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Journal Article

Lignin-Derived Carbon Fiber as a Co-Product of Refining Cellulosic Biomass

2014-01-15
2013-01-9092
Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.
Journal Article

X-ray Imaging of Cavitation in Diesel Injectors

2014-04-01
2014-01-1404
Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.
Journal Article

Eulerian CFD Modeling of Coupled Nozzle Flow and Spray with Validation Against X-Ray Radiography Data

2014-04-01
2014-01-1425
This paper implements a coupled approach to integrate the internal nozzle flow and the ensuing fuel spray using a Volume-of-Fluid (VOF) method in the CONVERGE CFD software. A VOF method was used to model the internal nozzle two-phase flow with a cavitation description closed by the homogeneous relaxation model of Bilicki and Kestin [1]. An Eulerian single velocity field approach by Vallet et al. [2] was implemented for near-nozzle spray modeling. This Eulerian approach considers the liquid and gas phases as a complex mixture with a highly variable density to describe near nozzle dense sprays. The mean density is obtained from the Favreaveraged liquid mass fraction. The liquid mass fraction is transported with a model for the turbulent liquid diffusion flux into the gas.
Journal Article

Buckling Analysis of Uncertain Structures Using Imprecise Probability

2015-04-14
2015-01-0485
In order to ensure the safety of a structure, adequate strength for structural elements must be provided. Moreover, catastrophic deformations such as buckling must be prevented. Using the linear finite element method, deterministic buckling analysis is completed in two main steps. First, a static analysis is performed using an arbitrary ordinate applied loading pattern. Using the obtained element axial forces, the geometric stiffness of the structure is assembled. Second, an eigenvalue problem is performed between structure's elastic and geometric stiffness matrices, yielding the structure's critical buckling loads. However, these deterministic approaches do not consider uncertainty the structure's material and geometric properties. In this work, a new method for finite element based buckling analysis of a structure with uncertainty is developed. An imprecise probability formulation is used to quantify the uncertainty present in the mechanical characteristics of the structure.
Technical Paper

Development of Ultra Low Viscosity 0W-8 Engine Oil

2020-04-14
2020-01-1425
Further fuel economy improvement of the internal combustion engine is indispensable for CO2 reduction in order to cope with serious global environmental problems. Although lowering the viscosity of engine oil is an effective way to improve fuel economy, it may reduce the wear resistance. Therefore, it is important to achieve both improved fuel economy and reliability. We have developed new 0W- 8 engine oil of ultra-low viscosity and achieved an improvement in fuel economy by 0.8% compared to the commercial 0W-16 engine oil. For this new oil, we reduced the friction coefficient under boundary lubrication regime by applying an oil film former and calcium borate detergent. The film former increased the oil film thickness without increasing the oil viscosity. The calcium borate detergent enhanced the friction reduction effect of molybdenum dithiocarbamate (MoDTC).
Journal Article

Prediction of the Nozzle Flow and Jet Characteristics at Start and End of Injection: Transient Behaviors

2015-09-01
2015-01-1850
This paper reports investigations on diesel jet transients, accounting for internal nozzle flow and needle motion. The calculations are performed with Large Eddy Simulation (LES) turbulence model by coupling the internal and external multiphase flows simultaneously. Short and multiple injection strategies are commonly used in internal combustion engines. Their features are significantly different from those generally found in steady state conditions, which have been extensively studied in the past, however, these conditions are seldom reached in modern engines. Recent researches have shown that residual gas can be ingested in the injector sac after the end-of-injection (EOI) and undesired dribbles can be produced. Moreover, a new injection event behaves differently at the start-of-injection (SOI) depending on the sac initial condition, and the initial spray development can be affected for the first few tens of μs.
Journal Article

Development of a Highly Anti-Corrosive Organic-Inorganic Hybrid Paint

2016-04-05
2016-01-0540
A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.
Journal Article

Time-Resolved X-Ray Radiography of Spark Ignition Plasma

2016-04-05
2016-01-0640
Understanding the short-lived structure of the plasma that forms between the electrodes of a spark plug is crucial to the development of improved ignition models for SI engines. However, measuring the amount of energy deposited in the gas directly and non-intrusively is difficult, due to the short time scales and small length scales involved. The breakdown of the spark gap occurs at nanosecond time scales, followed by an arc phase lasting a few microseconds. Finally, a glow discharge phase occurs over several milliseconds. It is during the arc and glow discharge phases that most of the heat transfer from the plasma to the electrodes and combustion gases occurs. Light emission can be used to measure an average temperature, but micron spatial resolution is required to make localized measurements.
Journal Article

