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Journal Article

Diesel Exhaust Aftertreatment with Scrubber Process: NOx Destruction

2012-05-15
2011-01-2440
Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.
Technical Paper

Alternative Fuel Truck Evaluation Project - Design and Preliminary Results

1998-05-04
981392
The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. This paper summarizes the design of the project and early results from the first two sites. Data collection is planned for operations, maintenance, truck system descriptions, emissions, duty cycle, safety incidents, and capital costs and operating costs associated with the use of alternative fuels in trucking.
Technical Paper

Parametric Study of 2007 Standard Heavy-Duty Diesel Engine Particulate Matter Sampling System

2007-01-23
2007-01-0060
Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.
Technical Paper

Neural Network Modeling of Emissions from Medium-Duty Vehicles Operating on Fisher-Tropsch Synthetic Fuel

2007-04-16
2007-01-1080
West Virginia University has conducted research to characterize the emissions from medium-duty vehicles operating on Fischer-Tropsch synthetic gas-to-liquid compression ignition fuel. The West Virginia University Transportable Heavy Vehicle Emissions Testing Laboratory was used to collect data for gaseous emissions (carbon dioxide, carbon monoxide, oxides of nitrogen, and total hydrocarbon) while the vehicles were exercised through a representative driving schedule, the New York City Bus Cycle (NYCB). Artificial neural networks were used to model emissions to enhance the capabilities of computer-based vehicle operation simulators. This modeling process is presented in this paper. Vehicle velocity, acceleration, torque at rear axel, and exhaust temperature were used as inputs to the neural networks. For each of the four gaseous emissions considered, one set of training data and one set of validating data were used, both based on the New York City Bus Cycle.
Technical Paper

Heat Release and Emission Characteristics of B20 Biodiesel Fuels During Steady State and Transient Operation

2008-04-14
2008-01-1377
Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.
Technical Paper

Emission Reductions and Operational Experiences With Heavy Duty Diesel Fleet Vehicles Retrofitted with Continuously Regenerated Diesel Particulate Filters in Southern California

2001-03-05
2001-01-0512
Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.
Technical Paper

Measurement of Brake-specific NOX Emissions using Zirconia Sensors for In-use, On-board Heavy-duty Vehicle Applications

2002-05-06
2002-01-1755
Emissions tests for heavy -duty diesel-fueled engines and vehicles are normally performed using engine dynamometers and chassis dynamometers, respectively, with laboratory grade gaseous concentration measurement analyzers and supporting test equipment. However, a considerable effort has been recently expended on developing in-use, on-board tools to measure brake-specific emissions from heavy -duty vehicles with the highest degree of accuracy and precision. This alternative testing methodology would supplement the emissions data that is collected from engine and chassis dynamometer tests. The on-board emissions testing methodology entails actively recording emissions and vehicle operating parameters (engine speed and load, vehicle speed etc.) from vehicles while they are operating on the road. This paper focuses on in-use measurements of NOX with zirconium oxide sensors and other portable NOX detectors.
Technical Paper

Emissions Modeling of Heavy-Duty Conventional and Hybrid Electric Vehicles

2001-09-24
2001-01-3675
Today's computer-based vehicle operation simulators use engine speed, engine torque, and lookup tables to predict emissions during a driving simulation [1]. This approach is used primarily for light and medium-duty vehicles, with large discrepancies inherently due to the lack of transient engine emissions data and inaccurate emissions prediction methods [2]. West Virginia University (WVU) has developed an artificial neural network (ANN) based emissions model for incorporation into the ADvanced VehIcle SimulatOR (ADVISOR) software package developed by the National Renewable Energy Laboratory (NREL). Transient engine dynamometer tests were conducted to obtain training data for the ANN. The ANN was trained to predict carbon dioxide (CO2) and oxides of nitrogen (NOx) emissions based on engine speed, torque, and their representative first and second derivatives over various time ranges.
Technical Paper

