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A comprehensive methodology for predicting the transient thermal response of spark-ignition engines subject to time-varying boundary conditions is presented. The approach is based on coupling a cycle-resolved quasi-dimensional simulation of in-cylinder thermodynamic events with a resistor-capacitor (R-C) thermal network of the various component and fluid interactions throughout the engine and exhaust system. The dynamic time step of the thermal solution is limited by either the frequency of the prescribed time-dependent boundary conditions or by the minimum thermal time constant of the R-C network. To demonstrate the need for fully-coupled, transient thermodynamic and heat transfer solutions, model behavior is first explored for step-change and staircase variations of engine operating conditions.

Conventional spark plugs ignite a fuel-air mixture via an electric-to-plasma energy transfer; the effectiveness of which can be described by an electric-to-plasma energy efficiency. Although conventional spark plug electric-to-plasma efficiencies have historically been viewed as adequate, it might be wondered how an increase in such an efficiency might translate (if at all) to improvements in the flame initiation period and eventual engine performance of a spark-ignition engine. A modification can be made to the spark plug that places a peaking capacitor in the path of the electrical current; upon coil energizing, the stored energy in the peaking capacitor substantially increases the energy delivered by the spark. A previous study has observed an improvement in the electric-to-plasma energy efficiency to around 50%, whereas the same study observed conventional spark plug electric-to-plasma energy efficiency to remain around 1%.

In the wake of global focus shifting towards the health and conservation of the planet, greater importance is placed upon the hazardous emissions of our fossil fuels, as well as their finite supply. These two areas remain intense topics of research in order to reduce greenhouse gas emissions and increase the fuel efficiency of vehicles, a sector which is a major contributor to society's global CO₂ emissions and consumer of fossil-fuel resources. A particular solution to this problem is the diesel engine, with its inherently fuel-lean combustion, which gives rise to low CO₂ production and higher efficiencies than other potential powertrain solutions. Diesel engines, however, typically exhibit higher nitrogen oxides (NOx) and soot engine-out emissions than their gasoline counterparts. NOx is an ingredient to ground-level ozone production and smoke is a possible carcinogen, both of which are facing stricter emissions regulations.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.