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The low temperature conditions that occur during high efficiency clean combustion (HECC) often lead to the formation of partially oxidized HC species such as aldehydes, ketones and carboxylic acids. Using the diesel fuels specified by the Fuels for Advanced Combustion Engines (FACE) working group, carbonyl species were collected from the exhaust of a light duty diesel engine operating under HECC conditions. High pressure liquid chromatography - mass spectrometry (LC-MS) was used to speciate carbonyls as large as C 9 . A relationship between carbonyl species formed in the exhaust and fuel composition and properties was determined. Data were collected at the optimum fuel efficiency point for a typical road load condition. Results of the carbonyl analysis showed changes in formaldehyde and acetaldehyde formation, formation of higher molecular weight carbonyls and the formation of aromatic carbonyls.

Transit buses contribute a meager amount to the U.S. criteria pollutant and greenhouse gas (GHG) inventory, but they attract a lot of attention from the public and from local government, due to their nature of operation. Transit bus fleets are often employed for the introduction of advanced heavy-duty vehicle technology and the formulation of new performance models. Emissions and fuel consumption data, gained using a chassis dynamometer, are often used to evaluate performance of these buses. However, the effect of road grade on fuel consumption and emissions most often is not accounted for in chassis dynamometer characterization. Grade effect on transit buses' fuel consumption was investigated using the road-load equation. It was observed that two parameters, including the type of terrain that buses traverse and the percentage of grade for that terrain, needed to be determined for this investigation.

Conventional crank-based engines are limited by mechanical, thermal, and combustion inefficiencies. The free piston of a linear engine generator reduces frictional losses by avoiding the rotational motion and crankshaft linkages. Instead, electrical power is generated by the oscillation of a translator through a linear stator. Because the free piston is not geometrically constrained, dead center positions are not specifically known. This results in a struggle against adverse events like misfire, stall, over-fueling, or rapid load changes. It is the belief that incorporating springs will have the dual benefit of increasing frequency and providing a restoring force to aid in greater cycle to cycle stability. For dual free piston linear engines the addition of springs has not been fully explored, despite growing interest and literature.

Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEPg) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEPg). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations.

The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this study, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

In 2007, US EPA implemented the rule that the crankcase emissions be added to the tailpipe emissions to determine the total emissions from a diesel engine if the crankcase were not closed, but few data exist to quantify crankcase emissions from earlier model diesel engines. This paper presents the results of a study on the measurement of the size distribution and number concentration of particulate matter (PM) emitted from the crankcase vents from four different diesel engines under different engine speeds and loads. The engines used in the study were a 1992 Detroit Diesel Series 60, a 1996 Caterpillar 3406E, a 1997 Cummins B5.9 and a 1995 Mack E7-400. The Detroit Diesel engine was tested on an engine dynamometer and crankcase and tailpipe particulates were observed at varying engine speeds and loads. The other three engines were mounted in vehicles, and crankcase PM was observed at several engine speeds with no external load.

Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

The key to overcoming Low Temperature Combustion (LTC) load range limitations is based on suitable control over the thermo-chemical properties of the in-cylinder charge. The proposed alternative to achieve the required control of LTC is the use of two separate fuel streams to regulate timing and heat release at specific operational points, where the secondary fuel, with different autoignition characteristics, is a reformed product of the primary fuel in the tank. It is proposed in this paper that the secondary fuel is produced using Thermo-Chemical Recuperation (TCR) with steam/fuel reforming. The steam/fuel mixture is heated by sensible heat from the engine exhaust gases in the recuperative reformer, where the original hydrocarbon reacts with water to form a hydrogen rich gas mixture. An equilibrium model developed by Gas Technology Institute (GTI) for n-heptane steam reforming was applied to estimate reformed fuel composition at different reforming temperatures.

One challenge in meeting emission regulations with catalytic aftertreatment systems is maintaining the proper catalyst temperatures that enable the catalytic devices to perform the emissions reduction. In this study, in-cylinder techniques are used to actively control the temperature of a catalyzed diesel particulate filter (DPF) in order to raise the DPF temperature to induce particulate oxidation. The performance of four strategies is compared for two different starting DPF temperatures (150°C and 300°C) on a 4-cylinder 1.7-liter diesel engine. The four strategies include: (1) addition of extra fuel injection early in the combustion cycle for all four cylinders, (2) addition of extra fuel injection late in the combustion cycle for all four cylinders, (3) operating one-cylinder with extra fuel injection early in the combustion cycle, and (4) operating one-cylinder with extra fuel injection late in the combustion cycle.

A CNG bi-fuel version of the GMC and Chevrolet C2500 pick up trucks was developed as an OEM (Original Equipment Manufacturer) vehicle. The converted bi-fuel vehicles use the same engine with modifications for use with gaseous fuels, and the same catalytic converters as the gasoline baseline. The fuel management system is an automatic switching bi-fuel system which is able to control fuel flow rate, spark timing, EGR, and perform OBD-II (On-Board Diagnostics II) on both gasoline and CNG. This system has been extensively tested and validated for durability, electro magnetic compatibility requirements, crash integrity, corrosion resistance, emissions performance and powertrain performance under extreme environmental conditions and different CNG fuel compositions. The CNG fuel storage technology of the bi-fuel system was validated to the most stringent safety and durability requirements in the industry.

