Search Results

The backward flow of the hot burned gas surrounding a diesel flame was found to be one of the factors dominating the set-off length (also called the lift-off length), that is, the distance from a nozzle exit into which a diffusion flame cannot intrude. In the combustion chamber of an actual diesel engine, the entrainment of the surrounding gas into a spray jet from a multi-hole nozzle is restricted by the walls and adjacent spray jets, which induces the backward flow of the surrounding gas. A new momentum theory to calculate the backward flow velocity was established by extending Wakuri's momentum theory. Shadowgraph imaging in an optical engine successfully visualized the backward flow of the hot burned gas.

A method of real time oil concentration measurment has been developed utilizing the effect of ultraviolet light absorption by lubricating oil in the liquid refrigerant line of an automotive air conditioning system. The light wavelengths from 200nm to 370nm are selected based on the ultraviolet light absorption sensitivity of the oils and refrigerants (CFC12,HFC134a). The effects of temperature,pressure and contaminantion on the absorbance of light are investigated in order to determine how these parameters affect the concentration measurement. The density changes of refrigerants are then compensated in the calculation for the oil concentration. The uncertainties of the overall concentration measurement are less than ±0.1 weight percent at 1 weight percent concentration. A transient oil circulation of the automotive air conditioner is measured by using this method.

The hole diameter of injection nozzles in diesel engines has become smaller and the nozzle coking could potentially cause injection characteristics and emissions to deteriorate. In this research, engine tests with zinc-added fuels, deposit analyses, laboratory tests and numerical calculations were carried out to clarify the deposit formation mechanisms. In the initial phase of deposit formation, lower zinc carboxylate formed close to the nozzle hole outlet by reactions between zinc in the fuel and lower carboxylic acid in the combustion gas. In the subsequent growth phase, the main component changed to zinc carbonate close to nozzle hole inlet by reactions with CO₂ in the combustion gas. Metal components and combustion gases are essential elements in the composition of these deposits. One way of removing these deposits is to utilize cavitations inside the nozzle holes.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.

We have developed a high-precision linear Hall sensor, which can detect absolute angles from 0 to 360°. In this sensor, novel vertical Hall elements have been used that can be fabricated using CMOS process technology, and the signal processing circuit is incorporated on the same chip. Using two vertical Hall elements placed precisely at an angle of 90° in the center of the chip, two-dimensional magnetic signals are detected. These signals are converted to an absolute angle by calculating the arc tangent of two Hall voltages. Moreover, this process compensates for the temperature dependence of these signals. Such a novel integrated vertical Hall sensor is promising for a wide range of applications.

In order to clarify the combustion behavior in the ultra high engine speed range, a new technique has been developed. This technique is composed of ionization current detection and flame observation, and is highly heat-resistant, vibration-resistant, and has a quick response. From analyzing the flame front propagation in the high-speed research engine, it was found that the flame propagated throughout the entire cylinder over almost the same crank angle period irrespective of engine speed introduction.

Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.

More than twenty years have passed since we invented polymer-clay nanocomposites (PCN), in which only a few wt.-% of silicate is randomly and homogeneously dispersed in the polymer matrix. When molded, these nanocomposites show superior properties compared to pristine polymers such as tensile strength, tensile modulus, heat distortion temperature, gas barrier property, and so on. The number of papers on PCN has increased rapidly in recent years, reaching over 500 only in 2005. As the pioneers of the new technology, we will review its history highlighting our works. Epoch-making events of PCN are as follows: In 1985, The first PCN, nylon 6-clay hybrid (NCH), was invented. In 1987, NCH was first presented at the ACS Fall Meetings. In 1989, NCH was presented at the MRS Fall Meetings, firing PCN. In 1989, Toyota launched cars equipped with a NCH part. In 1996, Clay was found to cause a memory effect in liquid crystals.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

Ever since the creation of the spark plug, improvements have continually been made to achieve high ignitability and long life. To fulfill these requirements, “Iridium Spark Plug” was introduced in 1997 with fine-wire center electrode technology to promote ignitability and long life. Then in 2003 “Super Ignition Spark Plug” was developed which uses fine-wire precious metal alloys on both the center and ground electrodes to achieve supreme ignitability and long life. Currently, the global technology trend is focusing more and more on the regulation of emissions and fuel consumption. This is driven by increased awareness for environmental conservation. These regulations are becoming stricter, which leads to a higher demand for spark plug ignitability from all kinds of vehicles ranging from luxury cars through compact sized cars. Particularly in the small vehicle category, both ignitability and low cost are a requirement.

