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A Mercedes E320 CDI vehicle has been modified for more optimal operation on Gas-To-Liquids (GTL) diesel fuel, in order to demonstrate the extent of exhaust emission reductions which are enabled by the properties of this fuel. The engine hardware changes employed comprised the fitment of re-specified fuel injectors and the reduction of the compression ratio from 18:1 to 15:1, as well as a re-optimisation of the software calibration. The demonstration vehicle has achieved a NOx emission of less that 0.08 g/km in the NEDC test cycle, while all other regulated emissions still meet the Euro 4 limits, as well as those currently proposed for Euro 5. CO2 emissions and fuel consumption, were not degraded with the optimised engine. This was achieved whilst employing only cost-neutral engine modifications, and with the standard vehicle exhaust system (oxidation catalyst and diesel particulate filter) fitted.

To fulfill future emission standards for diesel engines, combined after-treatment systems consisting of different catalyst technologies and diesel particulate filters (DPF) are necessary. For designing and optimizing the resulting systems of considerable complexity, effective simulation models of different catalyst and DPF technologies have been developed and integrated into a common simulation environment called ExACT (Exhaust After-treatment Components Toolbox). This publication focuses on a model for the NOx storage and reduction catalyst as a part of that simulation environment. A heterogeneous, spatially one-dimensional (1D), physically and chemically based mathematical model of the catalytic monolith has been developed. A global reaction kinetic approach has been chosen to describe reaction conversions on the washcoat. Reaction kinetic parameters have been evaluated from a series of laboratory experiments.

A numerical model describing the ammonia based SCR process of NOX on zeolite catalysts is presented. The model is able to simulate coated and extruded monoliths. The development of the reaction kinetics is based on a study which compares the activity of zeolite and vanadium based catalysts. This study was conducted in a microreactor loaded with washcoat powder and with crushed coated monoliths. A model for the SCR reaction kinetics on zeolite catalysts is presented. After the parameterization of the reaction mechanism the reaction kinetics were coupled with models for heat and mass transport. The model is validated with laboratory data and engine test bench measurement data over washcoated monolith catalysts. A numerical simulation study is presented, aiming to reveal the differences between zeolite and vanadium based SCR catalysts.

After-treatment systems (ATS) consisting of new catalyst technologies and particulate filters will be necessary to meet increasingly stringent global regulations limiting particulate matter (PM) and NOx emissions from heavy duty and light duty diesel vehicles. Fuels and lubes contain elements such as sulfur, phosphorus and ash-forming metals that can adversely impact the efficiency and durability of these systems. Investigations of the impact of lubricant formulation on the transfer of ash-forming elements to diesel particulate filters (DPF) and transfer of sulfur to NOx storage catalysts were conducted using passenger car diesel engine technology. It was observed that for ATS configurations with catalyst(s) upstream of the DPF, transfer of ash-forming elements to the DPF was significantly lower than expected on the basis of oil consumption and lube composition. Sulfur transfer strongly correlated with oil consumption and lubricant sulfur content.

To meet future emission levels the industry is trying to reduce tailpipe emissions by both, engine measures and the development of novel aftertreatment concepts. The present study focuses on a joint development of aftertreatment concepts for gasoline engines that are optimized in terms of the exhaust system design, the catalyst technology and the system costs. The best performing system contains a close-coupled catalyst double brick arrangement using a new high thermal stable catalyst technology with low precious metal loading. This system also shows an increased tolerance against catalyst poisoning by engine oil.

A design is robust when the performance targets have been achieved and the effects of variation have been minimized without eliminating the causes of the variation such as manufacturing tolerances, material properties, environmental temperature, humidity, operational wear etc. In recent years several robust design concepts have been introduced in an effort to obtain optimum designs and minimize the variation in the product characteristics [1,2]. In this study, a probabilistic design analysis was performed on a catalytic converter substrate in order to determine the required manufacturing tolerance that results in a robust design. Variation in circularity (roundness) and the ultimate shear stress of the substrate material were considered. The required manufacturing tolerance for a robust design with 1,2 and 3 sigma quality levels was determined. The same manufacturing tolerance for a reliability based design with reliability levels of 85%, 90% and 95% was also determined and compared.

