Search Results

The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).

In April 2003, a small field study was initiated to evaluate the effect of lube oil formulations on ash accumulation in heavy-duty diesel DPFs. Nine (9) Fuel Delivery Trucks were retrofitted with passive diesel particulate filters and fueled with ultra low sulfur diesel which contains less than 15 ppm sulfur. Each vehicle operated in the field for 18 months or approximately 160,000 miles (241,401 km) using one of three lube oil formulations. Ash accumulation was determined for each vehicle and compared between the three differing lube oil formulations. Ash analyses, used lube oil analysis and filter substrate evaluations were performed to provide a complete picture of DPF operations. The evaluation also examined some of the key parameters that allows for the successful implementation of the passive DPF in this heavy-duty application.

Current production heavy duty diesel engines have a brake thermal efficiency (BTE) between 43-46% [1]. In partnership with the United States Department of Energy (DOE) as part of the Supertruck 2 program, Cummins has undertaken a research program to develop a new heavy-duty diesel engine designed to deliver greater than 50% BTE without the use of waste heat recovery. A system level optimization focused on: increased compression ratio, higher injection rate, carefully matched highly efficient turbocharging, variable lube oil pump, variable cooling components, and low restriction after treatment designed to deliver 50% BTE at a target development point. This work will also illustrate the system level planning and understanding of interactions required to allow that same 50% BTE heavy duty diesel engine to be integrated with a waste heat recovery (WHR) system to deliver system level efficiency of 55% BTE at a single point.