Measurement of In-Use, On-Board Emissions from Heavy-Duty Diesel Vehicles:Mobile Emissions Measurement System

2001-09-24
2001-01-3643
Emissions tests for heavy-duty diesel-fueled vehicles are normally performed using an engine dynamometer or a chassis dynamometer. Both of these methods generally entail the use of laboratory-grade emissions measurement instrumentation, a CVS system, an environment control system, a dynamometer, and associated data acquisition and control systems. The results obtained from such tests provide a means by which engines may be compared to the emissions standards, but may not be truly indicative of an engine's in-vehicle performance while operating on the road. An alternative to such a testing methodology would be to actively record the emissions from a vehicle while it was operating on-road. A considerable amount of discussion has been focused on the development of on-road emissions measurement systems (OREMS) that would provide for such in-use emissions data collection.
Technical Paper

Research Approach for Aging and Evaluating Diesel Lean-NOx Catalysts

2001-09-24
2001-01-3620
The goal of the Diesel Emissions Control-Sulfur Effects (DECSE) program was to determine the impact of diesel fuel sulfur levels on emissions control devices that could lower emissions of oxides of nitrogen (NOX) and particulate matter (PM) from on-highway trucks and buses. West Virginia University (WVU) performed evaluations of lean-NOx catalysts to determine the effects of fuel sulfur content on emissions reduction efficiency and catalyst durability in the first 250 hours of operation. A Cummins ISM370 engine (10.8 liter, 370 horsepower), typical of heavy -duty truck applications, was utilized to evaluate high-temperature lean-NOX catalyst while a Navistar T444E (7.3 liter, 210 horsepower), typical of medium-duty applications, was used to evaluate low-temperature catalyst. Catalysts were evaluated periodically during the first 250 hours of exposure to exhaust from engines operated on 3ppm, 30ppm, 150ppm and 350ppm sulfur content diesel fuel.
Technical Paper

Year-Long Evaluation of Trucks and Buses Equipped with Passive Diesel Particulate Filters

2002-03-04
2002-01-0433
A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Development of a Vehicle Road Load Model for ECU Broadcast Power Verification in On-Road Emissions Testing

2006-10-16
2006-01-3392
The 1998 Consent Decrees between the United States Government and the settling heavy-duty diesel engine manufacturers require in-use emissions testing from post 2000 model year engines. The emissions gathered from these engines must be reported on a brake-specific mass basis. To report brake-specific mass emissions, three primary parameters must be measured. These are the concentration of each emission constituent, the exhaust mass flow rate, and the engine power output. The measurement of the concentration level and exhaust mass flow rate can be (and are generally) measured directly with instrumentation installed in the exhaust transfer tube. However, engine power cannot be measured directly for in-use emissions testing due to the direct coupling of the engine output shaft to the vehicle's transmission. Engine power can be inferred from the electronic control unit (ECU) broadcast of engine speed and engine torque.
Technical Paper

Influences of Real-World Conditions on In-Use Emission from Heavy-Duty Diesel Engines

2006-10-16
2006-01-3393
The 1998 Consent Decrees between the settling heavy-duty diesel engine manufacturers and the United States Government require the engine manufacturer to perform in-use emissions testing to evaluate their engine designs and emissions when the vehicle is placed into service. This additional requirement will oblige the manufacturer to account for real-world conditions when designing engines and engine control algorithms and include driving conditions, ambient conditions, and fuel properties in addition to the engine certification test procedures. Engine operation and ambient conditions can be designed into the engine control algorithm. However, there will most likely be no on-board determination of fuel properties or composition in the near future. Therefore, the engine manufacturer will need to account for varying fuel properties when developing the engine control algorithm for when in-use testing is performed.
Technical Paper

Emissions Comparisons of Twenty-Six Heavy-Duty Vehicles Operated on Conventional and Alternative Fuels