A turbocharged version of the 2.4L engine has been developed by the Chrysler Group of DaimlerChrysler Corporation. This new engine is derived from the proven 2.4L 4-cylinder, with significant changes to achieve a durable, high performance package for the PT Cruiser vehicle. The package includes an integrated turbocharger / exhaust manifold, oil squirters for piston cooling, and numerous other upgrades to satisfy the demanding performance, emissions, and durability requirements unique to this powertrain. The purpose of this paper is to describe the mechanical changes to the base engine, the unique turbocharger configuration, and the new parts necessary to accommodate the higher output.

A 1D+1D numerical model describing the ammonia based SCR process of NO and NO2 on vanadia-titania catalysts is presented. The model is able to simulate coated and extruded monoliths. Basing on a fundamental investigation of the catalytic processes a reaction mechanism for the NO/NO2 - NH3 reacting system is proposed and modeled. After the parameterization of the reaction mechanism the reaction kinetics have been coupled with models for heat and mass transport. Model validation has been performed with engine test bench experiments. Finally the model has been applied to study the influence of NO2 on SCR efficiency within ETC and ESC testcycles, Additional simulations have been conducted to identify the potential for catalyst volume reduction if NO2 is present in the inlet feed.

This paper describes work supporting the development of a new Diesel particulate trap system for heavy duty vehicles based on porous sintered metal materials that exhibit interesting characteristics with respect to ash tolerance. Experimental data characterizing the material (permeability, soot and ash deposit properties) are obtained in a dedicated experimental setup in the side-stream of a modern Diesel engine as well as in an accelerated ash loading rig. System level simulations coupling the new media characteristics to 3-D CFD software for the optimization of complete filter systems are then performed and comparative assessment results of example designs are given.

Vehicle thermal protection is an important aspect of the overall vehicle development process. It involves optimizing the exhaust system routing and designing heat shields to protect various components that are in near proximity to the exhaust system. Reduced time to market necessitates an efficient process for thermal protection development. A robust procedure that utilizes state of the art CFD simulation techniques proactively during the design phase is described. Simulation allows for early detection of thermal issues and development of countermeasures several months before prototype vehicles are built. Physical testing is only used to verify the thermal protection package rather than to develop heat shields. The new procedure reduces the number of physical tests and results in a robust, efficient methodology.

The emerging Variable Valve Timing (VVT) technology complicates the estimation of air flow rate because both intake and exhaust valve timings significantly affect engine's gas exchange and air flow rate. In this paper, we propose to use Artificial Neural Networks (ANN) to model the air flow rate through a 2.4 liter VVT engine with independent intake and exhaust camshaft phasers. The procedure for selecting the network architecture and size is combined with the appropriate training methodology to maximize accuracy and prevent overfitting. After completing the ANN training based on a large set of dynamometer test data, the multi-layer feedforward network demonstrates the ability to represent air flow rate accurately over a wide range of operating conditions. The ANN model is implemented in a vehicle with the same 2.4 L engine using a Rapid Prototype Controller.

Component bench fatigue testing is a cost-effective way to evaluate the durability of exhaust catalytic converters. A successful bench fatigue test depends on the development of a test specification. The test specification should represent the actual customer duty cycle that the component is exposed to. Based on the concept of equivalent fatigue damage, a systematic approach is presented to obtain the test specification from the acquired road load data. A method based on damage analysis is proposed to determine the effective notch factor, and an empirical relationship is presented to account for the thermal effect on the test specification. The principles and procedures of multiple block testing and constant amplitude testing are also presented.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

In response to ever more stringent emission limits (EURO IV, SULEV), engine developers are increasingly turning their attention to engine start-up and warm-up phases. Since in this phase the catalytic converter has not yet reached its operating temperature, problems occur especially with regard to hydrocarbon emissions (HC) which are emitted untreated. Secondary air injection represents one option for heating up the catalytic converter more quickly. The engine is operated during the heating up cycle with retarded ignition angles and a rich mixture. Ambient air (secondary air) is injected close to the exhaust valve seat. During the spontaneously occurring post oxidation phase, the reactive exhaust components ignite and heat up the catalytic converter while simultaneously reducing HC. The various processes which affect the post oxidation, are not well known up to now. In order to achieve concrete improvements, detailed knowledge of its influences are necessary.