Refine Your Search

Topic

Author

Search Results

Video

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
Journal Article

Development of Improved Method for Magnetically Formed Decorative Painting

2014-11-11
2014-32-0045
Currently, there is a growing demand for application of plastic coverings for motorcycles in the market. Accordingly, decorative features for plastic coverings are increasingly important to enhance the attractiveness of exterior designs of those motorcycles. Under these circumstances, the magnetically formed decorative painting had been adopted to a mass-production model sold in Thailand in 2008. Magnetically formed decorative painting is a method in which the design patterns are formed by painting a material that contains flakes movable along with magnetic fields, while applying magnetic sheets in the ornamenting design shapes underneath the part being painted. It offers a three-dimensional appearance even though its surface has no protrusions or indentations. The degree of three-dimensionality on the paint surface appearance was defined as “plasticity” [1] (a term used in pictorial arts).
Journal Article

Application of Rapid Heat and Cool Molding to High Strength Outer Parts without Painting Treatment

2016-11-08
2016-32-0024
Glass fiber reinforced plastic of polyamide is applied as one of the materials used for the high strength exterior parts of a motorcycle, such as a rear grab rail or a carrier, to which both strength and good exterior appearance are required. However, Glass Fiber reinforced Polypropylene (PPGF), which is relatively inexpensive material, has a property that the contained glass fibers are prone to be exposed at the surface and, therefore, the requirements for good appearance are hardly met by using PPGF. In this study, Heat and Cool molding method (H&C molding) was employed to realize a cost reduction by using PPGF yet without applying painting process, and the established method was applied to mass production while fulfilling the requirements for a good exterior appearance. In H&C molding, the metal molds are heated up by steam and cooled down by water after molding.
Journal Article

Multi-Variable Air-Path Management for a Clean Diesel Engine Using Model Predictive Control

2009-04-20
2009-01-0733
Recently, emission regulations have been strict in many countries, and it is very difficult technical issue to reduce emissions of diesel cars. In order to reduce the emissions, various combustion technologies such as Massive EGR, PCCI, Rich combustion, etc. have been researched. The combustion technologies require precise control of the states of in-cylinder gas (air mass flow, EGR rate etc.). However, a conventional controller such as PID controller could not provide sufficient control accuracy of the states of in-cylinder gas because the air-pass system controlled by an EGR valve, a throttle valve, a variable nozzle turbo, etc. is a multi-input, multi-output (MIMO) coupled system. Model predictive control (MPC) is well known as the advanced MIMO control method for industrial process. Generally, the sampling period of industrial process is rather long so there is enough time to carry out the optimization calculation for MPC.
Journal Article

Ag-Type PM Oxidation Catalyst with Nd Added to Increase Contact Property between PM and Catalyst

2018-04-03
2018-01-0328
Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.
Journal Article

NOx Trap Three-Way Catalyst (N-TWC) Concept: TWC with NOx Adsorption Properties at Low Temperatures for Cold-Start Emission Control

2015-04-14
2015-01-1002
A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.
Technical Paper

Study on Emission Reducing Method with New Lean NOX Catalyst for Diesel Engines

2007-07-23
2007-01-1933
In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.
Technical Paper

Study on Low NOX Emission Control Using Newly Developed Lean NOX Catalyst for Diesel Engines

2007-04-16
2007-01-0239
In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.
Technical Paper

Development of a 6-Cylinder Gasoline Engine with New Variable Cylinder Management Technology

2008-04-14
2008-01-0610
Aiming for higher output power, greater fuel economy and reduced exhaust emissions, a new V-6 3.5-liter i-VTEC Variable Cylinder Management (VCM) engine has been developed. This engine uses a cylinder-deactivation mechanism with VTEC technology that allows the number of cylinders to be controlled in three modes (three, four or all six cylinders), according to the operating conditions. This adds a four-cylinder mode to the conventional cylinder- deactivation engine. In addition to increasing the number of cylinder- deactivation modes, the new hydraulic circuits, a hydraulic pressure switching mechanism and a switchover control were also developed. These make it possible to instantaneously switch the active cylinders without impairing drivability, in the same manner as a conventional engine.
Technical Paper

