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For controlling oxides of nitrogen (NOx) and particular matter (PM) emissions from diesel engines, various fuel and combustion mode modification strategies are investigated in the past. Low temperature combustion (LTC) is an alternative combustion strategy that reduces NOx and PM emissions through premixed lean combustion. Dual fuel reactivity-controlled compression ignition (RCCI) is a promising LTC strategy with better control over the start and end of combustion because of reactivity and equivalence ratio stratification. However, the unburned hydrocarbon (HC) and carbon monoxide (CO) emissions are significantly higher in RCCI, especially at part-load conditions. The present work intends to address this shortcoming by utilizing oxygenated alternative fuels. Considering the limited availability and higher cost, replacing conventional fuels completely with alternative fuels is not feasible.

The presence of unsaturated methyl esters in biodiesel makes it susceptible to oxidation and fuel quality degradation upon long-term storage. In the present work, the effects of oxidation of Karanja biodiesel upon long-term storage on the combustion and emission characteristics of a heavy-duty truck diesel engine are studied. The Karanja biodiesel is stored for one year in a 200 litres steel barrel at room conditions to mimic commercial storage conditions. The results obtained show that compared to diesel, the start of injection of fresh and aged biodiesels are advanced by ~2-degree crank angle, and the ignition delay time is reduced. Aged biodiesel showed a slightly smaller ignition delay compares to fresh biodiesel. The fuel injection and combustion characteristics of fresh and aged biodiesels were similar at all the load conditions. Both fresh and aged biodiesels produced higher oxides of nitrogen (NOx) and lower smoke emissions compared to diesel.

In-cylinder emission control methods for simultaneous reduction of oxides of nitrogen (NOx) and particulate matter (PM) are gaining attention due to stringent emission targets and the higher cost of after-treatment systems. In addition, there is a renewed interest in using carbon-neutral biodiesel due to global warming concerns with fossil diesel. The bi-directional NOx-PM trade-off is reduced to a unidirectional higher NOx emission problem with biodiesel. The effect of water injection with biodiesel with low water quantities is relatively unexplored and is attempted in this investigation to mitigate higher NOx emissions. The water concentrations are maintained at 3, 6, and 9% relative to fuel mass by varying the pulse width of a low-pressure port fuel injector. Considering the corrosive effects of water at higher concentrations, they are maintained below 10% in the present work.

The research on reducing emissions from automotive engines through modifications in the combustion mode and the fuel type is gaining momentum because of the increasing contribution to global warming by the transportation sector. The combustion and emission formation in the advanced low temperature combustion (LTC) engine strategies are susceptible to fuel molecular composition and properties. Ignition timing in LTC strategies is primarily controlled by fuel composition and associated chemical kinetics. Thus, tailoring of fuel properties is required to address the limitations of LTC in terms of lack of control on ignition timing and narrow engine operating load range. Utilizing fuel blends and additives such as nanoparticles is a promising approach to achieving targeted fuel property. An improved understanding of fundamental processes, including fuel evaporation, is required due to its role in fuel-air mixing and emission formation in LTC.

The upcoming Bharat Stage VI (BS VI) emission legislation has put enormous pressure on the future of small diesel engines which are widely used in the Indian market. The present work investigates the emission reduction potential of a common rail direct injection single cylinder diesel engine by adopting a holistic approach of lowering the compression ratio, boosting the intake air and down-speeding the engine. Experimental investigations were conducted across the entire operating map of a mass-production, light-duty diesel engine to examine the benefits of the proposed approach and the results are quantified for the modified Indian drive cycle (MIDC). By reducing the compression ratio from 18:1 to 14:1, the oxides of nitrogen (NOx) and soot emissions are reduced by 40% and 75% respectively. However, a significant penalty in fuel economy, unburned hydrocarbon (HC) and carbon monoxide (CO) emissions are observed with the reduced compression ratio.

Extensive experimental investigations done over a decade in different engine types demonstrated the capability of achieving high efficiency along with low levels of oxides of nitrogen (NOx) and soot emissions with low temperature combustion (LTC) modes. However, the commercial application of LTC strategies requires several challenges to be addressed, including precise ignition timing control, reducing higher unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions. The lower exhaust gas temperatures with LTC operation pose severe challenges for after-treatment control systems. Among the available LTC strategies, Reactivity Controlled Compression Ignition (RCCI) has emerged as the most promising strategy due to better ignition timing control with higher thermal efficiency. Nevertheless, the complexity of engine system hardware due to the dual fuel injection system and associated controls, high HC and CO emissions are the major limiting factors in RCCI.

Adopting a low compression ratio (LCR) is a viable approach to meet the stringent emission regulations since it can simultaneously reduce the oxides of nitrogen (NOx) and particulate matter (PM) emissions. However, significant shortcomings with the LCR approach include higher unburned hydrocarbon (HC) and carbon monoxide (CO) emissions and fuel economy penalties. Further, poor combustion stability of LCR engines at cold ambient and part load conditions may worsen the transient emission characteristics, which are least explored in the literature. In the present work, the effects of implementing the low compression ratio (LCR) approach in a mass-production light-duty vehicle powered by a single-cylinder diesel engine are investigated with a major focus on transient emission characteristics.

