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It is generally accepted that emissions of nitrogen oxides (NOx) increase as the volume fraction of bio diesel increases in blends with conventional diesel fuel. While many mechanisms based on bio diesel effects on in-cylinder processes have been proposed to explain this observation, a clear understanding of the relative importance of each has remained elusive. To gain further insight into the cause(s) of the bio diesel NOx increase, experiments were conducted in a single-cylinder version of a heavy-duty diesel engine with extensive optical access to the combustion chamber. The engine was operated using two bio diesel fuels and two hydrocarbon reference fuels, over a wide range of loads, and using undiluted air as well as air diluted with simulated exhaust gas recirculation.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

Reactivity Controlled Compression Ignition (RCCI) has been shown to be an attractive concept to achieve clean and high efficiency combustion. RCCI can be realized by applying two fuels with different reactivities, e.g., diesel and gasoline. This motivates the idea of using a single low reactivity fuel and direct injection (DI) of the same fuel blended with a small amount of cetane improver to achieve RCCI combustion. In the current study, numerical investigation was conducted to simulate RCCI and HCCI combustion and emissions with various fuels, including gasoline/diesel, iso-butanol/diesel and iso-butanol/iso-butanol+di-tert-butyl peroxide (DTBP) cetane improver. A reduced Primary Reference Fuel (PRF)-iso-butanol-DTBP mechanism was formulated and coupled with the KIVA computational fluid dynamic (CFD) code to predict the combustion and emissions of these fuels under different operating conditions in a heavy duty diesel engine.

Leaner lifted-flame combustion (LLFC) is a mixing-controlled combustion strategy for compression-ignition (CI) engines that does not produce soot because the equivalence ratio at the lift-off length is less than or equal to approximately two. In addition to completely preventing soot formation, LLFC can simultaneously control emissions of nitrogen oxides because it is tolerant to the use of exhaust-gas recirculation for lowering in-cylinder temperatures. Experiments were conducted in a heavy-duty CI engine that has been modified to provide optical access to the combustion chamber, to study whether LLFC is facilitated by an oxygenated fuel blend (T50) comprising a 1:1 mixture by volume of tri-propylene glycol mono-methyl ether with an ultra-low-sulfur #2 diesel emissions-certification fuel (CFA). Results from the T50 experiments are compared against baseline results using the CFA fuel without the oxygenate.

Experiments conducted with a set of reference diesel fuels in an optically accessible, compression-ignition engine have revealed a strong correlation between hydrocarbon (HC) emissions and the flame lift-off length at the end of the premixed burn (EOPMB), with increasing HC emissions associated with longer lift-off lengths. The correlation is largely independent of fuel properties and charge-gas O2 mole fraction, but varies with fuel-injection pressure. A transient, one-dimensional jet model was used to investigate three separate mechanisms that could explain the observed impact of lift-off length on HC emissions. Each mechanism relies on the formation of mixtures that are too lean to support combustion, or “overlean.” First, overlean regions can be formed after the start of fuel injection but before the end of the premixed burn.

The dual-fuel Reactivity Controlled Compression Ignition (RCCI) combustion could achieve high efficiency and low emissions over a wide range of operating conditions. However, further high load extension is limited by the excessive pressure rise rate and soot emission. Polyoxymethylene dimethyl ethers (PODE), a novel diesel alternative fuel, has the capability to achieve stoichiometric smoke-free RCCI combustion due to its high oxygen content and unique molecule structure. In this study, experimental investigations on high load extension of gasoline/PODE RCCI operation were conducted using late intake valve closing (LIVC) strategy and intake boosting in a single-cylinder, heavy-duty diesel engine. The experimental results show that the upper load can be effectively extended through boosting and LIVC with gasoline/PODE stoichiometric operation.

This work numerically investigates the detailed combustion kinetics of partially premixed combustion (PPC) in a diesel engine under three different premixed ratio fuel conditions. A reduced Primary Reference Fuel (PRF) chemical kinetics mechanism was coupled with CONVERGE-SAGE CFD model to predict PPC combustion under various operating conditions. The experimental results showed that the increase of premixed ratio (PR) fuel resulted in advanced combustion phasing. To provide insight into the effects of PR on ignition delay time and key reaction pathways, a post-process tool was used. The ignition delay time is related to the formation of hydroxyl (OH). Thus, the validated Converge CFD code with the PRF chemistry and the post-process tool was applied to investigate how PR change the formation of OH during the low-to high-temperature reaction transition. The reaction pathway analyses of the formations of OH before ignition time were investigated.

