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A promising SCR-only solution is presented to meet post-2010 NOx emission targets for heavy duty applications. The proposed concept is based on an engine from a EURO IV SCR application, which is considered optimal with respect to fuel economy and costs. The addition of advanced SCR after treatment comprising a standard and a close-coupled SCR catalyst offers a feasible emission solution, especially suited for EURO VI. In this paper, results of a simulation study are presented. This study concentrates on optimizing SCR deNOx performance. Simulation results of cold start FTP and WHTC test cycles are presented to demonstrate the potential of the close-coupled SCR concept. Comparison with measured engine out emissions of an EGR engine shows that a close-coupled SCR catalyst potentially has NOx reduction performance as good as EGR. Practical issues regarding the use of an SCR catalyst in close-coupled position will be addressed, as well as engine and exhaust layout.

Global demand for alternative fuels to combat rising energy costs has sparked a renewed interest in catalysts that can effectively remediate NOx emissions resulting from combustion of a range of HC based fuels. Because many of these new engine technologies rely on lean operating environments to produce efficient power, the resulting emissions are also present in a lean atmosphere. While HCs are easily controlled in such environments, achieving high NOx conversion to N2 has continued to elude fully satisfactory solution. Until recently, most approaches have relied on catalysts with precious metals to either store NOx and subsequently release it as N2 under rich conditions, or use NH3 SCR catalysts with urea injection to reduce NOx under lean conditions. However, new improvements in Ag based technologies also look very promising for NOx reduction in lean environments.

Heavy-duty diesel engines are used in different application areas, like long-haul, city distribution, dump truck and building and construction industry. For these wide variety of areas, the engine performance needs to comply with the real-world legislation limits and should simultaneously have a low fuel consumption and good drivability. Meeting these requirements takes substantial development and calibration effort, where an optimal fuel consumption for each application is not always met in practice. TNO's Integrated Emission Management (IEM) strategy, is able to deal with these variations in operating conditions, while meeting legislation limits and obtaining on-line cost optimization. Based on the actual state of the engine and aftertreatment, optimal air-path setpoints are computed, which balances EGR and SCR usage.

To meet future emission targets, it becomes increasingly important to optimize the synergy between engine and aftertreatment system. By using an integrated control approach minimal fluid (fuel and DEF) consumption is targeted within the constraints of emission legislation during real-world operation. In such concept, the on-line availability of engine-out NOx emission is crucial. Here, the use of a Virtual NOx sensor can be of great added-value. Virtual sensing enables more direct and robust emission control allowing, for example, engine-out NOx determination during conditions in which the hardware sensor is not available, such as cold start conditions. Furthermore, with use of the virtual sensor, the engine control strategy can be directly based on NOx emission data, resulting in reduced response time and improved transient emission control. This paper presents the development and on-line implementation of a Virtual NOx sensor, using in-cylinder pressure as main input.

Selective Catalytic Reduction (SCR) is the dominant solution for meeting future NOx reduction regulations for heavy-duty diesel powertrains. SCR systems benefit from closed-loop control if an appropriate exhaust gas sensor were available. An ammonia sensor has recently been developed for use as a feedback element in closed-loop control of urea dosing in a diesel SCR aftertreatment system. Closed-loop control of SCR dosing enables the SCR system to be robust against disturbances and to meet conformity of production (COP) and in-use compliance norms. The ammonia sensor is based on a non-equilibrium electrochemical principle and outputs emf signals. The sensor performs well when tested in a diesel engine exhaust environment and has minimum cross interference with CO, HC, NO, NO2, SO2, H2O and O2. Previous work, done in a simulation environment, demonstrated that an ammonia sensor provides the optimal feedback for urea dosing control algorithms in closed-loop SCR systems.

Low-cost lean NOx aftertreatment is one of the main challenges facing high-efficiency gasoline and diesel engines operating with lean mixtures. While there are many candidate technologies, they all offer tradeoffs. We have investigated a multi-component Dual SCR aftertreatment system that is capable of obtaining NOx reduction efficiencies of greater than 90% under lean conditions, without the use of precious metals or urea injection into the exhaust. The Dual SCR approach here uses an Ag HC-SCR catalyst followed by an NH3-SCR catalyst. In bench reactor studies from 150 °C to 500 °C, we have found, for modest C/N ratios, that NOx reacts over the first catalyst to predominantly form nitrogen. In addition, it also forms ammonia in sufficient quantities to react on the second NH3-SCR catalyst to improve system performance. The operational window and the formation of NH3 are improved in the presence of small quantities of hydrogen (0.1–1.0%).

