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Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

The effect on the intake flow field, air fuel mixing processes, thermodynamic performance and emissions output has been investigated for a range of valve operating profiles. A standard speed load point of 2000 rpm and 2.7 bar IMEP720° has been reached by throttling the intake whilst running standard cam profiles, by early closing of both inlet valves (EIVC) and by early closing of each inlet individually to generate bulk swirl motions within the cylinder. Data has been recorded at stoichiometric air fuel ratios for both direct injection and port fuelled operation. The valve profiles have been applied to two single cylinder homogeneous gasoline direct injection (GDI) spark ignition engines, developed to investigate the potential of controlling engine load by limiting the inducted air mass using fully variable valve timing (FVVT) to reduce pumping losses at part load.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

Exhaust emissions legislation for diesel engines generally limits only the mass of emitted particulate matter. This limitation reflects the concerns and measurement technology at the time the legislation was drafted. However, evolving diesel particulate filter (DPF) systems offer the potential for reductions in the mass and more importantly, the number of particles emitted from diesel exhausts. Particulate filters require frequent cleaning or regeneration of accumulated soot, if the engine is to continue to operate satisfactorily. Exothermic reactions during regeneration can lead to severe thermal gradients in the filter system resulting in damage. Fuel additives have been evaluated to show significant reductions in light off temperature which allow frequent small regeneration events to occur, under mild operating conditions.

The operating cycle of many vehicles fitted with diesel particulate filters is such that soot accumulates within the filter and must periodically be oxidised. Work was carried out on a passenger car engine to elucidate how fuel borne catalyst (FBC) to soot ratio, oxygen mass flow rate, temperature and soot loading influence the oxidation rate of soot accumulated in a sintered metal filter (SMF). Results show that soot loading had a major influence; increased soot loading increased the oxidation rate. The other parameter had a smaller influence with increasing oxygen flow rate and FBC/soot ratio each increasing the oxidation rate.

Diesel particulate filters (DPF), in conjunction with fuel borne catalysts (FBC) to facilitate regeneration, are now an accepted technology for passenger car application. Retrofitting of such systems has demonstrated the possibility of applying this technology to heavy-duty vehicles. To demonstrate the efficacy of DPF/FBC systems and to assess their affect on engine durability and economy, five heavy-duty trucks were fitted with DPF/FBC systems. After the completion of over ¼ million kms four trucks underwent a full engine strip-down and rating. This paper briefly reviews the installation of the systems and their effect on the regulated emissions, present details of the mileage accumulation and of the engine strip-downs. The conclusions drawn are that after a ¼ million km of use with the DPF/FBC systems the trucks had not suffered any abnormal deterioration and in fact there was some indication of reduced wear on the engine.

In view of increasing concern over diesel particulates and tightening legislation to control their emission, much work has been done to develop diesel particulate filters (DPFs) and systems to allow them to work reliably. Although a filter will effectively trap solid particles, any material in the vapour phase, such as unburned hydrocarbons, may pass through the filter and subsequently condense. The use of a catalytic wash coat, either on the DPF itself or on a separate substrate, has been proposed to oxidise these hydrocarbons and thus reduce the total material emitted. The use of fuel borne catalysts to aid the regeneration of trapped material within the DPF is also well documented. Such catalyst will also catalyse the oxidation of any hydrocarbons bound up within the particulate. The oxidation of such hydrocarbon occurs at a lower temperature than that of carbon itself, thus allowing lower temperature regeneration of the DPF.

Diesel particulate filter (DPF) technology is becoming increasingly established as a practical method for control of particulate emissions from diesel engines. In the year 2000, production vehicles with DPF systems, using metallic fuel additive to assist regeneration, became available in Europe. These early examples of first generation DPF technology are forerunners of more advanced systems likely to be needed by many light-duty vehicles to meet Euro IV emissions legislation scheduled for 2005. Aspects requiring attention in second generation DPF systems are a compromise between regeneration kinetics and ash accumulation. The DPF regeneration event is activated by fuel injection, either late in the combustion cycle (late injection), or after normal combustion (post injection), leading to increased fuel consumption. Therefore for optimum fuel economy, the duration of regeneration and/or the soot ignition temperature must be minimised.

