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Emission of carbon dioxide from mobile sources seriously concerned to solve greenhouse effect and high price of gasoline in some countries have resulted in the development of lean-burn concept engine. In spite of many studies on the lean deNOx catalyst, we have no clear solution to obtain high fuel economy and high efficiency of NOx conversion in lean-burn application. This paper describes applicability and problems of NOx adsorber system to partial lean-burn vehicle, the development of three-way catalyst with improvement of washcoat technology based on three-way catalyst used for gasoline application, and comparison test results of evaluations is synthesized gas activity test, Federal Test Procedure (FTP) test, etc. This study shows improved three-way catalysts in partial lean- burn vehicle have max. 89% of NOx conversion in FTP without adding rich spike and regeneration functions to engine management system.

This study suggests new types of catalysts that show low hydrogen sulfide emission without scavenger such as NiO. Hydrogen sulfide can be reduced by changing the physicochemical properties of washcoat components. Synthesized gas activity tests were performed to investigate the effect of modified washcoat on hydrogen sulfide formation and catalytic activity. BET surface area tests, X- ray diffraction tests, and gas chromatography tests were also carried out to examine the characteristics of catalysts. Preparation methods for catalysts were focused on minimizing the adsorption of sulfur species on catalysts. The first approach is heat treatment of cerium oxide to reduce adsorption sites for sulfur compounds. But this leads to deterioration of CO and NOx conversion efficiencies. The second one is adding new types of promoters that increase thermal durability and dynamic oxygen storing function of cerium oxide.

This paper describes the development of THC reduction technologies compliant with SULEV regulations. Technologies embodied by the developmental work include improvement of fuel spay atomization, quick warm-up through coolant control shut off, and acceleration of fuel atomization for the fast rise of cylinder head temp inside the water jacket as well as the improvement of combustion state. The technologies likewise entail reduced HC while operating in lean A/F condition during engine warm-up with the cold lean-burn technology, individual cylinder A/F control for improvement of catalytic converting efficiency, aftertreatment such as thin-wall catalyst, HC absorber and EHC and etc., through vehicle application evaluation in cold start. We carried out an experimental as well as a practical study against SULEV regulations, and the feasibility of adopting these items in vehicle was likewise investigated.

In HMC, the fundamental research on the hydrogen fueled engine and vehicle has been carried out. For this engine, solenoid driven injector is used to supply gaseous hydrogen into the cylinder and various operating parameters have been changed to study the combustion characteristics of hydrogen. After these experiments on engine, hydrogen fueled vehicle has been constructed and it is controlled by ECU. The amount of emission from the hydrogen vehicle with stoichiometric operation is less than 1/3 of the ULEV legislation.

It is well known that the EHC (Electrically Heated Catalyst) is very effective for the reduction of cold-start hydrocarbon emissions. To optimize EHC applications for LEVI (Low Emission Vehicle) and ULEV (Ultra Low Emission Vehicle) standards, the effect of heating and secondary air injection on the emission purification efficiency in FTP (Federal Test Procedure) were evaluated with three different EHC system configurations. The exhaust manifold location EHC system in which the EHC with a light-off catalyst is installed near the exhaust manifold, yields 0.038g/mile of THC (Total Hydrocarbon emissions) when the test was performed according to the FFP with an engine-aged condition equivalent to 50,000miles. Therefore, the ULEV standards could be achieved through the system. A new battery system for the EHC and a single battery system for vehicle application were evaluated. Evaluation of the Ni-MH battery for EHC system is included.

A new exhaust system has been developed to cope with post-SULEV (Super Ultra-Low Emissions Vehicle) regulation by newly designed hardware of exhaust system. This paper will describe the various new technologies used for achieving the post-SULEV standards, such as Conicat (cone-type metal catalyst), dual-wall pipe, pipe-type metal catalyst, ultra thin wall monolith and HC trap system for the improvement of catalyst light-off time. The tested data on 2.0L SULEV vehicle indicate that Conicat(cone-type metal catalyst) and HC trap (hydrocarbon absorbing catalyst) have more positive characteristics, and are expected to show the enhanced HC reduction performance with the optimization of emission system.