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It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

In a typical automotive SCR system, the urea-water solution is injected into the exhaust gas stream and breaks up into small droplets through the atomization process due to the interaction with the exhaust gas flow. The water vapor is released by vaporization and leaves the urea component in the droplets. The urea component is converted to ammonia and iso-cyanic acid and other species through thermal decomposition and hydrolysis processes. A multi-dimensional CFD model is developed in the present study to simulate injection and mixing in the automotive SCR systems. The urea-water solution is modeled as a bi-component liquid mixture with evaporation laws for each component. A Lagrangian method with spray sub-models is used to track the liquid droplets and the atomization process. The thermal decomposition and hydrolysis processes of the urea and iso-cyanic acid are simulated by simplified two-step reaction mechanisms.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

Urea/SCR systems have been proven effective at reducing NOx over a wide range of operating conditions on mid/heavy duty diesel vehicles. However, design changes due to reduction in the size of modern compact Urea/SCR systems and lower exhaust temperature have increased the possibility of urea deposit formation. Urea deposits are formed when urea in films and droplets undergoes undesirable secondary reactions and generate by-products such as ammelide, biuret and cyanuric Acid (CYA). Ammelide and CYA are difficult to decompose which lead to the formation of solid deposits on the surface. This phenomenon degrades the performance of the after treatment system by decreasing overall mixing efficiency, lowering de-NOx efficiency and increasing pressure drop. Therefore, mitigating urea deposits is a primary design goal of modern diesel after-treatment systems.

With stringent emission regulations, aftertreatment systems with a Diesel Particulate Filter (DPF) and a Selective Catalytic Reduction (SCR) are required for diesel engines to meet PM and NOx emissions. The adoption of aftertreatment increases the back pressure on a typical diesel engine and makes engine calibration a complicated process, requiring thousands of steady state testing points to optimize engine performance. When configuring an engine to meet Tier IV final emission regulations in the USA or corresponding Stage IV emission regulations in Europe, this high back pressure dramatically impacts transient performance. The peak NOx, smoke and exhaust temperature during a diesel engine transient cycle, such as the Non-Road Transient Cycle (NRTC) defined by the US Environmental Protection Agency (EPA), will in turn affect the performance of the aftertreatment system and the tailpipe emissions level.

This paper discusses a joint customer-supplier program intended to further develop the ability to design and apply aluminum alloy pistons selectively reinforced with ceramic fibers for heavy duty diesel engines. The approach begins with a comprehensive mechanical properties evaluation of base and reinforced material. The results demonstrated significant fatigue strength improvement due to fiber reinforcement, specially at temperatures greater than 300°C. A simplified numerical analysis is performed to predict the temperature and fatigue factor values at the combustion bowl area for conventional and reinforced aluminum piston designs for a 6.6 liter engine. It concludes that reinforced piston have a life expectation longer than conventional aluminum piston. Structural engine tests under severe conditions of specific power and peak cylinder pressure were used to confirm the results of the cyclic properties evaluation and numerical analysis.

The properties of aluminum alloys reinforced by ceramic nanoparticles (less than 100nm) would be enhanced considerably while the ductility is retained over that of the native alloy. The potential of bulk Al-based metal matrix nano-composites (Al MMNCs) cannot be fully developed for industrial applications unless complex structural Al MMNC components can be fabricated cost effectively, such as by casting. Reliable bulk Al MMNCs cannot be cast unless the nanoparticles can be dispersed and distributed uniformly in molten Al alloys. This paper investigates a high volume production method for high performance aluminum matrix nanocomposites, in particular, the application of high intensity ultrasonic cavitation in mixing and dispersing nano-sized ceramic particles in Al melts to cast bulk Al MMNCs for complex automobile structures. Nano-sized SiC particles have been dispersed in molten aluminum alloy A356 for casting.

The growth of auto sales in emerging markets provides a good opportunity for automakers. Cost is a key factor for any automaker to win in an emerging market. This paper analyzes risks and opportunities in a low cost manufacturing environment. The Chinese auto market is used as an example and three categories of risks are analyzed. A typical risk assessment for cost reduction includes the analysis of environment risks, process risks and strategic risks associated with all phases of a product life. In an emerging market, emission regulations are a rapidly-evolving environment variable, since most countries with less regulated emission codes try to catch up with the newly- developed technologies to meet sustainable growth targets. Emission regulations have a huge impact on product design, manufacturing and maintenance in the automotive industry, and hence the related cost reduction must be thoroughly analyzed during risk assessment.

Various engine platforms employ Selective Catalytic Reduction (SCR) technology to reduce the tail pipe emissions of oxides of nitrogen (NOx) from diesel engines as part of an overall strategy to comply with the emission regulations in place in various countries. High levels of NOx conversion (greater than 98%) in SCR aftertreatment may provide operating margin to increase overall fuel efficiency. However, to realize the potential fuel efficiency gains, the SCR technology employed should achieve high NOx conversion with limited reductant slip over transient application cycles in addition to steady state operation. A new approach to SCR controls was developed and implemented. This approach does not rely on any maps to determine the amount of urea solution to be dosed, thus significantly reducing calibration and development time and effort when implementing the SCR technology on multiple engine platforms and applications.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

For competition in the 1998 FutureCar Challenge (FCC98), the University of Wisconsin - Madison FutureCar Team has designed and built a lightweight, charge sustaining, parallel hybrid electric vehicle by modifying a 1994 Mercury Sable Aluminum Intensive Vehicle (AIV), nicknamed the Aluminum Cow. The Wisconsin team is striving for a combined, FTP cycle gasoline-equivalent fuel economy of 21.3 km/L (50 mpg) and Ultra Low Emissions Vehicle (ULEV) federal emissions levels while maintaining the full passenger/cargo room, appearance, and feel of a full-size car. To reach these goals, Wisconsin has concentrated on reducing the overall vehicle weight. In addition to customizing the drivetrain, the team has developed a vehicle control strategy that both aims to achieve these goals and also allows for the completion of a reliable hybrid in a short period of time.

