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Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

Internal combustion (IC) engines fueled by hydrogen are among the most efficient means of converting chemical energy to mechanical work. The exhaust has near-zero carbon-based emissions, and the engines can be operated in a manner in which pollutants are minimal. In addition, in automotive applications, hydrogen engines have the potential for efficiencies higher than fuel cells.[1] In addition, hydrogen engines are likely to have a small increase in engine costs compared to conventionally fueled engines. However, there are challenges to using hydrogen in IC engines. In particular, efficient combustion of hydrogen in engines produces nitrogen oxides (NOx) that generally cannot be treated with conventional three-way catalysts. This work presents the results of experiments which consider changes in direct injection hydrogen engine design to improve engine performance, consisting primarily of engine efficiency and NOx emissions.

New emissions certification requirements for medium duty vehicles (MDV) meeting chassis dynamometer regulations in the 8,500 lb to 14,000 lb weight classes as well as heavy duty (HD) engine dynamometer certified applications in both the under 14,000 lb and over 14,000 lb weight classes employing large diameter exhaust pipes (up to 4″) have created new exhaust stream sampling concerns. Current On-Board-Diagnostic (OBD) dyno certified particulate matter (PM) requirements were/are 7x the standard for 2010-2012 applications with a planned phase in down to 3x the standard by 2017. Chassis certified applications undergo a similar reduction down to 1.75x the standard for 2017 model year (MY) applications. Failure detection of a Diesel Particulate Filter (DPF) at these low detection limits facilitates the need for a particulate matter sensor.

A new method to estimate instantaneous A/F ratio and use the estimation as a feedback signal to control AFR during cold transients, before the oxygen sensor is functional, has been realized by a on-board PCM for a vehicle with a 4.6L, V8, PFI engine [4, 6]. Different AFRs cause variations in flame propagation, causing fluctuations in the effective torque. When a known AFR disturbance is induced into an engine system, a corresponding crankshaft angular velocity fluctuation can be detected. A variable derived from this physical phenomenon can be used to characterize the problem. The optimal fuel perturbation signal is designed by a relaxation concept, and the system model is determined by employing a dual-direction screening multivariate stepwise regression analysis. The estimated AFR is used by the PCM in a closed loop control to correct the fuel during cold transients.

Two-stroke cycle direct injection engines can achieve adequate stability at idle with stratified combustion at very lean overall air-fuel ratio, but exhaust temperature is very low. A rotary valve system was designed to spill charge from the cylinder into the intake tract during the compression stroke, in order to allow stable operation at lower engine delivery ratio and thereby increase exhaust temperature. Reduction of the engine delivery ratio was not achieved due to the poor scavenging characteristics of the swirl liners used, which resulted in high content of exhaust residual gas in the spill recirculation flow. Although the concept objective of higher exhaust temperature was not realized, the results indicate that the concept may be feasible if high purity of the spill recirculation flow can be achieved in conjunction with high trapping efficiency.

The effects of injector targeting and fuel volatility on transient fuel dynamics were studied with a comprehensive quasi-dimensional model and compared with experimental results from Part I of this report (1). The model includes the transient, convective vaporization of four multi-component fuel films coupled with a transient thermal warm-up model for realistic valve, port and cylinder temperatures (2, 3). Two injector targetings were analyzed, first with the fuel impacting the intake valve and in addition, the fuel impacting the port floor directly in front of the intake valve. The model demonstrates the importance of both component temperature and fuel impaction area on fuel vaporization, transient air fuel ratio (AFR) response and the amount of liquid fuel entering the cylinder. Generally, a smaller injector footprint area will lead to more liquid fuel entering the cylinder even if the spray is targeted at the back of the intake valve.

Robust on-board diagnosis of emission catalyst performance requires the development of artificially damaged "threshold" catalysts that accurately mimic the performance of damaged catalysts in customer use. The threshold catalysts are used by emissions calibrators to determine fore-aft exhaust oxygen sensor responses that indicate catalyst failure. Rather than rely on traditional trial-and-error processes to generate threshold catalysts, we have used a DFSS (Design For Six-Sigma) approach that explores, at a research level, the relationship between oxygen storage capacity (OSC) of the catalyst (i.e., the fundamental property dictating the response of the aft oxygen sensor) and key process input variables: high-temperature exposure, phosphorus poisoning, and catalyst "recovery."