Premixed charged compression ignition (PCCI) is a promising low temperature combustion strategy for achieving a simultaneous reduction of oxides of nitrogen (NOx) and soot emissions in diesel engines. However, early direct injection results in a significant penalty in fuel economy, high unburned hydrocarbon (HC), and carbon monoxide (CO) emissions, especially in small-bore diesel engines. In the present work, computational fluid dynamic (CFD) investigations are carried out in a small-bore diesel engine using a commercial CFD software, CONVERGE. The computational models are validated with experimental results at two different load conditions, 20% and 40% of rated load. The validated models are used to carry out parametric investigations on the effects of fuel injection parameters, namely the start of fuel injection timing, injection pressure, and spray cone angle on PCCI combustion.

The ignition quality of a fuel is described by its cetane number. Experimental methods used to determine cetane number employ Co-operative fuel research (CFR) engine and Ignition quality tester (IQT) which are expensive, have less repeatability and require skilled operation, and hence least preferred. There are many prediction models reported, which involve number of double bonds and number of carbon atoms whose determination is not direct. Using models that relate biodiesel composition to its cetane number is limited by the range of esters involved. Hence, a model to predict cetane number of biodiesels that addresses the limitations of the existing models, without ignoring the influence of factors such as degree of unsaturation and number of carbon atoms, is needed. Fourier transform infrared spectroscopy (FTIR) could be one such method.

To comply with the stringent future emission mandates of light-duty diesel engines, it is essential to deploy a suitable combination of emission control devices like diesel oxidation catalyst (DOC), diesel particulate filter (DPF) and DeNOx converter (LNT or SCR). Arriving at optimum size and layout of these emission control devices for a particular engine through experiments is both time and cost-intensive. Thus, it becomes important to develop suitable well-tuned simulation models that can be helpful to optimize individual emission control devices as well as arrive at an optimal layout for achieving higher conversion efficiency at a minimal cost. Towards this objective, the present work intends to develop a one-dimensional Exhaust After Treatment Devices (EATD) model using a commercial code. The model parameters are fine-tuned based on experimental data. The EATD model is then validated with experiment data that are not used for tuning the model.

Premixed Charge Compression Ignition (PCCI) is a promising LTC strategy to reduce NOx and soot emissions without relying on after-treatment devices. One major drawback of PCCI is high HC and CO emissions resulting from fuel-wall impingement due to early injection of diesel. Narrow-angle direct injection (NADI) helps reduce the wall wetting of fuel. But it is effective only at lower loads. At mid and higher loads, it increases soot and CO emissions in small-bore engines due to the formation of fuel-rich pockets in the piston bowl region. This problem is addressed using a split injection strategy in the present work. A 3-D CFD model is developed and validated with experimental data at two load conditions. Simulations are performed using CONVERGE CFD software. Split injection strategies are explored using wide (148 deg) and narrow (88 deg) spray included angles.

Supercharging a single-cylinder diesel engine has proved to be a viable methodology to reduce engine-out emissions and increase full-load torque and power. The increased air availability of the supercharger (SC) system helps to inject more fuel quantity that can improve the engine's full-load brake mean effective pressure (BMEP) without elevating soot emissions. However, the increased inlet temperature of the boosted air and the availability of excess oxygen can pose significant challenges to contain oxides of nitrogen (NOx) emissions. Hence, it is important to investigate the potential NOx reduction options in supercharged diesel engines. In the present work, the potential of low-pressure exhaust gas recirculation (LP EGR) was evaluated in a single-cylinder supercharged diesel engine for its benefits in NOx emission reduction and impact on other criteria emissions and brake specific fuel consumption (BSFC).

It is well established that reducing the compression ratio (CR) of a diesel engine leads to a significant increase in hydrocarbon (HC) and carbon monoxide (CO) emissions, especially in cold and transient conditions. Hence, it is essential to find new strategies to reduce the HC and CO emissions of a low compression ratio (LCR) diesel engine in transient conditions. In the present work, a detailed evaluation of different warm-up technologies was conducted for their effects on transient emissions characteristics of a single-cylinder naturally aspirated LCR diesel engine. For this purpose, the engine was coupled to an instrumented transient engine dynamometer setup. A transient cycle of 160 seconds with starting, idling, speed ramp-up and load ramp-up was defined, and the engine was run in automatic mode by the dynamometer. The experiments were conducted by overnight soaking the engine at a specified temperature of 25 deg.C.

Mass-production single-cylinder engines are generally not turbocharged due to pulsated exhaust flow. Hence, about one-third of the fuel chemical energy is wasted in the engine exhaust. To extract the exhaust energy and boost the single-cylinder engines, a novel supercharging with a turbo-compounding strategy is proposed in the present work, wherein an impulse turbine extracts energy from the pulsated exhaust gas flow. Employing an impulse turbine for a vehicular application, especially on a single-cylinder engine, has never been commercially attempted. Hence, the design of the impulse turbine assumes higher importance. A nozzle, designed as a stator part of the impulse turbine and placed at the exhaust port to accelerate the flow velocity, was included as part of the layout in the present work. The layout was analyzed using the commercial software AVL BOOST. Different nozzle exit diameters were considered to analyze their effect on the exhaust back pressure and engine performance.

