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Journal Article

Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

2009-06-15
2009-01-1790
Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.
Journal Article

Resonance of a Spring Opposed Free Piston Engine Device

2016-04-05
2016-01-0568
Recent free piston engine research reported in the literature has included development efforts for single and dual cylinder devices through both simulation and prototype operation. A single cylinder, spring opposed, oscillating linear engine and alternator (OLEA) is a suitable architecture for application as a steady state generator. Such a device could be tuned and optimized for peak efficiency and nominal power at unthrottled operation. One of the significant challenges facing researchers is startup of the engine. It could be achieved by operating the alternator in a motoring mode according to the natural system resonant frequency, effectively bouncing the translator between the spring and cylinder, increasing stroke until sufficient compression is reached to allow introduction of fuel and initiation of combustion. To study the natural resonance of the OLEA, a numeric model has been built to simulate multiple cycles of operation.
Journal Article

Effect of Combustion Timing and Heat Loss on Spring-Assisted Linear Engine Translator Motion

2016-04-05
2016-01-0560
The free piston linear engine has the potential to achieve high efficiency and might serve as a viable platform for robust implementation of low temperature combustion schemes (such as homogeneous charge compression ignition - HCCI) due to its ability to vary compression and stroke in response to cylinder and load events. A major challenge is control of the translator motion. Lack of geometric constraint on the piston leads to uncertainty about its top dead center position and timing. While combustion control depends on knowledge of the piston motion, the combustion event also affects the motion profile of the piston. To advance understanding of this coupled system, a numeric model was developed to simulate multiple cycles of a dual cylinder, spring assisted, 2-stroke HCCI, free piston linear engine generator.
Technical Paper

Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy

2006-10-16
2006-01-3301
The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).
Journal Article

Analysis of Ethanol Fuel Blends

2013-11-20
2013-01-9071
In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.
Journal Article

Heat of Vaporization Measurements for Ethanol Blends Up To 50 Volume Percent in Several Hydrocarbon Blendstocks and Implications for Knock in SI Engines

2015-04-14
2015-01-0763
The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.
Technical Paper

Emissions Testing of a Hybrid Fuel Cell Bus

1998-02-23
980680
The fuel cell bus program at Georgetown University (GU) has directed the operational development and testing of three hybrid fuel cell powered buses for transit operation. These are the world's first liquid-fueled, fuel cell powered road vehicles. This paper describes the emissions testing of one of these buses on a heavy duty chassis dynamometer at West Virginia University (WVU). The tested bus was driven by a 120 kW DC motor and utilized a 50 kW phosphoric acid fuel cell (PAFC) as an energy source with a 100 kW battery for supplemental power. A methanol/water fuel mixture was converted by a steam reformer to a hydrogen rich gas mixture for use in a fuel cell stack. Emissions from the reformer, fuel cell stack and startup burner were monitored for both transient and steady-state operation.
Technical Paper

A Parametric Study of Knock Control Strategies for a Bi-Fuel Engine

1998-02-23
980895
Until a proper fueling infrastructure is established, vehicles powered by natural gas must have bi-fuel capability in order to avoid a limited vehicle range. Although bi-fuel conversions of existing gasoline engines have existed for a number of years, these engines do not fully exploit the combustion and knock properties of both fuels. Much of the power loss resulting from operation of an existing gasoline engine on compressed natural gas (CNG) can be recovered by increasing the compression ratio, thereby exploiting the high knock resistance of natural gas. However, gasoline operation at elevated compression ratios results in severe engine knock. The use of variable intake valve timing in conjunction with ignition timing modulation and electronically controlled exhaust gas recirculation (EGR) was investigated as a means of controlling knock when operating a bi-fuel engine on gasoline at elevated compression ratios.
Technical Paper

Numerical Prediction of Knock in a Bi-Fuel Engine

1998-10-19
982533
Dedicated natural gas engines suffer the disadvantages of limited vehicle range and relatively few refueling stations. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. However, the bi-fuel engine must be made to provide equal performance on both fuels. Although bi-fuel conversions have existed for a number of years, historically natural gas performance is degraded relative to gasoline due to reduced volumetric efficiency and lower power density of CNG. Much of the performance losses associated with CNG can be overcome by increasing the compression ratio. However, in a bi-fuel application, high compression ratios can result in severe engine knock during gasoline operation. Variable intake valve timing, increased exhaust gas recirculation and retarded ignition timing were explored as a means of controlling knock during gasoline operation of a bi-fuel engine.
Technical Paper

Emissions from Trucks using Fischer-Tropsch Diesel Fuel

1998-10-19
982526
The Fischer-Tropsch (F-T) catalytic conversion process can be used to synthesize diesel fuels from a variety of feedstocks, including coal, natural gas and biomass. Synthetic diesel fuels can have very low sulfur and aromatic content, and excellent autoignition characteristics. Moreover, Fischer-Tropsch diesel fuels may also be economically competitive with California diesel fuel if produced in large volumes. An overview of Fischer-Tropsch diesel fuel production and engine emissions testing is presented. Previous engine laboratory tests indicate that F-T diesel is a promising alternative fuel because it can be used in unmodified diesel engines, and substantial exhaust emissions reductions can be realized. The authors have performed preliminary tests to assess the real-world performance of F-T diesel fuels in heavy-duty trucks. Seven White-GMC Class 8 trucks equipped with Caterpillar 10.3 liter engines were tested using F-T diesel fuel.
Technical Paper

A Long Term Field Emissions Study of Natural Gas Fueled Refuse Haulers in New York City

1998-10-19
982456
New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these vehicles was for street collection and transporting the collected refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines.
Technical Paper

The Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-out and Tailpipe Particulate Matter Emissions