Exhaust gas temperature is often measured with a device such as thermocouple or RTD (Resistance Temperature Detector). An alternative method to determine the gas temperature would be to use an existing gas sensor heating mechanism to perform as a temperature sensor. A planar type FLOH (Fast Light Off HEGO-Heated Exhausted Gas Oxygen) sensor under transient vehicle speed/load conditions is suited to this function and was modeled to predict the exhaust gas temperature. The numerical input to the model includes exhaust flow rate, heater voltage, and heater current. Laboratory experiments have been performed to produce an equation relating the resistance of the heater and the temperature of the sensor (heater), which provides a method to indirectly determine HEGO sensor temperature.

This paper summarizes results from a study on the effects of aging temperature and A/F ratio on the NOx storage capacity of a lean NOx trap. When aged at stoichiometry at 700°C, the NOx storage capacity of the NOx trap dropped considerably during the first 200 hours of aging and then at a much slower rate beyond 200 hours. The NOx storage capacity dropped more rapidly as the aging temperature increased, with the drop in capacity particularly evident between 900°C and 1000°C. The drop in NOx capacity was significantly larger for samples aged with part-time lean operation and/or part-time rich operation than for samples aged continuously at stoichiometry. The detrimental effects of lean and rich operation increased as the temperature increased. A Pt/Al2O3 model catalyst was exposed to reducing conditions at temperatures ranging from 670°C to 1041°C and then to oxidizing conditions over the same temperature range, and in-situ XRD was used to investigate Pt particle coarsening.

An experimental study of the performance of a reverse tumble, DISI engine is reported. Specific fuel consumption and engine-out emissions have been investigated for both homogeneous and stratified modes of fuel injection. Trends in performance with varying AFR, EGR, spark and injection timings have been explored. It is shown that neural networks can be trained to describe these trends accurately for even the most complex case of stratified charge operation with exhaust gas recirculation.

Partial flow sampling methods in emissions testing are interesting and preferred because of their lower cost, smaller size and applicability to engines of all sizes. However the agreement of the results obtained with instruments based on this method to those obtained with the traditional, large tunnel full flow sampling systems needs to be achieved, and the factors of construction that influence this agreement must be understood. These issues have received more attention lately in connection with ISO and WHDC standardization efforts underway to achieve a world-wide harmony in the sampling methods for heavy duty diesel engines, and with the introduction of similar Bag-minidiluter techniques into light duty SULEV gaseous pollutant measurement. This paper presents the theory and practice of a partial flow probe and tunnel design that addresses and minimizes the undesirable effects of the necessary differences between the two sampling methods.

Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.

Power Split Hybrids are unique when compared to conventional powertrains from the perspective that the engine speed is directly controlled by the motor/generator at all times. Therefore, traditional methods of detecting variations in fuel volatility do not apply for Power Split Hybrid based configurations. In their place, the Ratio-metric Fuel Compensation (RFC) method has been developed for Power Split Hybrid generator configurations to detect and compensate for engine hesitations within milliseconds of the first injection event. Furthermore, test results have shown that in the presence of low volatility fuel, RFC provides robust starts at the ideal lean air fuel ratio required for PZEV emissions compliance.

Emissions sample probes are widely used in engine and vehicle emissions development testing. Tailpipe bag summary data is used for certification, but the time-resolved (or modal) emissions data at various points along the exhaust system is extremely important in the emission control technology development process. Exhaust gas samples need to be collected at various locations along the exhaust aftertreatment system. Typically, a tube with a small diameter is inserted inside the exhaust pipe to avoid any significant effect on flow distribution. The emissions test equipment draws a gas sample from the exhaust stream at a constant volumetric flow rate (typically around 10 SLPM). The sample probe tube delivers exhaust gas from the exhaust pipe to emissions test equipment through multiple holes on the surface of tube. There can be multiple rows of holes at different axial planes along the length of the sample probe as well as multiple holes on a given axial plane of the sample probe.