With the wider use of biofuels in the marketplace, a program was conducted to study the deposit forming tendencies and performance of E85 (85% denatured ethanol and 15% gasoline) in a modern Flexible Fuel Vehicle (FFV). The test vehicle for this program was a 2006 General Motors Chevrolet Impala FFV equipped with a 3.5 liter V-6 powertrain. A series of 5,000 mile Chassis Dynamometer (CD) Intake Valve Deposits (IVD) and performance tests were conducted while operating the FFV on conventional (E0) regular unleaded gasoline and E85 to determine the deposit forming tendencies of both fuels. E85 test fuels were found to generate significantly higher levels of IVD than would have been predicted from the base gasoline component alone. The effects on the weight and composition of IVD due to a corrosion inhibitor and sulfates that were indigenous to one of the ethanols were also studied.

This paper includes a numerical and experimental study of fluid flow in automotive catalytic converters. The numerical work involves using computational fluid dynamics (CFD) to perform three-dimensional calculations of turbulent flow in an inlet pipe, inlet cone, catalyst substrate (porous medium), outlet cone, and outlet pipe. The experimental work includes using hot-wire anemometry to measure the velocity profile at the outlet of the catalyst substrate, and pressure drop measurements across the system. Very often, the designer may have to resort to offset inlet and outlet cones, or angled inlet pipes due to space limitations. Hence, it is very difficult to achieve a good flow distribution at the inlet cross section of the catalyst substrate. Therefore, it is important to study the effect of the geometry of the catalytic converter on flow uniformity in the substrate.

Implementation of real-time combustion feedback for use in closed-loop combustion control is a technology that has potential to assist in the successful production implementation of advanced diesel combustion modes. Low-temperature, pre-mixed diesel combustion is presently of interest because it offers the ability to lower the engine-out emissions of oxides of nitrogen (NOx) and particulate matter (PM). The need for lowering these two emissions is driven by tighter regulations enacted worldwide, especially the NOx limits in the United States. Reducing engine-out emissions eases the need for additional exhaust aftertreatment devices and their associated cost and mass. In this paper we will describe an experimental cylinder pressure-based control system and present both steady-state and transient results from a diesel engine employing a pre-mixed type of combustion.

Modern engines are becoming highly complex, with several strongly interactive subsystems - - variable cam phasers on both intake and exhaust, along with various kinds of variable valve lift mechanisms. Isolated component models may not yield adequate information to deal with system-level interactive issues, especially when it comes to transient behavior. In addition, massive amounts of expensive experimental work will be required for optimization. Recent computing speed improvements are beginning to permit the use of co-simulation to couple highly detailed and accurate submodels of the various engine components, each created using the most appropriate available simulation package. This paper describes such a system model using GT-Power to model the engine, AMESim to model cam phasers and the engine lubrication system, and Matlab/Simulink to model the engine controllers and the vehicle.

To meet 2010 emission targets, optimal SCR system performance is required. In addition, attention has to be paid to in-use compliance requirements. Closed-loop control seems an attractive option to meet the formulated goals. This study deals with the potential and limitations of closed-loop SCR control. High NOx conversion in combination with acceptable NH3 slip can be realized with an open-loop control strategy. However, closed-loop control is needed to make the SCR system robust for urea dosage inaccuracy, catalyst ageing and NOx engine-out variations. Then, the system meets conformity of production and in-use compliance norms. To demonstrate the potential of closed-loop SCR control, a NOx sensor based control strategy with cross-sensitivity compensation is compared with an adaptive surface coverage/NH3 slip control strategy and an open-loop strategy. The adaptive surface coverage/NH3 slip control strategy shows best performance over simulated ESC and ETC cycles.

A key quantity for use in engine control is the exhaust manifold pressure. For production applications it is an important component in the calculation of the engine volumetric efficiency, as well as EGR flow and residual fraction. For cost reasons, however, it is preferable to not have to measure the exhaust manifold pressure for production applications. For that reason, it is advantageous to develop a model for estimating the exhaust manifold pressure in production application software that is small, accurate, and simple to calibrate. In this paper, a mean-value model for calculating the exhaust manifold pressure is derived from the compressible flow equation, treating the exhaust system as a fixed-geometry restriction between the exhaust manifold and the outlet of the tailpipe. Validation data from production applications is presented.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

Reaching EUROVI Heavy Duty emission limits will result in more testing time for developing control and OBD algorithms than to reach EUROV emissions. It is likely that these algorithms have to be adapted for a WHTC (World Heavy Duty Transient Cycle) for EUROVI. This cycle when started cold can only be performed a limited times a day on the engine testbench, because of the cooling down time. The development time and cost increases to reach EUROVI emission levels. Accurate simulation tools can reduce the time and costs by reducing the amount of tests required on the testbench. In order to use simulation tools to develop pre calibrations, the models must be fitted and validated. This paper will focus on the fit process of an SCR (Selective Catalytic Reduction) model. A unique test procedure has been developed to characterize an SCR catalyst using an engine testbench in ±2 days. This data is used in an automatic SCR fit tool to obtain the model parameters in a few days.