In an attempt to improve ambient air quality, retrofit programmes have been encouraged; targeting reductions in PM emissions by means of diesel particulate filters (DPFs). However depending on the DPF design and operating conditions increased nitrogen dioxide (NO2) emissions have been observed, which is causing concern. Previous work showed that retrofitting a DPF system employing a fuel borne catalyst (FBC) to facilitate regeneration, reduced NO2 emissions. This paper outlines the investigation of a base metal coated DPF to enhance the reduction of NO2. Such a DPF system has been fitted to older technology buses and has demonstrated reliable field performance.

For many years now, epidemiologists have been highlighting the potential damage to health and the associated cost, caused by diesel particulate emissions. There is still debate concerning the crucial characteristics of these particles, however many authorities have concluded that it is their duty to legislate the reduction of such emissions. The most common approach is to legislate that all new vehicles should meet ever stricter emissions limits. This puts the onus and the cost on the engine manufacturers. The emissions limits in developing countries are inevitably less stringent than those in the developed world, this gives the indigenous manufacturers the opportunity to compete and develop. However, vehicle replacement intervals dictate that the effect of legislation controlling new vehicles takes many years to propagate throughout the existent vehicle fleet.

Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.

Controlled Auto-Ignition (CAI) combustion was realised in a production type 4-stroke 4-cylinder gasoline engine without intake charge heating or increasing compression ratio. The CAI engine operation was achieved using substantially standard components modified only in camshafts to restrict the gas exchange process The engine could be operated with CAI combustion within a range of load (0.5 to 4 bar BMEP) and speed (1000 to 3500 rpm). Significant reductions in both specific fuel consumption and CO emissions were found. The reduction in NOx emission was more than 93% across the whole CAI range. Though unburned hydrocarbons were higher under the CAI engine operation. In order to evaluate the potential of the CAI combustion technology, the European NEDC driving cycle vehicle simulation was carried out for two identical vehicles powered by a SI engine and a CAI/SI hybrid engine, respectively.

Impending legislation will make it almost inevitable that heavy-duty trucks will have to be fitted with some form of particulate removal after-treatment device. The challenge is to provide a system that is not only environmentally acceptable and cost effective but also durable enough to meet the demands of the trucking industry. Diesel particulate filters (DPF), in conjunction with fuel borne catalysts to facilitate regeneration, are now a recognised technology for meeting future passenger car emissions limits. Retrofitting of such systems to older technology vehicles, where specific environmental concerns exist, has demonstrated the possibility of applying this technology to the heavy-duty vehicle sector. Most of these retrofit applications tend to be to vehicles with a relatively low duty cycle. Whereas this type of duty cycle poses the greatest challenge to the successful regeneration of the filters it is not necessarily the most arduous test of the durability of the system.

Forthcoming emissions legislation is driving the passenger car manufacturers towards the fitting of Diesel Particulate Filters (DPFs) as original equipment. In areas with a particular problem such as heavily congested city centres, retrospective legislation has also been introduced, for example in Hong Kong and Tokyo. Legislation mandating the retrofitting of DPFs obviously has an immediate effect on particulate emissions. Other authorities are thus investigating the efficacy of such measures. However with the increasing use of DPF technology concerns are now being raised over some currently unregulated emissions such as ultra fine particulate and NO2, although total particulate mass and oxides of nitrogen are regulated. To add to the data base for such issues a programme of work was run using London Black Cabs. Four cars were fitted with a DPF, an on-board dosing system to meter a fuel borne catalyst (FBC) into the fuel and a data logger to monitor the DPF performance.

Forthcoming emissions legislation is driving the passenger car manufacturers towards the fitting of Diesel Particulate Filters (DPFs) as original equipment. However such initiatives are not retrospective and due to the replacement rate of the vehicle fleet, there is a time lag before the full benefit of the new measures are fully realised. To overcome this drawback, in areas with a particular problem such as heavily congested city centres, retrospective legislation has been introduced, for example in Hong Kong and Tokyo. Legislation mandating the retrofitting of DPFs obviously has an immediate effect on particulate emissions. Other authorities are thus investigating the efficacy of such measures. To add to the data base for such assessments Octel is running a demonstration programme using London Black Cabs. Four cars have been fitted with a DPF, an on-board dosing system to meter a fuel borne catalyst (FBC) into the fuel and a data logger to monitor the DPF performance.