Automotive three-way catalysts (TWC) were characterized using temperature-programmed reduction (TPR), x-ray diffraction (XRD), Raman spectroscopy, chemisorption measurements and laboratory activity measurements. Capabilities and limitations of these standard analytical techniques for the characterization of production-type automotive catalysts are pointed out. With the exception of chemisorption techniques, all appear to have general utility for analyzing exhaust catalysts. The techniques were used to show that the noble metals and ceria in fresh Pt/Rh and Pd/Rh catalysts are initially highly dispersed and contain a mixture of interacting and non-interacting species. Thermal aging of these catalysts (in the reactor or vehicle) caused both precious metal and ceria particles to sinter, thereby decreasing the interaction between the two.

Recent Federal and California legislation have mandated major improvements in emission control. Tailpipe HC emission must be decreased an order of magnitude for the California Ultra Low Emission Vehicle (ULEV) standard. Present feedback A/F* control systems employ a Heated Exhaust Gas Oxygen sensor (HEGO sensor) upstream of the catalyst to perform A/F feedback control. Limitations on the ultimate accuracy of these switching sensors are well known. To overcome these limitations a linear Universal Exhaust Gas Oxygen sensor (UEGO sensor) placed downstream from the minicatalyst is employed to attain improved A/F control and therefore, higher three-way catalyst (TWC) conversion efficiency. This configuration was granted a patent in 1992 (1**). This study compares performance differences between the two feedback control systems on a Ford Mustang. In initial studies both the UEGO and HEGO sensors were compared at the midposition location downstream of a minicatalyst.

A model is presented which incorporates the key mechanisms in the formation and reduction of unburned HC emissions from spark ignited engines. The model includes the effects of piston crevice volume, oil layer absorption / desorption, partial burns, and in-cylinder and exhaust port oxidation. The mechanism for the filling and emptying of the piston crevice takes into account the location of the flame front so that the flow of both burned gas and unburned gas is recognized. Oxidation of unburned fuel is calculated with a global, Arrhenius-type equation. A newly developed submodel is included which calculates the amount of unburned fuel to be added to the cylinder as a result of partial burns. At each crankangle, the submodel compares the rate of change of the burned gas volume to the rate of change of the cylinder volume.

Exhaust gas air-fuel ratio (A/F) sensors are common devices in powertrain feedback control systems aimed at minimizing emissions. Both resistive (using TiO2) and electrochemical (using ZrO2) mechanisms are used in the high temperature ceramic devices now being employed. In this work a new mechanism for making the measurement is presented based on the change in the workfunction of a Pt film in interaction with the exhaust gas. In particular it is found that the workfunction of Pt increases reversibly by approximately 0.7 V at that point (the stoichiometric ratio) where the exhaust changes from rich to lean conditions. This increase arises from the adsorption of O2 on the Pt surface. On returning to rich conditions, catalytic reaction of the adsorbed oxygen with reducing species returns the workfunction to its original value. Two methods, one capacitive and one thermionic, for electrically sensing this workfunction change and thus providing for a practical device are discussed.

Here we present a latent heat storage device which is used to provide “quick/supplemental” heat to the vehicle's conventional heating system. First, we present data from actual in-vehicle cold weather tests. Data are presented for heater and defroster performance tests, emissions tests and cold start tests after extended soaks. Secondly, heater performance predictions are made using a computer simulation program. Finally, the actual heater performance results are compared with the computer simulation.

Current demands for high fuel efficiency and low emissions in automotive powerplants have drawn attention to the two-stroke engine configuration. The present study measured trapping and scavenging efficiencies of a firing two-stroke spark-ignition engine by in-cylinder gas composition analysis. Intermediate results of the procedure included the trapped air-fuel ratio and residual exhaust gas fraction. Samples, acquired with a fast-acting electromagnetic valve installed in the cylinder head, were taken of the unburned mixture without fuel injection and of the burned gases prior to exhaust port opening, at engine speeds of 1000 to 3000 rpm and at 10 to 100% of full load. A semi-empirical, zero-dimensional scavenging model was developed based on modification of the non-isothermal, perfect-mixing model. Comparison to the experimental data shows good agreement.