1993-11-01
932952
Gaseous and particulate emissions from heavy-duty vehicles are affected by fuel types, vehicle/engine parameters, driving characteristics, and environmental conditions. Transient chassis tests were conducted on twenty-six heavy-duty vehicles fueled with methanol, compressed natural gas (CNG), #1 diesel, and #2 diesel, using West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory. The vehicles were operated on the central business district (CBD) testing cycle, and regulated emissions of carbon monoxide (CO), total hydrocarbon (HC), nitrogen oxides (NOx), and particulate matter (PM) were measured. Comparisons of regulated emissions results revealed that the vehicles powered on methanol and CNG produced much lower particulate emissions than the conventionally fueled vehicles.
Technical Paper

A Study of Emissions from CNG and Diesel Fueled Heavy-Duty Vehicles

1993-10-01
932826
The West Virginia University (WVU) Transportable Heavy-Duty Vehicle Emissions Testing Laboratory was employed to conduct chassis dynamometer tests in the field to measure the exhaust emissions from heavy-duty buses and trucks. This laboratory began operation in the field in January, 1992. During the period January, 1992 through June, 1993, over 150 city buses, trucks, and tractors operated by 18 different authorities in 11 states were tested by the facility. The tested vehicles were powered by 14 different types of engines fueled with natural gas (CNG or LNG), methanol, ethanol, liquified petroleum gas (LPG), #2 diesel, and low sulfur diesel (#1 diesel or Jet A). Some of the tested vehicles were equipped with exhaust after-treatment systems. In this paper, a total of 12 CNG-fueled and #2 diesel-fueled transit buses equipped with Cummins L-10 engines, were chosen for investigation.
Technical Paper

Sampling Strategies for Characterization of the Reactive Components of Heavy Duty Diesel Exhaust Emissions

1994-11-01
942262
Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.
Technical Paper

Final Operability and Chassis Emissions Results from a Fleet of Class 6 Trucks Operating on Gas-to-Liquid Fuel and Catalyzed Diesel Particle Filters

2005-10-24
2005-01-3769
Six 2001 International Class 6 trucks participated in a project to determine the impact of gas-to-liquid (GTL) fuel and catalyzed diesel particle filters (DPFs) on emissions and operations from December 2003 through August 2004. The vehicles operated in Southern California and were nominally identical. Three vehicles operated “as-is” on California Air Resources Board (CARB) specification diesel fuel and no emission control devices. Three vehicles were retrofit with Johnson Matthey CCRT® (Catalyzed Continuously Regenerating Technology) filters and fueled with Shell GTL Fuel. Two rounds of emissions tests were conducted on a chassis dynamometer over the City Suburban Heavy Vehicle Route (CSHVR) and the New York City Bus (NYCB) cycle. The CARB-fueled vehicles served as the baseline, while the GTL-fueled vehicles were tested with and without the CCRT filters. Results from the first round of testing have been reported previously (see 2004-01-2959).
Technical Paper

In-Cylinder Combustion Pressure Characteristics of Fischer-Tropsch and Conventional Diesel Fuels in a Heavy Duty CI Engine

1999-05-03
1999-01-1472
The emissions reduction benefits of Fischer-Tropsch (FT) diesel fuel have been shown in several recent published studies in both engine testing and in-use vehicle testing. FT diesel fuel shows significant advantages in reducing regulated engine emissions over conventional diesel fuel primarily to: its zero sulfur specification, implying reduced particulate matter (PM) emissions, its relatively lower aromaticity, and its relatively high cetane rating. However, the actual effect of FT diesel formulation on the in-cylinder combustion characteristics of unmodified modern heavy-duty diesel engines is not well documented. As a result, a Navistar T444E (V8, 7.3 liter) engine, instrumented for in-cylinder pressure measurement, was installed on an engine dynamometer and subjected to steady-state emissions measurement using both conventional Federal low sulfur pump diesel and a natural gas-derived FT fuel.
Technical Paper

On-Road Use of Fischer-Tropsch Diesel Blends

1999-04-27
1999-01-2251
Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.
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