“Adherent odors” emitted from the evaporator in an air-conditioning (A/C) unit are caused by desorption of adherent odorant on the evaporator such as exhaust gas, cigarette odor, interior materials and so on. In an attempt to reduce adherent odors we have developed and initiated production of the ‘Adherent Odor Reductive Coating’. In this paper we investigate the adherent and desorption mechanisms of these odors by componential analyses and odor sensory tests. As the result of the investigation, we find that the odor emission relates to hydrophilic group on the evaporator surface and we design evaporator coating based on the result. This paper also reports the positive effects that our ‘Adherent Odor Reductive Coating’ has in reducing adherent odors.

To meet diesel emission regulations, high injection pressure is demanded for the supply pump of electronically controlled common-rail type injection system. DENSO has produced common-rail type injection system in 1999. Cam and roller to generate high pressure in the supply pump at the system are composed of steel and silicon nitride ceramics, and are rolling contact under light oil lubrication. Therefore, rolling contact fatigue failure had been concerned. In order to assure the components, we estimated the influence on the materials and the lubrication on the rolling fatigue strength of silicon nitride ceramics, the contact fatigue life was tested under oil lubrication.

One of typical outcome of the desire for increasing passenger comfort is that especially for deodorant efficiency. Since customers are becoming so sensitive about cabin odor, development of more effective deodorant filter is strongly required. Out side of vehicle, which most being disliked is diesel odor, therefore, analysis on this diesel gas and investigation to identity the ingredient for the main cause of the strong odor were executed, and found that acetaldehyde gas is the one. Therefore, identification of the chemical that adsorb acetaldehyde gas with being impregnated in activated carbon was required, since activated carbon itself does not have ability of adsorbing acetaldehyde gas, and finally found appropriate chemical, vitamin Bx. At the end of this report, sensory evaluation result by twenty panelists with deodorant type cabin air filter impregnated with vitamin Bx, and its efficiency for deodorant will be shown at the end of this report.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

Recently, the demand of shortening the period of development of Mold and Die and the demand of reducing costs are increasing more and more with the shortening of the life cycle of products. In such a situation, Production workplaces for Molds and Dies need development of the environment that more efficiently produces a product with higher added value. Therefore, development of a high performance machine tool and automation of manufacturing by using computer support are more important. However, the determination of the machining process still depends on the experience of the workers and the past actual results. In this work, support of the computer is not fully developed. In this research, we develop process-planning systems for the machining of Molds and Dies (Mill-Plan) as one of the technologies, which solves such a problem. This report reports the result applied to the composition of this system, and some examples.

A new material recycling technology for crosslinked rubber was developed using the continuous reactive processing method. In this process of producing reclaimed rubber, breakage of crosslinking points in the crosslinked rubber occurs selectively under the controls of shear stress, reaction temperature, and internal pressure in a modular screw type reactor. Deodorization during the process has also become possible by a newly developed method. The reclaimed rubber obtained from rubber waste generated from both automobile manufacturing products and post-consumer products shows excellent mechanical properties applicable to new rubber compounds. Furthermore, an enhanced rubber recycling process for producing thermoplastic elastomer (TPE) based on rubber waste has been established. The obtained TPE exhibits highly recoverable rubber elasticity and mechanical properties comparable to commercial TPE.

We studied the adoption of plastics derived from plants (bioplastics) such as poly(lactic acid) (PLA) for automotive parts in order to contribute to suppressing the increase in CO, emissions. For this application. major improvements of heat and impact resistance are needed. As a method to improve heat resistance, we developed PLA combined with clay of high heat resistance. As a result. we succeeded in synthesizing a PLA-clay nanocomposite using 18(OH)2-Mont. In-mold crystallization of PLA-clay nanocomposite lead to the great suppression of storage modulus decrease at high temperature. which in turn improved the heat resistance of PLA.

Phosphating is a surface treatment process widely used for preparing metal surfaces before painting. The phosphate coating plays a very important role in enhancing after-painting corrosion resistance, which is one of the essential quality requirements of painted surfaces. Continued research and development is therefore under way in various parts of the world to increase the corrosion resistance enhancement effect of phosphating. Moreover, because the demand for environmental protection has been increasing in recent years, reducing the amount of waste (sludge) generated during the phosphating process is also strongly required. To meet these requirements, we have developed a novel phosphating technology called the “electrolytic phosphating process,” which drastically enhances corrosion resistance after painting and reduces sludge generation. The developed process has already been put to practical use for surface preparation before cation electrodeposition painting of automotive parts.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.