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This research focuses on co-cations modified Cu-zeolite catalyst CuCe/SSZ-13. The NOx conversion and hydrothermal stability of fresh and aged Cu/SSZ-13 and CuCe/SSZ-13 were evaluated to conclude the impact of Ce on the zeolite stability and mechanism of NH3-SCR reaction. For fresh samples, CuCe/SSZ-13 exhibited more than 80% efficiency at 225 °C to 600 °C, and showed higher NOx conversion below 225 °C and above 450 °C than Cu/SSZ-13. For aged catalysts, CuCe/SSZ-13 exhibited higher efficiency at all test temperatures than Cu/SSZ-13, and exhibited over 80% conversion at 225 °C to 350 °C, whereas, that was only 250 °C to 300 °C over fresh Cu/SSZ-13 sample. Furthermore, the effect of co-cation Ce on the phase structure changes, acid sites, redox capacity, transformation of various Cu species, and framework stability of the samples were evaluated by several techniques, such as TPD, TPO, TPR, BET, and XRD.

Exhaust gas recirculation (EGR) is effective in reducing engine-out NOx emissions; however, the EGR system is subject to fouling and corrosion. Fouling is mainly due to particulate buildup on the EGR component (e.g., EGR valve and cooler) surfaces. Corrosion is primarily related to oxides of sulfur and nitrogen in the gas stream, especially problematic when condensation occurs [1]. Because cooled EGR is most effective in controlling NOx emissions, EGR cooler design and operation are important considerations in engine design in order to meet durability requirements. An approach has been developed to greatly reduce EGR system fouling. Four EGR coolers were tested simultaneously with various PM control devices installed upstream of the cooler. System configuration and on-engine test results are presented herein.

In-cylinder emission controls were the focus for diesel engines for many decades before the emergence of diesel aftertreatment. Even with modern aftertreatment, control of in-cylinder processes remains a key issue for developing diesel vehicles with low tailpipe emissions. A reduction in in-cylinder emissions makes aftertreatment more effective at lower cost with superior fuel economy. This paper describes a study focused on an in-cylinder combustion control approach using a Delphi E3 flexible fuel system to achieve low engine-out NOx and PM emissions. A 2003 model year Detroit Diesel Corporation Series 60 14L heady-duty diesel engine, modified to accept the Delphi E3 unit injectors, and ultra low sulfur fuel were used throughout this study. The process of achieving premixed low temperature combustion within the limited range of parameters of the stock ECU was investigated.

The diesel particulate filter (DPF) is a critical aftertreatment device for control of particulate matter (PM) emissions from a diesel engine. DPF survivability is challenged by several key factors such as: excessive thermal stress due to DPF runaway regenerations (or uncontrolled regeneration) may cause DPF substrate and washcoat failure. Catalyst poisoning elements from the diesel fuel and engine oil may cause performance degradation of the catalyzed DPF. Harsh vibration from the powertrain, as well as from the road surface, may lead to mechanical failure of the substrate and/or the matting material. Evaluations of these important validation parameters were performed.

A high-efficiency NOx aftertreatment system has been proposed for use in Diesel engines. This system includes a Lean NOx Trap (LNT) in series with a Selective Catalyst Reduction (SCR) catalyst [6], [7], [8], and is hereinafter referred to as the LNT-SCR system. The combined LNT-SCR system can potentially overcome many of the drawbacks of LNT-only and SCR-only operation and achieve very high NOx conversion efficiency without external addition of ammonia (or urea). A laboratory test procedure was developed to validate the LNT-SCR system concept, and a series of tests was conducted to test the NOx conversion of this system under various conditions. A Synthetic Gas Reactor (SGR) system was modified to accommodate LNT and SCR catalyst cores and synthetic gas mixtures were used to simulate rich-lean regeneration cycles from a diesel engine. A Fourier Transform Infrared (FTIR) system was used to measure gas compositions within the LNT-SCR system.

Four-way catalyst system consisting of diesel oxidation catalyst (DOC), diesel particulate filter (DPF) and lean NOx trap (LNT) with alternative combustion such as low temperature combustion (LTC) and premixed controlled compression ignition (PCCI) is one of the effective ways to achieve the US Tier 2 Bin 5 and future European emissions for light duty diesel vehicles. However, thermal responses such as substrate temperature and temperature gradient of each catalyst component in the exhaust treatment system are different under different combustion modes and operation conditions. One exhaust treatment component's performance or durability can not be sacrificed for the sake of another. In this paper, thermal management strategies for exhaust treatment component temperature and temperature gradient by controlling lean and rich conditions of low temperature combustions as well as premixed controlled combustion, EGR rate and exhaust flow are demonstrated on a Renault G9T600 engine.