Single-cylinder engines in mass production are generally not turbocharged due to the pulsated and intermittent exhaust gas flow into the turbocharger and the phase lag between the intake and exhaust stroke. The present work proposes a novel approach of decoupling the turbine and the compressor and coupling them separately to the engine to address these limitations. An impulse turbine is chosen for this application to extract energy during the pulsated exhaust flow. Commercially available AVL BOOST software was used to estimate the overall engine performance improvement of the proposed novel approach compared to the base naturally aspirated (NA) engine. Two different impulse turbine layouts were analyzed, one without an exhaust plenum and the second layout having an exhaust plenum before the power turbine. The merits and limitations of both layouts are compared in the present study.

Unsaturated methyl esters in biodiesel make it susceptible to oxidation and fuel quality degradation upon long-term storage. It is almost impossible to use biodiesel for commercial applications immediately after production. The lead time between biodiesel production and usage is generally high, causing auto-oxidation and fuel quality degradation. Hence any onsite improvement in fuel quality should be tested with aged biodiesel. To avoid the food versus fuel debate, non-edible oil feedstocks are preferable for producing biodiesel. However, biodiesel from non-edible oil sources has more unsaturated methyl ester constituents. The traditional trade-off between oxides of nitrogen (NOx) and soot emissions in conventional diesel combustion is reduced to a more severe NOx problem with biodiesel. In the present study, NOx mitigation through fuel modifications is studied for oxidized biodiesel produced from a non-edible oil, Karanja.

Emulsification of biodiesel with water aids in reducing oxides of nitrogen (NOx) and smoke emissions simultaneously whilst improving the engine performance. However, widespread commercial applications of biodiesel-water emulsions require cost-effective surfactants that result in stable emulsions to avoid the corrosive effects of water at high temperatures prevailing in the engine combustion systems. The current investigation explored the effect of adding water to biodiesel at 6 and 12% by weight. A novel, cost-effective surfactant Polyglycerol Polyricinoleate (PGPR), was used to stabilize the emulsions. A magnetic stirrer with a heating facility was utilized to prepare biodiesel-water emulsions that were stable for over five months. The experiments were carried out on a light-duty diesel engine at a constant rated speed and varying load conditions. The results obtained with the emulsions were compared with neat biodiesel as the reference fuel.

Currently, alternative fuels produced from waste resources are gaining much attention to replace depleting fossil fuels. The disposal of waste plastic poses severe environmental problems across the globe. The energy embodied in waste plastics can be converted into liquid fuel by pyrolysis. The present work explores the possibility of utilizing waste plastic oil (WPO) produced from municipal plastic wastes and waste cooking oil (WCO) biodiesel produced from used cooking oil in a dual fuel reactivity-controlled compression ignition (RCCI) mode. A single-cylinder light-duty diesel engine used for agricultural water pumping applications is modified to run in RCCI through suitable intake and fuel injection systems modifications. Alternative fuel blends, viz. WPO and WCO biodiesel with 20 vol. % in gasoline and diesel is used as a port and direct-injected fuels in RCCI. The premixed ratio and direct-injected fuel timings are optimized to achieve maximum thermal efficiency.

Over the years, much progress has been made in automotive vehicle technology to achieve high efficiency and clean combustion. Reactivity controlled compression ignition (RCCI) is one of the most widely studied high-efficiency, clean combustion strategies. However, complex dual-fuel injection systems and associated controls, high unburned hydrocarbon (UHC), and carbon monoxide (CO) emissions limit RCCI use in practical applications. Recently, single fuel RCCI strategies are gaining more attention as the above shortcomings are effectively addressed. Homogeneous charge with direct injection (HCDI) is a single fuel RCCI strategy that results in high thermal efficiency and lower UHC and CO emissions. In HCDI, the port-injected diesel fuel vapour and air are inducted during the intake stroke and ignited with direct-injected diesel fuel near the end of the compression stroke. However, high oxides of nitrogen (NOx) make HCDI less viable for practical applications.

Despite the advantages of turbocharging in improved engine performance and reduced exhaust emissions, commercial single-cylinder engines used for automotive applications remain naturally aspirated (NA) and are not generally turbocharged. This is due to the shortcomings with pulsated and intermittent exhaust gas flow into the turbine and the phase lag between the intake and exhaust stroke. In the present study, experimental investigations are initially carried out with a suitable turbocharger closely coupled to a single-cylinder diesel engine. Results indicated that the engine power dropped significantly by 40% for the turbocharged engine compared to the NA version even though the air mass flow rate was increased by at least 1.5 times with turbocharging. A novel approach of decoupling the turbine and the compressor and coupling them separately to the engine is proposed to address these limitations.