The absorption of unburned fuel into the engine cylinder wall oil film has been identified as a source of hydrocarbon (HC) emissions from spark-ignited (SI)engines. While significant work has been done under steady-state operating conditions to quantify the contribution of this mechanism to overall unburned hydrocarbon emissions, little work has focused on cold starting conditions and in situ measurement of the fuel / oil film interaction. The work reported here shows how laser-induced fluorescence (LIF) spectroscopy can be used to make in situ measurements of the absorption of fuel into the cylinder wall oil film of a single cylinder engine. Measurements were made at two points in the engine cycle under cold start conditions. Results indicate that fuel concentration in the oil film reached a maximum of fifty percent (50%) during cold start operation, though fuel was present in the oil film throughout the engine cycle.

Liquefied Petroleum Gas (LPG) and Compressed Natural Gas (CNG) have long been recognized as ideal clean and potentially available fuels for motor vehicles. However, some disadvantages of the two gaseous fuels such as lower energy density (kW/l) compared to gasoline, a loss of power in unmodified converted engines relative to gasoline and the current shortage of refueling stations hamper their widespread use. Additionally, engines with throttle-body gaseous fuel fumigation need longer cranking time and exhibit relatively slow response during transient engine operation. To alleviate the above shortcomings, a low cost dual-fuel system was developed. The prototype system uses a mixture of gaseous fuel (Liquefied Petroleum Gas) and gasoline to enhance fuel economy, drivability, and lower emissions. The two fuels can be mixed at any percentage depending on the customer's need.

The objective of this project, which is supported by the U.S. Department of Energy (DOE) through the National Renewable Energy Laboratory (NREL), is to provide a comprehensive comparison of heavy-duty trucks operating on alternative fuels and diesel fuel. Data collection from up to eight sites is planned. This paper summarizes the design of the project and early results from the first two sites. Data collection is planned for operations, maintenance, truck system descriptions, emissions, duty cycle, safety incidents, and capital costs and operating costs associated with the use of alternative fuels in trucking.

As emission regulations become increasingly strict, the need for more accurate sampling systems becomes essential. When calculating emissions from a dilution system, a correction is made to remove the effects of contaminants in the dilution air. The dilution air correction was explored to determine why this correction is needed, when this correction is important, and what methods are available for calculating the dilution factor (DF). An experimental and error analysis investigation into the standard and recently proposed methods for calculating the DF was conducted. Five steady state modes were run on a 1992 Detroit Diesel engine series 60 and the DF from eleven different equations were investigated. The effects of an inaccurate dilution air correction on calculated fuel flow from a carbon balance and the mass emissions was analyzed. The dilution air correction was shown to be important only for hydrocarbons, particulate matter (PM), and CO2.

Heavy-Duty Diesel (HDD) engines' particulate matter (PM) emissions are most often measured quantitatively by weighing filters that collect diluted exhaust samples pre- and post-test. PM sampling systems that dilute exhaust gas and collect PM samples have different effects on measured PM data. Those effects usually contribute to inter-laboratory variance. The U.S. Environmental Protection Agency (EPA)'s 2007 PM emission measurement regulations for the test of HDD engines should reduce variability, but must also cope with PM mass that is an order of magnitude lower than legacy engine testing. To support the design of a 2007 US standard HDD PM emission sampling system, a parametric study based on a systematic Simulink® model was performed. This model acted as an auxiliary design tool when setting up a new 2007 HDD PM emission sampling system in a heavy-duty test cell at West Virginia University (WVU). It was also designed to provide assistance in post-test data processing.

Biodiesel fuels benefit both from being a renewable energy source and from decreasing in carbon monoxide (CO), total hydrocarbons (THC), and particulate matter (PM) emissions relative to petroleum diesel. The oxides of nitrogen (NOx) emissions from biodiesel blended fuels reported in the literature vary relative to baseline diesel NOx, with no NOx change or a NOx decrease found by some to an increase in NOx found by others. To explore differences in NOx, two Cummins ISM engines (1999 and 2004) were operated on 20% biodiesel blends during the heavy-duty transient FTP cycle and the steady state Supplemental Emissions Test. For the 2004 Cummins ISM engine, in-cylinder pressure data were collected during the steady state and transient tests. Three types of biodiesel fuels were used in the blends: soy, tallow (animal fat), and cottonseed. The FTP integrated emissions of the B20 blends produced a 20-35% reduction in PM and no change or up to a 4.3% increase in NOx over the neat diesel.

A CNG bi-fuel version of the Chevrolet Cavalier has been developed as an OEM (Original Equipment Manufacturer) vehicle. The fuel management system is an automatically switching bi-fuel system which is able to control fuel flow rate, spark timing, EGR, and perform OBD-II (On-Board Diagnostics II). The system consists of a CNG fuel tank, fuel filter, electric and manual fuel shutoff valves, high and low pressure regulators, gas mass sensor, mixture control valve, gas distribution system, CNG fuel gauge, OEM exhaust gas oxygen sensor, digital engine control unit (ECU), OEM powertrain control module (PCM) and unique wiring harness. This paper discusses the components, operation, and calibration of the CNG bi-fuel management system. A computer engine simulation model able to predict engine performance, fuel economy, and exhaust emissions, was used to assist spark, fuel, and EGR table mapping.

Diesel fuels derived from different types of crude oil can exhibit different chemistry while still meeting market requirements and specifications. Oil sands derived fuels typically contain a larger proportion of cycloparaffinic compounds, which result from the cracking and hydrotreating of bitumens in the crude. In the current study, 17 refinery streams consisting of finished fuels and process streams were obtained from a refinery using 100% oil sands derived crude oil. All samples except one met the ULSD standard of 15 ppm sulfur. The samples were characterized for properties and chemistry and run in a simple premixed HCCI engine using intake heating for combustion phasing control. Results indicate that the streams could be equally well characterized by chemistry or properties, and some simple correlations are presented. Cetane number was found to relate mainly to mono-aromatic content and the cycloparaffins did not appear to possess any unique diesel related chemical effects.