Dow Automotive has developed an ACM DPF substrate, characterized with light-weight, low pressure-drop, rapid regeneration, and excellent chemical resistance at high temperature. An uncatalyzed DPF was tested on a 2.0L common-rail diesel engine for over 100 soot loading and regeneration cycles, which included a combination of controlled regenerations, uncontrolled regenerations and incomplete regenerations. The DPF demonstrated high filtration efficiency and physical integrity throughout the entire test. The ACM DPF has also demonstrated excellent catalyst coating capability and performance. An ACM DPF with a total volume of three-liter and coated with the same catalyst formulation as the original catalyzed DPF, was used to replace the OEM four-liter catalyzed SiC DPF on a 2005 model-year 1.9L European diesel passenger car. It was demonstrated that the ACM DPF has lower pressure drop and faster regeneration than that of the OEM DPF.

A novel urea evaporation and mixing device has been developed to improve the overall performance of a urea-SCR system. The device was tested with a MY2007 Cummins ISB 6.7L diesel engine equipped with an SCR aftertreatment system. Test results show that the device effectively improved the overall NO conversion efficiency of the SCR catalyst over both steady-state and transient engine operating conditions, while NH₃ slip from the catalyst decreased.

Particulate Matter (PM) emissions from gasoline direct injection (GDI) engines are becoming a concern and will be limited by future emissions regulations, such as the upcoming Euro 6 legislation. Therefore, PM control from a GDI engine will be required in addition to effective reduction of HC, CO and NOx emissions. Three different integrated aftertreatment systems were developed to simultaneously reduce PM, HC, CO and NOx emissions from a preproduction Ford 3.5L EcoBoost GTDI engine, with PM reduction as the major focus. PM reduction efficiencies were calculated based on the measurements of PM mass and solid particle number. Test results show that tradeoffs exist in the design of aftertreatment systems to significantly reduce PM emissions from a GDI engine.

The University of Texas 2000 Ethanol Vehicle Challenge team remains focused on cold start, cold drivability, fuel economy, and emissions reduction for our 2000 Ethanol Vehicle Challenge entry. We used the stock PCM for all control functions except control of an innovative cold-start system our team designed. The primary modifications for improved emissions control involved ceramic coating of the exhaust manifolds, use of close-coupled ethanol-specific catalysts, use of a moddified version of the California Emissions Calibrated PCM, and our cold-start system that eliminates the need to overfuel the engine at the beginning of the FTP. Additionally, we eliminated EGR at high load to improve power density. Major modifications, such as increasing the compression ratio or pressure boosting, were eliminated from consideration due to cost, complexity, reliability, or emissions penalties.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. All of our prior tests with the injector probe used California Phase 2 reformulated gasoline as the liquid fuel. In the present study, a variety of pure liquid hydrocarbon fuels are used to examine the influence of fuel volatility and structure. Additionally, the exhaust hydrocarbons are speciated to differentiate between the emissions resulting from the gaseous fuel and those resulting from the liquid fuel. It is shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs.

An optical access engine was used to image the liquid film evaporation off the piston of a simulated direct injected gasoline engine. A directional injector probe was used to inject liquid fuel (gasoline, i-octane and n-pentane) directly onto the piston of an engine primarily fueled on propane. The engine was run at idle conditions (750 RPM and closed throttle) and at the Ford World Wide Mapping Point (1500 RPM and 262 kPa BMEP). Mie scattering images show the liquid exiting the injector probe as a stream and directly impacting the piston top. Schlieren imaging was used to show the fuel vaporizing off the piston top late in the expansion stroke and during the exhaust stroke. Previous emissions tests showed that the presence of liquid fuel on in-cylinder surfaces increases engine-out hydrocarbon emissions.

Low-cost automotive catalysts have been developed that contain 20-30% of the precious metals (7-15 g/ft3) commonly used in conventional catalysts, while providing a high efficiency of emissions control and durability for vehicles operating in emerging market countries. These catalysts were reformulated by replacing the Pd, Pt and Rh mixtures with optimized mixtures of rare-earth oxides (REOs). Laboratory studies demonstrated that these aged REO catalysts (80,000 km) with unleaded Chinese fuels reduce vehicle emissions by an average of 99%, 80% and 92% for CO, HC and NOx, respectively, when operating as a three-way catalyst in a closed-loop control mode at a stoichiometric air-to-fuel ratio. REO catalysts with 7.6g/ft3 of precious metals were tested on in-use Chinese Volkswagen Santanas with carbureted engine. Several strategies for air injection were tested on these vehicles.