The need for improved emissions control in lean exhaust to meet tightening, world-wide NOx emissions standards has led to the development of selective catalytic reduction of NOx with ammonia as a major technology for emissions control. Current systems are being designed to use a solution of urea (32.5 wt %) dissolved in water or Diesel Exhaust Fluid (DEF) as the ammonia source. While DEF or AdBlue® is widely used as a source of ammonia, it has a number of issues at low temperatures, including freezing below −12 °C, solid deposit formation in the exhaust, and difficulties in dosing at exhaust temperatures below 200 °C. Additionally creating a uniform ammonia concentration can be problematic, complicating exhaust packaging and usually requiring a discrete mixer.

Improving fuel economy, emissions, passenger comfort and convenience, safety, and vehicle performance in the automobile is resulting in the growth of electrical loads. In order to meet these electrical load demands and to meet the requirement of power generation when the engine is off, several technologies are on the horizon for on-board power generation in the vehicles. In this paper, new on-board power generation technologies based on the solid oxide fuel cell (SOFC), proton exchange membrane (PEM) fuel cell, thermo-photovoltaic (TPV) system, and diamond or carbon nanostructures are compared in terms power density, cost, and long term feasibility for automotive applications.

In the past decade, SCR deNOx technology with urea injection has grown to maturity. European OEMs will apply SCR deNOx to meet future heavy-duty emissions legislation starting with EURO-4 (2005/2006). Numerous research programs in Europe and the US have shown a variety of system layouts and control strategies. The main differences are formed by: the engine-out NOx calibration the application of an NO to NO2 catalyst open-loop or closed-loop urea dosage control. This paper gives an overview of possible SCR system configurations that are required for different stages of future emission legislation. Engine-out NOx emission is strongly influenced by ambient conditions. Projections in this study show that a combination of cold climate and a wintergrade fuel is the most severe: it may lead to 30% lower engine-out NOx emission with respect to laboratory conditions.

Implementation of engine turnoff at idle is desirable to gain improvements in vehicle fuel economy. There are a number of alternatives for implementation of the restarting function, including the existing cranking motor, a 12V or 36V belt-starter, a crankshaft integrated-starter-generator (ISG), and other, more complex hybrid powertrain architectures. Of these options, the 12V belt-alternator-starter (BAS) offers strong potential for fast, quiet starting at a lower system cost and complexity than higher-power 36V alternatives. Two challenges are 1) the need to accelerate a large engine to idle speed quickly, and 2) dynamic torque control during the start for smoothness. In the absence of a higher power electrical machine to accomplish these tasks, combustion-assisted starting has been studied as a potential method of aiding a 12V accessory drive belt-alternator-starter in the starting process on larger engines.

A new single-brick Ba + alkali metals NOx-Trap catalyst has been developed to replace a two-brick NOx-Trap system containing a downstream three-way catalyst. Major development efforts include: 1) platinum group metals selection for higher HC oxidation with potassium-containing washcoat, 2) alumina and ceria selection, and Rh architecture design for more efficient NOx reduction and 3) NiO to suppress H2S odor. Mitsubishi Motors' 1.8L GDI™ with this Delphi new NOx-Trap catalyst with H2S control achieves J-LEV standard with less cost and lower backpressure compared to the previous model. It is further discovered that incorporation of NiO into the NOx-Trap washcoat is effective for H2S control during sulfur purge but has a negative impact on thermal durability and sulfur resistance. Further study to improve this trade-off has been made and preliminary results of an advanced washcoat design are presented in this paper. Details will be reported in a future publication.

This paper reports on a study of the TNO venturi EGR system and the Johnson Matthey CRT particulates trap on a DAF 355 kW engine. The results obtained indicate that this EGR-CRT combination is an effective means to achieve EURO-4 emission level, while maintaining good fuel economy. EGR strategy, injection timing and air-fuel ratio were optimised in such a way that good regeneration conditions were obtained across most of the engine operating map. Also transient EGR control is optimised to combine low NOx emission during the ETC with good driveability and good engine out particulates emission. The size of the oxidation catalyst in the CRT was investigated. It appeared that the larger oxidation catalyst showed a better regeneration performance during a low temperature duty-cycle. Negative aspects of a larger oxidation catalyst are increased costs and increased NO2 emission (because of the catalyst ability to oxidise more NO into NO2).