changes in formaldehyde and acetaldehyde formation, formation of higher molecular weight carbonyls and the formation of aromatic carbonyls.

The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and1H/13C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT™) apparatus.

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studies that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

The combustion and exhaust emission characteristics of a DME fueled HCCI engine were investigated. Different fuel injection strategies were tested under various injection quantities and timings with exhaust gas recirculation (EGR). The combustion phase in HCCI was changed by an in-cylinder direct injection and EGR, due to changes in the in-cylinder temperature and mixture homogeneity. The gross indicated mean effective pressure (IMEPgross) increased and the hydrocarbon (HC) and carbon monoxide (CO) emissions decreased as the equivalence ratio was augmented. The IMEPgross with direct injection was greater than with the port injection due to retarded ignition timing resulting from latent heat of direct injected DME fuel. It was because that most of burn duration was completed before top dead center owing to higher ignitability for DME with high cetane number. However, HC and CO emissions were similar for both injection locations.

Stringent fuel economy and emissions regulations have driven development of new mixture preparation technologies and increased spark-ignition engine complexity. Additional degrees of freedom, brought about by devices such as cam phasers and charge motion control valves, enable greater range and flexibility in engine control. This permits significant gains in fuel efficiency and emission control, but creates challenges related to proper engine control and calibration techniques. Accurate experimental characterization of high degree of freedom engines is essential for addressing the controls challenge. In particular, this paper focuses on the evaluation of three experimental residual gas fraction measurement techniques for use in a spark ignition engine equipped with dual-independent variable camshaft phasing (VVT).

Low-sulfur “clean” diesel fuel has been mandated in the US and Europe. However, quality of diesel fuel, particularly the sulfur content, varies significantly in other parts of the world. Due to logistical issues in various theaters of operation, the Army is often forced to rely on local fuel supplies, which exposes vehicles to diesel fuel or jet fuel (JP-8) with elevated levels of sulfur. Modern engines typically use cooled Exhaust Gas Recirculation (EGR) to meet emissions regulations. Using high-sulfur fuels and cooled EGR elevates problems associated with cooler fouling and corrosion of engine components. Hence, an experimental study has been carried out in a heavy-duty diesel engine running on standard JP-8 fuel and fuel doped with 2870 ppm of sulfur. Gas was sampled from the EGR cooler and analyzed using a condensate collection device developed according to a modified ASTM 3226-73T standard. Engine-out emissions were analyzed in parallel.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

The CRC Fuels for Advanced Combustion Engines (FACE) Working Group has provided a matrix of experimental diesel fuels for use in studies on the effects of three parameters, Cetane number (CN), aromatics content, and 90 vol% distillation temperature (T90), on combustion and emissions characteristics of advanced combustion strategies. Various types of fuel analyses and engine experiments were performed in well-known research institutes. This paper reviews a collection of research findings obtained with these nine fuels. An extensive collection of analyses were performed by members of the FACE working group on the FACE diesel fuels as a means of aiding in understanding the linkage between fuel properties and combustion and emissions performance. These analyses included non-traditional chemical techniques as well as established ASTM tests. In a few cases, both ASTM tests and advanced analyses agreed that some design variables differed from their target values when the fuels were produced.

The combustion process in a diesel engine was simulated using KIVA-II, a multi-dimensional computer code. The original combustion model in KIVA-II is based on chemical kinetics, and thus fails to capture the effects of turbulence on combustion. A mixing-controlled, eddy break-up combustion model was implemented into the code. Realistic diesel fuel data were also compiled. Subsequently, the sensitivity of the code to a number of parameters related to fuel injection, mixing, and combustion was studied. Spray injection parameters were found to have a strong influence on the model's predictions. Higher injection velocity and shorter injection duration result in a higher combustion rate and peak pressure and temperature. The droplet size specified at injection significantly affects the rate of spray penetration and evaporation, and thus the combustion rate. Contrary to expectation, the level of turbulence at the beginning of the calculation did not affect fuel burning rate.

Homogenous Charge Compression Ignition (HCCI) engines offer a good potential for achieving high fuel efficiency while virtually eliminating NOx and soot emissions from the exhaust. However, realizing the full fuel economy potential at the vehicle level depends on the size of the HCCI operating range. The usable HCCI range is determined by the knock limit on the upper end and the misfire limit at the lower end. Previously proven high sensitivity of the HCCI process to thermal conditions leads to a hypothesis that combustion chamber deposits (CCD) could directly affect HCCI combustion, and that insight about this effect can be helpful in expanding the low-load limit. A combustion chamber conditioning process was carried out in a single-cylinder gasoline-fueled engine with exhaust re-breathing to study CCD formation rates and their effect on combustion. Burn rates accelerated significantly over the forty hours of running under typical HCCI operating conditions.

Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate.