2010-10-25
2010-01-2125
In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.
Technical Paper

Chemical Speciation of Exhaust Emissions from Trucks and Buses Fueled on Ultra-Low Sulfur Diesel and CNG

2002-03-04
2002-01-0432
A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Fischer-Tropsch Diesel Fuels - Properties and Exhaust Emissions: A Literature Review

2003-03-03
2003-01-0763
Natural gas, coal, and biomass can be converted to diesel fuel through Fischer-Tropsch (F-T) processes. Variations of the F-T process and/or product work-up can be used to tailor the fuel properties to meet end-users needs. Regardless of feedstock or process, F-T diesel fuels typically have a number of very desirable properties. This review describes typical F-T diesel fuel properties, discusses how these fuel properties impact pollutant emissions, and draws together data from known engine and chassis dynamometer studies of emissions. The comparison of fuel properties reveals that F-T diesel fuel is typically one of two types - a very high cetane number (>74), zero aromatic product or a moderate cetane (∼60), low aromatic (≤15%) product. The very high cetane fuels typically have less desirable low temperature properties while the moderate cetane fuels have cold flow properties more typical of conventional diesel fuels.
Technical Paper

Hydrocarbon Speciation of a Lean Burn Spark Ignited Engine

1997-10-01
972971
A research program at West Virginia University sought to identify and quantify the individual hydrocarbon species present in alternative fuel exhaust. Compressed natural gas (CNG) has been one of the most widely researched fuels proposed to replace liquid petroleum fuels. Regulated CNG non-methane hydrocarbon emissions are often lower than hydrocarbon emissions from conventional liquid fuels because of the absence of heavier hydrocarbons in the fuel. Reducing NOx and non-methane organic gas (NMOG) emission levels reduces the ozone forming potential (OFP) of the exhaust gases. A Hercules GTA 3.7 liter medium duty CNG engine was operated at seven load and speed set points using local supply CNG gas. The engine was operated at several rated, intermediate and idle speed set points. The engine was operated while the air/fuel ratio value was varied.
Technical Paper

Exhaust Gas Recirculation in a Lean-Burn Natural Gas Engine

1998-05-04
981395
Lean-burn natural gas engines offer attractively low particulate matter emissions and enjoy higher efficiencies than their stoichiometric counterparts. However, even though oxides of nitrogen emissions can be reduced through operation at lambda ratios of greater than 1.3, catalysts cannot reduce the oxides of nitrogen emissions in the oxidizing exhaust environment. Exhaust Gas Recirculation (EGR) offers the potential to reduce engine out oxides of nitrogen emissions by reducing the flame temperature and oxygen partial pressure that encourages their formation during the combustion process. A comparative study involving a change in the nature of primary diluent (air replaced by EGR) in the intake of a Hercules, 3.7 liter, lean-burn natural gas engine has been undertaken in this research. The Hercules engine was equipped with a General Motors electronically controlled EGR valve for low EGR rates, and a slide valve, constructed in house, for high EGR rates.
Technical Paper

Emissions from Trucks and Buses Powered by Cummins L-10 Natural Gas Engines

1998-05-04
981393
Both field research and certification data show that the lean burn natural gas powered spark ignition engines offer particulate matter (PM) reduction with respect to equivalent diesel power plants. Concerns over PM inventory make these engines attractive despite the loss of fuel economy associated with throttled operation. Early versions of the Cummins L-10 natural gas engines employed a mixer to establish air/fuel ratio. Emissions measurements by the West Virginia University Transportable Heavy Duty Emissions Testing Laboratories on Cummins L-10 powered transit buses revealed the potential to offer low emissions of PM and oxides of nitrogen, (NOx) but variations in the mixture could cause emissions of NOx, carbon monoxide and hydrocarbons to rise. This was readily corrected through mixer repair or readjustment. Newer versions of the L-10 engine employ a more sophisticated fueling scheme with feedback control from a wide range oxygen sensor.
Technical Paper

Performance of a High Speed Engine with Dual Fuel Capability

1994-03-01
940517
Concern over dwindling oil supplies has led to the adoption of alternate fuels to power fleet vehicles. However, during the interim period when alternate fuel supply stations are few and far between, dual fuel engines prove a necessity. In the light duty arena, these engines are typically gasoline engines modified to accommodate compressed natural gas (CNG) as an alternate fuel, but they are seldom optimized with both fuels in mind. A Saturn 1.9 liter 4 cylinder dual overhead cam engine was selected as a base for developing an optimized gasoline/CNG powerplant. Baseline data on power and steady state emissions (CO2, CO, NOx, HC) were found using the standard Saturn controller. In addition to monitoring standard sensor measurements, real-time pressure traces were taken for up to 256 cycles using a modified head with embedded PCB piezoelectric pressure transducers.
Technical Paper

Turbocharging a Bi-Fuel Engine for Performance Equivalent to Gasoline

1994-10-01
942003
A bi-fuel engine capable of operating either on compressed natural gas (CNG) or gasoline is being developed for the transition to alternative fuel usage. A Saturn 1.9 liter 4-cylinder engine was selected as a base powerplant. A control system that allows closed-loop optimization of both fuel delivery and spark timing was developed. Stock performance and emissions of the engine, as well as performance and emissions with the new controller on gasoline and CNG, have been documented. CNG operation in an engine designed for gasoline results in power loss because of the lower volumetric efficiency with gaseous fuel use, yet such an engine does not take advantage of the higher knock resistance of CNG. It is the goal of this research to use the knock resistance of CNG to recover the associated power loss. The two methods considered for this include turbocharging with a variable boost wastegate and raising the compression ratio while employing variable valve timing.
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