The University of Wisconsin - Madison FutureCar Team has designed and built a lightweight, charge sustaining, parallel hybrid-electric vehicle for entry into the 1999 FutureCar Challenge. The base vehicle is a 1994 Mercury Sable Aluminum Intensive Vehicle (AIV), nicknamed the “Aluminum Cow,” weighing 1275 kg. The vehicle utilizes a high efficiency, Ford 1.8 liter, turbo-charged, direct-injection compression ignition engine. The goal is to achieve a combined FTP cycle fuel economy of 23.9 km/L (56 mpg) with California ULEV emissions levels while maintaining the full passenger/cargo room, appearance, and feel of a full-size car. Strategies to reduce the overall vehicle weight are discussed in detail. Dynamometer and experimental testing is used to verify performance gains.

Urea water solution-based Selective Catalytic Reduction (SCR) of NOx emissions from vehicular diesel engines is now widely used world-wide to meet strict health and environmental protection regulations. While urea-based SCR is proven effective, urea-derived deposits often form near injectors, on mixers and pipes, and on the SCR catalyst face. Further understanding of these deposit-formation processes is needed to design aftertreatment system hardware and control systems capable of avoiding severe urea-derived deposits. Computational Fluid Dynamics (CFD) is widely used in SCR aftertreatment design. Film formation, movement, solid wall cooling and deposit initiation/growth time-scales are in the range of minutes to hours, but traditional CFD simulations take too long to reach these time-scales. Here, we propose and demonstrate the frozen flow approach for pulsed sprays and conjugate heat transfer to reduce computation time while maintaining accuracy of key physics.

In order to assist in fast design cycle of Diesel engines selective catalytic reduction (SCR) exhaust systems, significant endeavor is currently being made to improve numerical simulation accuracy of urea thermo-hydrolysis. In this article, the achievements of a recently developed urea semi-detailed decomposition chemical scheme are assessed using three available databases from the literature. First, evaporation and thermo-hydrolysis of urea-water solution (UWS) single-droplets hanged on a thin thermocouple ring (127 μm) as well as on a thick quartz (275 μm), have been simulated at ambient temperature conditions ranging from 473K to 773K. It has been shown that the numerical results, in terms of evaporation rate and urea gasification, as well as droplet temperature history are very close to the experiments if the heat flux coming from the droplet support is properly accounted for.

Urea-water solution (UWS) injection combined with Selective Catalytic Reduction (SCR) has developed as an effective method of meeting EPA and EURO NOx emissions regulations for diesel engines. Urea/SCR systems encompass a wide range of engine sizes, from light duty vehicles to large ship or power generation engines. One key challenge faced by modern urea/SCR systems is the formation of solid deposits of urea decomposition by-products that are difficult to remove. These deposits are proven to be detrimental to urea/SCR systems by decreasing ammonia uniformity, clogging injector nozzles and increasing pressure drop of the whole system. Urea deposits only form in a narrow range of wall temperatures and take many minutes to hours to form. The decomposition of urea into deposits begins with the formation of biuret and then progresses into the crystalline species cyanuric acid (CYA), ammelide, and ammeline.

Fuel properties impact the engine-out emission directly. For some geographic regions where diesel engines can meet emission regulations without aftertreatment, the change of fuel properties will lead to final tailpipe emission variation. Aftertreatment systems such as Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) are required for diesel engines to meet stringent regulations. These regulations include off-road Tier 4 Final emission regulations in the USA or the corresponding Stage IV emission regulations in Europe. As an engine with an aftertreatment system, the change of fuel properties will also affect the system conversion efficiency and regeneration cycle. Previous research works focus on prediction of engine-out emission, and many are based on chemical reactions. Due to the complex mixing, pyrolysis and reaction process in heterogeneous combustion, it is not cost-effective to find a general model to predict emission shifting due to fuel variation.

The proposed Euro 7 regulation aims to substantially reduce the NOx emissions to 0.03 g/km, a trend also seen in upcoming China 6b and US EPA regulations. Meeting these stringent requirements necessitates advancements in Urea/Selective Catalytic Reduction (SCR) aftertreatment systems, with the urea deposit formation being a key challenge to its design. It’s proven that Computational Fluid Dynamics (CFD) can be an effective tool to predict Urea deposits. Transient wall temperature prediction is crucial in Urea deposit modeling. Additionally, fully understanding the kinetics of urea decomposition and by-products solidification are also critical in predicting the deposit amount and its location. In this study, we introduce (i) a novel film boiling model (IFPEN-BRT model) and (ii) a new urea by-product solidification model in the CONVERGE CFD commercial solver, and validate the results against the recent experiments.