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Technical Paper

Vapor Pressures of Diesel Fuel Oxygenate Blends

2002-10-21
2002-01-2850
A gas chromatographic technique was used to determine the vapor pressures of blends of six candidate diesel fuel oxygenates with three diesel fuels at 0, 5, 10, 30, and 100 percent blend levels. Both the oxygenates and the diesel fuels were selected to represent a variety of chemical compositions. The vapor pressures were determined over a range of temperatures from -30 C to +30 C. In each case the fraction of the vapor pressure derived from the oxygenate and the fuel was identified. The vapor pressure results showed that there were significant deviations from ideality, leading to both higher and lower vapor pressures than would be predicted from Raoult's Law. These results are significant for fire safety and evaporative emissions as well as for a more basic understanding of the behavior of these blends. Data were also obtained on the heats of vaporization for each of the blends.
Technical Paper

Oxygenate Compatibility with Diesel Fuels

2002-10-21
2002-01-2848
Miscibility, water tolerance, cloud point, and flash point data are presented for seven candidate diesel fuel oxygenates: dipentyl ether, dibutoxymethane, 2-ethoxyethyl ether, diethyl maleate, tripropylene glycol monomethyl ether, dibutyl maleate, and glycerol tributrate. These oxygenates were blended with three different diesel fuels: an oil sands diesel, an ultra-low sulfur diesel, and a Fischer-Tropsch diesel. Blend levels included 0, 5, 10, 30, and 100 % oxygenate. Properties were measured at temperatures of -30, -15, 0, 15, and 30 C.
Technical Paper

Extent of Indoor Flammable Plumes Resulting from CNG Bus Fuel System Leaks

1992-11-01
922486
A validated three-dimensional mathematical model was used to examine the extent of flammable plumes resulting from both large and small CNG leak scenarios inside a typical transit maintenance and storage facility ventilated at a rate of five air changes per hour. The leak rates used were based on an engineering and experimental analysis of actual CNG bus fuel system components. The results showed that both large and small CNG leaks produced flammable plumes, such plumes extended from a half a bus length to several bus lengths away from the leak source, and the plume from a large leak formed a layer along the ceiling before being dispersed by building ventilation.
Technical Paper

Vehicle Fuel Economy-The CleanFleet Alternative Fuels Project

1995-02-01
950396
Fuel economy estimates are provided for the CleanFleet vans operated for two years by FedEx in Southern California. Between one and three vehicle manufacturers (Chevrolet, Dodge, and Ford) supplied vans powered by compressed natural gas (CNG), propane gas, California Phase 2 reformulated gasoline (RFG), methanol (M-85), and unleaded gasoline as a control. Two electric G-Vans, manufactured by Conceptor Corporation, were supplied by Southern California Edison. Vehicle and engine technologies are representative of those available in early 1992. A total of 111 vans were assigned to FedEx delivery routes at five demonstration sites. The driver and route assignments were periodically rotated within each site to ensure that each vehicle would experience a range of driving conditions. Regression analysis was used to estimate the relationships between vehicle fuel economy and factors such as the number of miles driven and the number of delivery stops made each day.
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