Technical Development of Electro Magnetic Compatibility for Plug-in Hybrid Vehicle / Electric Vehicle Using Wireless Power Transfer System

2016-04-05
2016-01-1161
In 2007, researchers at the Massachusetts Institute of Technology successfully completed a Wireless Power Transfer (WPT) experiment. Ever since, interest in WPT has been growing. At Toyota, we have been developing the underlying technology of a WPT system. Simultaneously we have been working with regulatory committees to create a standard for WPT. In particular, there are concerns that WPT’s radiated emissions could cause harm to humans and the neighboring electronic equipment. There are many challenges that need to be overcome, but a key concern is understanding WPT’s electromagnetic compatibility (EMI: Electro-Magnetic Interference and EMF: Electro-Magnetic Field). In this paper, we show the technical issues, the evaluation method, and the development status of EMI and EMF on PHVs/EVs when using WPT. For Electromagnetic interference (EMI) performance, we investigated both an open area test site and an electromagnetic anechoic chamber as evaluation environments.
Journal Article

Development of Paint Booth: “New Paint Mist Collection Method”

2016-04-05
2016-01-1258
1 Inside a paint booth to spray paint on vehicle bodies, bumpers, and other parts (hereinafter referred to as “works”), air whose temperature and humidity are controlled by air-conditioner is supplied by blower fans through filters. Dust-eliminated and regulated air flow is sent downward from top to bottom (hereinafter referred to as “downflow”) in the painting booth. Conventionally, paint which does not adhere to work in spraying (hereinafter referred to as “paint mist”) is collected while flowing at a high speed through a slit opening called venturi scrubber in a mixture of air and water. However, this mist collecting system using venturi scrubber requires a large space with a large amount of pressure loss while consuming substantial energy. By radically changing the mist collecting principle, we developed a new compact system with less pressure loss aiming to reduce energy consumption by 40% in a half-size booth.
Journal Article

Development of Fracture Model for Laser Screw Welding

2016-04-05
2016-01-1344
This paper describes the development of a fracture finite element (FE) model for laser screw welding (LSW) and validation of the model with experimental results. LSW was developed and introduced to production vehicles by Toyota Motor Corporation in 2013. LSW offers superb advantages such as increased productivity and short pitch welding. Although the authors had previously developed fracture FE models for conventional resistance spot welding (RSW), a fracture model for LSW has not been developed. To develop this fracture model, many comprehensive experiments were conducted. The results revealed that LSW had twice as many variations in fracture modes compared to RSW. Moreover, fracture mode bifurcations were also found to result from differences in clearance between welded plates. In order to analyze LSW fracture phenomena, detailed FE models using fine hexahedral elements were developed.
Journal Article

Development of Chemical Process for Recovering High-quality Rare-earth Oxides from HV Motor Magnets

2017-03-28
2017-01-1278
In the automobile industry, interest in the prevention of global warming has always been high. The development of eco cars (HV, EV etc.), aimed at reducing CO2 emissions during operation, has been progressing. In the announcement of its "Toyota Environmental Challenge 2050", Toyota declared its commitment to creating a future in which people, cars, and nature coexist in harmony. In this declaration, Toyota committed to reducing CO2 emissions not only during operation but also over the entire life cycle of vehicles, and to using resources effectively based on a 4 R’s approach (refuse, reduce, reuse, and recycle). Although eco cars decrease CO2 emissions during operation, most of them increase CO2 emissions during manufacturing. For example, the rare-earths (Nd, Dy etc.) used in the magnets of driving motors are extracted through processes that produce a significant amount of CO2 emissions.
Technical Paper

Development of RC-IGBT with a New Structure That Contributes to Both Reduced Size of Power Control Unit and Low Loss in Hybrid Electric Vehicles

2020-04-14
2020-01-0596
In order to improve the fuel efficiency of Hybrid Electric Vehicles (HEVs), it is necessary to reduce the size and power loss of the HEV Power Control Units (PCUs). The loss of power devices (IGBTs and FWDs) used in a PCU accounts for approximately 20% of electric power loss of an HEV. Therefore, it is important to reduce the power loss while size reduction of the power devices. In order to achieve the newly developed PCU target for compact-size vehicles, the development targets for the power device were to achieve low power loss equivalent to its previous generation while size reduction by 25%. The size reduction was achieved by developing a new RC-IGBT (Reverse Conducting IGBT) with an IGBT and a FWD integration. As for the power loss aggravation, which was a major issue due to this integration, we optimized some important parameters like the IGBT and FWD surface layout and backside FWD pattern.
Technical Paper