Growing concern over the health effects of airborne particles and a desire to reduce the associated cost has resulted in legislation, regulations and other measures, in the industrialised world to severely restrict particulate emissions from diesel-fuelled automotive transport. Developing countries are also introducing initiatives to try and reduce emissions, an example is the legislation in India to replace diesel engines with gas fuelled engines in some major conurbations. Such measures are expensive, both in terms of replacing the engines of the vehicles and of implementing the required infrastructure. There is still also debate over whether such measures reduce the number of ultra-fine particulates. A well-proven alternative is to fit diesel engines with Diesel Particulate Filters (DPFs), either as original equipment or as a retrofit system. Regenerating DPFs has in the past been an obstacle to their widespread application.

The effects of Air/Fuel (A/F) ratios and Exhaust Gas Re-Circulation (EGR) rates on Homogeneous Charge Compression Ignition (HCCI) combustion of n-heptane have been experimentally investigated. The experiments were carried out in a single-cylinder, 4-stroke and variable compression-ratio engine equipped with a port fuel injector. Investigations concentrate on the HCCI combustion of n-heptane at different A/F ratios, EGR rates and their effects on knock limit, engine load, combustion variability, and engine-out emissions such as NOx, CO, and unburned HC. Variations of auto-ignition timings and combustion durations in the two-stage combustion process are analyzed in detail. Results show that HCCI combustion with a diesel type fuel can be implemented at room temperature with a conventional diesel engine compression-ratio. However, its knock limit occurs at very high A/F ratios, although high EGR rates can be tolerated.

A diesel particulate filter (DPF) is a crucial weapon in the fight to control the downsides traditionally associated with diesel engined vehicles. The DPF not only produces the benefits required from an environmental standpoint but also has the consumer benefit of eliminating the visible black smoke associated with diesel engines. Thus DPFs have now become a reality, both for series production vehicles and as a retrofit application. Inevitably there are a number of alternative types of DPF and alternative techniques are used for ensuring they continue to function in an acceptable manner. Due to the complexity of the diesel combustion process and the emissions produced it is only to be expected that a device intended primarily to control one parameter would have some effect on other parameters. This paper looks at some different DPF technologies and how they effect emissions, with the emphasis on particulate emissions and the speciation of oxides of nitrogen.

A novel dosing system for fuel borne catalyst (FBC), used to assist regeneration with a diesel particulate filter (DPF), has been developed. The system was designed for on-board vehicle use to overcome problems encountered with batch dosing systems. Important design features were simplicity, to minimise system cost, and the use of in-line dosing rather than batch dosing linked to tank refuelling. The paper describes the development of the dosing system which continuously doses FBC into the fuel line feeding the engine injection pump. The theoretical considerations behind the concept are explored, together with the realities imposed by fuelling regimes in which a variable proportion of the fuel flowing through the injection pump is passed back to the fuel tank. Two types of system are considered, ie where 1) FBC is added to the fuel in direct proportion to the flow rate of fuel and 2) FBC is added at a constant time-based rate.

Future emissions limits are pushing vehicle manufacturers towards the fitting of Diesel Particulate Filters (DPFs) as original equipment. However due to the replacement rate of the vehicle fleet, there is a delay before the full benefit of these measures are fully realised. To overcome this problem, in areas with a particular problem such as heavily congested city centres, retrospective legislation has been, and may be introduced. Legislation mandating the retrofitting of DPFs obviously has an immediate effect on particulate emissions. In some countries including the UK there are also fiscal incentives to fit DPFs. Due to its duty cycle the London taxi or Black Cab is one of the more challenging areas of application for the DPF. Previous work has shown that the use of a fuel borne catalyst (FBC) can extend the operating range of DPF systems providing the possibility of a viable system for such applications.