The Energy Independence and Security Act of 2007 requires the U.S. to use 36 billion gallons of renewable fuel per year by 2022. Domestic ethanol production has increased steadily in recent years, growing from less than 5 billion gallons per year (bgpy) in 2006 to over 13 bgpy in 2010. While there is interest in developing non-oxygenated renewable fuels for use in conventional vehicles as well as interest in expanding flex-fuel vehicle (FFV) production for increased E85 use, there remains concern that EISA compliance will require further use of oxygenated biofuels in conventional vehicles. The Environmental Protection Agency (EPA) recently granted partial approval to a waiver allowing the use of E15 in 2001 and newer light-duty vehicles.

The effect of biodiesel produced from waste cooking oil (WCO) on the soot particles in a compression ignition engine was investigated and compared with conventional diesel fuel. The indicated mean effective pressure of approximately 0.65 MPa was tested under an engine speed of 1200 revolutions per minute. The fuels were injected at an injection timing of −5 crank angle degree after top dead center with injection pressures of 80 MPa. Detailed characteristics of particulate matters were analyzed in terms of transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and elemental analysis. Soot aggregates were collected on TEM grid by thermophoretic sampling device installed in the exhaust pipe of the engine. High-resolution TEM images revealed that the WCO biodiesel soot was composed of smaller primary particle than diesel soot. The mean primary particle diameter was measured as 19.9 nm for WCO biodiesel and 23.7 nm for diesel, respectively.

During the 1980s, the U.S. Environmental Protection Agency (EPA) incorporated the R factor into fuel economy calculations in order to address concerns about the impacts of test fuel property variations on corporate average fuel economy (CAFE) compliance, which is determined using the Federal Test Procedure (FTP) and Highway Fuel Economy Test (HFET) cycles. The R factor is defined as the ratio of the percent change in fuel economy to the percent change in volumetric heating value for tests conducted using two differing fuels. At the time the R-factor was devised, tests using representative vehicles initially indicated that an appropriate value for the R factor was 0.6. Reassessing the R factor has recently come under renewed interest after EPA's March 2013 proposal to adjust the properties of certification gasoline to contain significant amounts of ethanol.

A methodology for developing modal vehicle emissions and fuel consumption models is described. These models, in the form of look-up tables for fuel consumption and emissions as functions of vehicle speed and acceleration, are designed for simulations such as the Federal Highway Administration's TRAF-series of models. These traffic models are used to evaluate the impacts of roadway design on emissions and fuel consumption. Vehicles are tested on-road and on a chassis dynamometer to characterize the entire operating range of each vehicle. As a verification exercise the models were used to predict cycle emissions and fuel consumption, and the results were compared to certification-type tests on a different population of vehicles. Results of the verification exercise show that the developed models can generally predict cycle emissions and fuel consumption with error comparable to the variability of repeat dynamometer tests.

A study has been conducted in order to investigate the effect of the location of knock initiation on heat flux in a Spark-Ignition (SI) combustion chamber. Heat flux measurements were taken on the piston and cylinder head under different knock intensity levels, induced by advancing the spark timing. Tests were performed with two engine configurations, the first with the spark-plug located on the rear side of the chamber and the other having a second non-firing spark-plug placed at the front side of the chamber. The presence of the non-firing spark-plug consistently shifted the location of autoignition initiation from the surface of the piston to its vicinity, without causing a noticeable increase in knock intensity. By localizing the initiation of knock, changes induced in the secondary flame propagation pattern affected both the magnitude and the rate of change of peak heat flux under heavy knock.

Dimethyl-ether combustion with pilot injection was investigated in a single cylinder direct injection diesel engine equipped with a common-rail injection system. Combustion characteristics and emissions were tested with dimethyl-ether and compared with diesel fuel. The main injection timing was fixed to have the best timings for maximum power output. The total injected fuel mass corresponded to a low heating value of 405 joules per cycle at 800 rpm. The fuel quantity and the injection timing of the pilot injection were varied from 8 to 20% of the total injected mass and from 50 to 10 crank angle degrees before the main injection timing, respectively. Ignition delay decreased with pilot injection. The effects of pilot injection were less significant with DME combustion than with diesel. Pilot injection caused the main combustion to increase in intensity resulting in decreased emissions of hydrocarbons, carbon monoxide and particulate matter.

Direct injection of natural gas under high pressure conditions has emerged as a promising option for improving engine fuel economy and emissions. However, since the gaseous injection technology is new, limited experience exists as to the optimum configuration of the injection system and associated combustion chamber design. The present study uses KIVA-3 based, multidimensional modeling to improve the understanding and assist the optimization of the gaseous injection process. Compared to standard k-ε models, a Renormalization Group Theory (RNG) based k-ε model [1] has been found to be in better agreement with experiments in predicting gaseous penetration histories for both free and confined jet configurations. Hence, this validated RNG model is adopted here to perform computations in realistic engine geometries.