Low-temperature combustion of diesel fuel was studied in a heavy-duty, single-cylinder, optical engine employing a 15-hole, dual-row, narrow-included-angle nozzle (10 holes × 70° and 5 holes × 35°) with 103-μm-diameter orifices. This nozzle configuration provided the spray targeting necessary to contain the direct-injected diesel fuel within the piston bowl for injection timings as early as 70° before top dead center. Spray-visualization movies, acquired using a high-speed camera, show that impingement of liquid fuel on the piston surface can result when the in-cylinder temperature and density at the time of injection are sufficiently low. Seven single- and two-parameter sweeps around a 4.82-bar gross indicated mean effective pressure load point were performed to map the sensitivity of the combustion and emissions to variations in injection timing, injection pressure, equivalence ratio, simulated exhaust-gas recirculation, intake temperature, intake boost pressure, and load.

The in-cylinder extent of liquid-phase fuel penetration (i.e., the liquid length) is an important parameter in combustion-chamber design because liquid lengths that are too long can lead to wall impingement and corresponding degradation of engine efficiency, emissions, and durability. Previous liquid-length measurements in constant-volume combustion chambers have shown that the liquid length is nominally independent of injection pressure, but these measurements have employed common-rail fuel systems where injection rate is approximately constant during the entire injection event, and they have been conducted under quasi-steady ambient thermodynamic conditions. The objective of the current work is to better understand the effects of injection-rate shape and injection pressure on the liquid length, including possible effects of unsteady ambient conditions in an engine.

This study summarizes the peer-reviewed literature regarding the use of raw pyrolysis liquids (PLs) created from woody biomass as fuels for compression-ignition (CI) engines. First, a brief overview is presented of fast pyrolysis and the potential advantages of PLs as fuels for CI engines. Second, a discussion of the general composition and properties of PLs relative to conventional, petroleum-derived diesel fuels is provided, with emphasis on the differences that are most likely to affect PL performance in CI-engine applications. Next, a synopsis is given of the peer-reviewed literature describing experimental studies of CI engines operated using neat PLs and PLs combined in various ways with other fuels. This literature conclusively indicates that raw PLs and PL blends cannot be used as “drop-in replacements” for diesel fuel in CI engines, which is reflected in part by none of the cited studies reporting successful operation on PL fuels for more than twelve consecutive hours.

High-efficiency, clean-combustion strategies for heavy-duty diesel engines are critical for meeting stringent emissions regulations and reducing the costs of aftertreatment systems that are currently required to meet these regulations. Results from previous constant-volume combustion-vessel experiments using a single jet of fuel under quiescent conditions have shown that mixing-controlled soot-free combustion (i.e., combustion where soot is not produced) is possible with #2 diesel fuel. These experiments employed small injector-orifice diameters (≺ 150 μm) and high fuel-injection pressures (≻ 200 MPa) at top-dead-center (TDC) temperatures and densities that could be achievable in modern heavy-duty diesel engines.

Natural luminosity (NL) and chemiluminescence (CL) imaging diagnostics are employed to investigate fuel-property effects on mixing-controlled combustion, using select research fuels-a #2 ultra-low sulfur emissions-certification diesel fuel (CF) and four of the Fuels for Advanced Combustion Engines (FACE) diesel fuels (F1, F2, F6, and F8)-that varied in cetane number (CN), distillation characteristics, and aromatic content. The experiments were performed in a single-cylinder heavy-duty optical compression-ignition (CI) engine at two injection pressures, three dilution levels, and constant start-of-combustion timing. If the experimental results are analyzed only in the context of the FACE fuel design parameters, CN had the largest effect on emissions and efficiency.

A fully coupled multi-dimensional CFD and reduced chemical kinetics model is adopted to investigate the effects of charge stratification on HCCI combustion and emissions. Seven different kinds of imposed stratification have been introduced according to the position of the maximal local fuel/air equivalence ratio in the cylinder at intake valve close. The results show that: The charge stratification results in stratification of the in-cylinder temperature. The former four kinds of stratification, whose maximal local equivalence ratios at intake valve close locate between the cylinder center and half of the cylinder radius, advance ignition timing, reduce the pressure-rise rate, and retard combustion-phasing. But the following three kinds of stratification, whose maximal local equivalence ratios at intake valve close appear between half of the cylinder radius and the cylinder wall, have little effect on the cylinder pressure.

