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This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

A recently completed program was developed to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different truck and bus fleets operating in Southern California. The primary test fuels, ECD and ECD-1, are produced by ARCO, a BP company, and have less than 15 ppm sulfur content. A test fleet comprised of heavy-duty trucks and buses were retrofitted with one of two types of catalyzed diesel particle filters, and operated for one year. As part of this program, a chemical characterization study was performed in the spring of 2001 to compare the exhaust emissions using the test fuels with and without aftertreatment. A detailed speciation of volatile organic hydrocarbons (VOC), polycyclic aromatic hydrocarbons (PAH), nitro-PAH, carbonyls, polychlorodibenzo-p-dioxins (PCDD) and polychlorodibenzo-p-furans (PCDF), inorganic ions, elements, PM10, and PM2.5 in diesel exhaust was performed for a select set of vehicles.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Optimized 1997 model year Caterpillar C10 dual-fuel natural gas engines certified to the California Air Resources Board's Alternative Low NOx 2.5 gram/brake horsepower-hour emission standard were demonstrated in three commuter buses over a 12-month period, in Santa Barbara, California. The project evaluated the retrofit costs and process, performance, reliability, fuel economy, operating costs, and emissions of the three C-10 dual-fuel natural gas engines compared to a standard C-10 diesel engine. Chassis dynamometer tests using the U.S. EPA Urban Dynamometer Drive Schedule, the Central Business District (West Virginia University version) and the 55-mph Steady State cycles were conducted to characterize in-use emissions of the dual-fuel engines for the commuter bus application. During 94,000 combined service miles, performance, reliability and durability of the dual fuel buses were similar to the diesel control.

Emissions from trucks and buses equipped with Caterpillar dual-fuel natural gas (DFNG) engines were measured at two chassis dynamometer facilities: the West Virginia University (WVU) Transportable Emissions Laboratory and the Los Angeles Metropolitan Transportation Authority (LA MTA). Emissions were measured over four different driving cycles. The average emissions from the trucks and buses using DFNG engines operating in dual-fuel mode showed the same trends in all tests - reduced oxides of nitrogen (NOx) and particulate matter (PM) emissions and increased hydrocarbon and carbon monoxide (CO) emissions - when compared to similar diesel trucks and buses. The extent of NOx reduction was dependent on the type of test cycle used.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.