Exhaust Gas Sensor with High Water Splash Resistant Layer for Lower Emission

2020-04-14
2020-01-0565
Increasingly stringent regulations call for the reduction of emissions at engine startup to purify exhaust gas and reduce the amount of CO2 emitted. Air-fuel ratio (A/F) sensors detect the composition of exhaust gas and provide feedback to control the fuel injection quantity in order to ensure the optimal functioning of the catalytic converter. Reducing the time needed to obtain feedback control and enabling the restriction-free installation of A/F sensors can help meet regulations. Conventional sensors do not activate feedback control immediately after engine startup as the combination of high temperatures and splashes of condensed water in the exhaust pipe can cause thermal shock to the sensor element. Moreover, sensors need to be installed near the engine to increase the catalyst reaction efficiency. This increases the possibility of water splash from the condensed water in the catalyst.
Journal Article

Influence of Bio Diesel Fuel on Engine Oil Performance

2010-05-05
2010-01-1543
To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.
Journal Article

Narrow-Band Omnidirectional Structural Color

2008-04-14
2008-01-1049
Automotive pigments consist of absorptive materials which absorb most of the wavelengths of light in the visible range (400-800 nm) except one particular range which gets reflected and seen as color. This coloring mechanism based on light absorption due to their molecular structure generally reflects a broader range of wavelength with a moderate reflectivity (50-60%). However in nature we find many magnificent colors in insects, butterflies, birds and fishes. These colors in nature are not based on the abortive pigments, but on the nanoscopic regular structures that interfere light reflected from those periodic sites. Since animals contain no solid metals, to produce metallic-like reflections they also rely on interference of light.[1] Most common and well-known form of animal reflector is the multilayer type where alternating high and low refractive index layers are formed. Such nanostructure assembly can reflect light up to 100%.
Journal Article

Study of Alternative Oxygen Reduction Electrocatalyst for Pt Based on Transition Metal Chalcogenides

2008-04-14
2008-01-1265
The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.
Journal Article

Measurement of Oil Film Pressure in the Main Bearings of an Operating Engine Using Thin-Film Sensors

2008-04-14
2008-01-0438
We developed a technique to measure oil film pressure distribution in engine main bearings using thin-film pressure sensors. The sensor is 7μm in thickness, and is processed on the surface of an aluminum alloy bearing. In order to increase the durability of the sensor, a layer of MoS2 and polyamide-imide was coated on thin-film sensors. This technique was applied to a 1.4L common-rail diesel engine operated at a maximum speed of 4,500r/min with a 100Nm full load, and the oil film pressure was monitored while the engine was operating. The measured pressure was compared with calculations based on hydrodynamic lubrication (HL) theory.
Journal Article

PEFC Performance Improvement Methodology for Vehicle Applications

2012-04-16
2012-01-1232
For over a decade and a half, Toyota Motor Corporation has been developing fuel cell vehicles (FCVs) and is continuing various approaches to enable mass production. This study used new methods to quantitatively observe some of the mass transfer phenomena in the reaction field, such as oxygen transport, water drainage, and electronic conductivity. The obtained results are applicable to the design requirements of ideal reaction fields, and have the potential to assist to reduce the size of the fuel cell.
Journal Article

Thermal Analysis of Traction Contact Area Using a Thin-film Temperature Sensor

2013-04-08
2013-01-0368
The purpose of this paper is to construct the thermal analysis model by measuring and estimating the temperature at the traction contact area. For measurement of temperature, we have used a thin-film temperature sensor. For estimation of temperature, we have composed the thermal analysis model. The thin-film temperature sensor was formed on the contact surface using a spattering device. The sensor is constituted of three layers (sensor layer, insulation layer and intermediate layer). Dimensions of the sensor were sufficiently smaller than the traction contact area. The sensor featured high specific pressure capacity and high speed responsiveness. The thermal analysis model was mainly composed of three equations: Carslaw & Jaeger equation, Rashid & Seireg equation and heat transfer equation of shear heating in oil film. The heat transfer equation involved two models (local shear heating model at middle plane, homogeneous shear heating model).
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