Performance of Motorcycle Engine Oil with Sulfur-Based Additive as Substitute Zn-DTP

2008-09-09
2008-32-0005
Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).
Technical Paper

A new concept for occupant deceleration control in a crash

2000-06-12
2000-05-0209
In order to minimize occupant injury in a vehicle crash, an approach was attempted to address this issue by making the wave form of vehicle body deceleration (deceleration curve) optimal to lower the maximum deceleration value applied to the occupant. A study with a one-dimensional, two-mass model was conducted to the kinetic mechanism between the body deceleration curve and the responding occupant''s motion while finding a mathematical solution for the optimal body deceleration curve. A common feature of the derived mathematical solutions is that they consist of three aspects: high deceleration, low or negative deceleration, and constant deceleration. This was demonstrated by simulation with a three-dimensional dummy. The results show that the response of the dummy closely agrees with that of the one-dimensional, two-mass model, thus proving the adequacy of the mathematical solution, and that occupant injury was reduced.
Technical Paper

Research of the ultimate cleanness of internal combustion engine and the application for mass production vehicles

2000-06-12
2000-05-0206
The needs of the non-internal combustion engine for the automobile have been increasingly emphasized due to the seriousness of the air pollution in major cities and the global warming. However, such power plant technologies are generally considered to be still far away from the full commercialization as technical issues including infrastructure and cost are still remaining to be solved, so the substantial emission cleanup through the market penetration requires a long time for the realization. For the mean time, attempts are made to investigate the maximum potential of the internal combustion engine for reduction of both exhaust emissions and CO2 focusing on Honda''s near-zero emission Zero Level Emission Vehicle (ZLEV) technology.
Technical Paper

Study on Engine Management System Using In-cylinder Pressure Sensor Integrated with Spark Plug

2004-03-08
2004-01-0519
There has been strong public demand for reduced hazardous exhaust gas emissions and improved fuel economy for automobile engines. In recent years, a number of innovative solutions that lead to a reduction in fuel consumption rate have been developed, including in-cylinder direct injection and lean burn combustion technologies, as well as an engine utilizing a large volume of exhaust gas recirculation (EGR). Furthermore, a homogeneous charge compression ignition (HCCI) engine is under development for actual application. However, one of the issues common to these technologies is less stable combustion, which causes difficulty in engine management. Additionally, it is now mandatory to provide an onboard diagnosis (OBD) system. This requires manufacturers to develop a technology that allows onboard monitoring and control of the combustion state. This paper reports on an innovative combustion diagnostic method using an in-cylinder pressure sensor.
Technical Paper

Intake and Exhaust Systems Equipped with a Variable Valve Control Device for Enhancing of Engine Power

2001-03-05
2001-01-0247
The variable intake and exhaust control valve system for the in-line four-cylinder motorcycle engine was developed for realization of high engine power in all the engine speed ranges. Both the variable intake and exhaust control valves are operated by one servomotor. For high engine speeds, the exhaust collector pipe design for merging of each exhaust gas flow at 180 degrees phase difference is used. For mid engine speeds, the design for merging of each exhaust gas flow at 360 degrees phase difference is used. Two modes are provided to the intake control, and three modes are provided to the exhaust control. Along with exhaust-gas treatment systems such as the catalyst and air-injection system, high engine performance with optimum driveability and reduced emission are realized.
Technical Paper

Improvement of Heat Resistance for Lean NOx Catalyst

2004-03-08
2004-01-1495
When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.
Technical Paper

Improvement of Thermal Resistance for Lean NOx Catalyst

2003-03-03
2003-01-1166
A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.
Technical Paper

On Demand Octane Number Enhancement Technology by Aerobic Oxidation

2016-10-17
2016-01-2167
For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.
Technical Paper

Study of an Aftertreatment System for HLSI Lean-burn Engine

2018-04-03
2018-01-0945
Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.
Technical Paper

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-04-16
2012-01-0365
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).
Technical Paper

Development of Gasoline Combustion Reaction Model

2013-04-08
2013-01-0887
Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.
X