Piston wetting can be isolated from the other sources of HC emissions from DISI engines by operating the engine predominantly on a gaseous fuel and using an injector probe to impact a small amount of liquid fuel on the piston top. This results in a marked increase in HC emissions. In a previous study, we used a variety of pure liquid hydrocarbon fuels to examine the influence of fuel volatility and structure on the HC emissions due to piston wetting. It was shown that the HC emissions correspond to the Leidenfrost effect: fuels with very low boiling points yield high HCs and those with a boiling point near or above the piston temperature produce much lower HCs. All of these prior tests of fuel effects were performed at a single operating condition: the Ford World Wide Mapping Point (WWMP). In the present study, the effects of load and engine speed are examined.

We have examined the influence of piston wetting on the size distribution and mass of particulate matter (PM) emissions in a SI engine using several different fuels. Piston wetting was isolated as a source of PM emissions by injecting known amounts of liquid fuel onto the piston top using an injector probe. The engine was run predominantly on propane with approximately 10% of the fuel injected as liquid onto the piston. The liquid fuels were chosen to examine the effects of fuel volatility and molecular structure on the PM emissions. A nephelometer was used to characterize the PM emissions. Mass measurements from the nephelometer were compared with gravimetric filter measurements, and particulate size measurements were compared with scanning electron microscope (SEM) photos of particulates captured on filters. The engine was run at 1500 rpm at the Ford world-wide mapping point with an overall equivalence ratio of 0.9.

The aim of this paper is to compile the state of the art of engine control and develop scenarios for improvements in a number of applications of engine control where the pace of technology change is at its most marked. The first application is control of downsized engines with enhancement of combustion using direct injection, variable valve actuation and turbo charging. The second application is electrification of the powertrain with its impact on engine control. Various architectures are explored such as micro, mild, full hybrid and range extenders. The third application is exhaust gas after-treatment, with a focus on the trade-off between engine and after-treatment control. The fourth application is implementation of powertrain control systems, hardware, software, methods, and tools. The paper summarizes several examples where the performance depends on the availability of control systems for automotive applications.

HCCI/PCCI combustion concepts have been demonstrated for both high brake thermal efficiency and low engine-out emissions. However, these advanced combustion concepts still could not be fully utilized partially due to the limitations of conventional fixed spray angle nozzle designs for issues related to wall wetting for early injections. The micro-variable circular orifice (MVCO) fuel injector provides variable spray angles, variable orifice areas, and variable spray patterns. The MVCO provides optimized spray patterns to minimize combustion chamber surface-wetting, oil dilution and emissions. Designed with a concise structure, MVCO can significantly extend the operation maps of high efficiency early HCCI/PCCI combustion, and enable optimization of a dual-mode HCCI/PCCI and Accelerated Diffusion Combustion (ADC) over full engine operating maps. The MVCO variable spray pattern characteristics are analyzed with high speed photographing.

Regulated and unregulated exhaust emissions (individual hydrocarbons, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), and nitro-polynuclear aromatic hydrocarbons (NPAH)) were characterized for the following alternate diesel combustion modes: premixed charge compression ignition (PCCI), and low-temperature combustion (LTC). PCCI and LTC were studied on a PSA light-duty high-speed diesel engine. Engine-out emissions of carbonyl compounds were significantly increased for all LTC modes and for PCCI-Lean conditions as compared to diesel operation; however, PCCI-Rich produced much lower carbonyl emissions than diesel operations. For PAH compounds, emissions were found to be substantially increased over baseline diesel operation for LTC-Lean, LTC-Rich, and PCCI-Lean conditions. PCCI-Rich operation, however, gave PAH emission rates comparable to baseline diesel operation.

Gasoline compression ignition (GCI) combustion is a promising solution to address increasingly stringent efficiency and emissions regulations imposed on the internal combustion engine. However, the high resistance to auto-ignition of modern market gasoline makes low load compression ignition (CI) operation difficult. Accordingly, a method that enables the variation of the fuel reactivity on demand is an ideal solution to address low load stability issues. Metal engine experiments conducted on a single cylinder medium-duty research engine allowed for the investigation of this strategy. The fuels used for this study were 87 octane gasoline (primary fuel stream) and diesel fuel (reactivity enhancer). Initial tests demonstrated load extension down to idle conditions with only 20% diesel by mass, which reduced to 0% at loads above 3 bar IMEPg.

With the rapid expansion of the automotive market in China, air quality in the major cities has become a severe concern. Great efforts have been made in introducing new emission regulations; however, fuel and lubricant qualities, emissions aftertreatment system durability and in-use compliance to the emissions regulations still require significant improvement. China follows the European Union (EU) emission regulations in general, but different levels of standards exist. This paper gives a comprehensive overview of the current and near-future heavy-duty diesel emission regulations, as well as fuel and lubricant specifications.