Engine combustion strategies that preserve high cycle efficiency while minimizing engine-out pollutant emissions are the focus of major research efforts around the world. Such high efficiency clean combustion (HECC) strategies typically employ compression ignition of a charge that exhibits an elevated degree of fuel/air premixing and/or dilution with combustion products. Prior studies have shown that a highly dilute, mixing-controlled combustion strategy using a high-cetane, oxygenated fuel can achieve HECC while avoiding the control, high-load knock, and light-load incomplete combustion difficulties that are often experienced with approaches that use a high degree of charge premixing. On the other hand, employing high dilution levels (e.g., by using large amounts of cooled exhaust gas recirculation, EGR) can place excessive burdens on engine heat exchangers and air-handling systems.

The effects of various injection timing of methanol on thermo-atmosphere combustion of methanol by port injection of dimethyl ether (DME) and direct injection of methanol were experimentally investigated. The experiment results show that, as injection timing is at 6 degree before TDC, the combustion process comprises three stages: low temperature heat release of DME, high temperature heat release of DME and diffusion combustion of methanol. As injection timing increases, premixed combustion proportion of methanol is increased and diffusion combustion proportion is decreased. As injection timing increases to 126 degree before TDC, diffusion combustion of methanol disappears. At this time, the combustion process shows typical two stages heat release of HCCI combustion. As injection timing increases, required DME rate is increased, combustion efficiency and indicated thermal efficiency all first increase and then decrease.

Combustion processes employing different injection strategies in a High-Speed Direct Inject (HSDI) diesel engine were investigated using a narrow angle injector (70 degree). Whole-cycle combustion was visualized using a high-speed digital video camera. The liquid spray evolution process was imaged by the Mie-scattering technique. Different injection strategies were employed in this study including early pre-Top Dead Center (TDC) injection, post-TDC injection, multiple injection strategies with an early pre-TDC injection and a late post-TDC injection. Smokeless combustion was obtained under some operating conditions. Compared with the original injection angle (150 degree), some new combustion phenomena were observed for certain injection strategies. For early pre-TDC injection strategies, liquid fuel impingement is observed that results in some newly observed fuel film combustion flame (pool fires) following an HCCI-like weak flame.

Computational fluid dynamic (CFD) simulations that include realistic combustion/emissions chemistry hold the promise of significantly shortening the development time for advanced high-efficiency, low-emission engines. However, significant challenges must be overcome to realize this potential. This paper discusses these challenges in the context of diesel combustion and outlines a technical program based on the use of surrogate fuels that sufficiently emulate the chemical complexity inherent in conventional diesel fuel.

Biodiesel fuel can be produced from a wide range of source materials that affect the properties of the fuel. The diesel engine has become a highly tuned power source that is sensitive to these properties. The objectives of this research were to measure and predict the key properties of biodiesel produced from a broad range of source materials to be used as inputs for combustion modeling; and second to compare the results of the model with and without the biodiesel fuel definition. Substantial differences in viscosity, surface tension, density and thermal conductivity were obtained relative to reference diesel fuels and among the different source materials. The combustion model revealed differences in the temperature and emissions of biodiesel when compared to reference diesel fuel.

An optically accessible single-cylinder high-speed direct-injection (HSDI) Diesel engine equipped with a Bosch common rail injection system was used to study the spray and combustion processes for European low sulfur diesel, bio-diesel, and their blends at different blending ratio. Influences of injection timing and fuel type on liquid fuel evolution and combustion characteristics were investigated under similar loads. The in-cylinder pressure was measured and the heat release rate was calculated. High-speed Mie-scattering technique was employed to visualize the liquid distribution and evolution. High-speed combustion video was also captured for all the studied cases using the same frame rate. NOx emissions were measured in the exhaust pipe. The experimental results indicated that for all of the conditions the heat release rate was dominated by a premixed combustion pattern and the heat release rate peak became smaller with injection timing retardation for all test fuels.

Biodiesel fuels and their blends with diesel are often used to reduce emissions from diesel engines. However, biodiesel has been shown to increase the NOx emissions. Operating a compression ignition engine in low-temperature combustion mode as well as using multiple injections can reduce NOx emissions. Experimental data for biodiesel are compared to those for diesel to show the effect of the biodiesel on the peak pressure, temperature, and emissions. Accurate prediction of biodiesel properties, combined with the KIVA 3V code, is used to investigate the combustion of biodiesel. The volume fraction of the cylinder that has temperatures greater than 2200 K is shown to directly affect the production of oxides of nitrogen. Biodiesel is shown to burn faster during the combustion events, though the ignition delay is often longer for biodiesel compared to diesel.